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71.
Fumio Kawamura Masaki TanpoNaoya Miyoshi Mamoru ImadeMasashi Yoshimura Yusuke MoriYasuo Kitaoka Takatomo Sasaki 《Journal of Crystal Growth》2009,311(10):3019-3024
We have discovered a mechanism which can significantly reduce the dislocation density during the growth of GaN single crystals in the Na flux method. The significant reduction of the dislocation density occurs in the later stage of LPE growth, rather than solely at the seed-LPE interface for which we have already reported evidence indicating the presence of bundling dislocations. The two-step dislocation reduction is the key in achieving extremely low dislocation density using this method. 相似文献
72.
Chizuko Kabuto Yutaka Higuchi Tomohiro Niimi Fumio Hamada Nobuhiko Iki Naoya Morohashi Sotaro Miyano 《Journal of inclusion phenomena and macrocyclic chemistry》2002,42(1-2):89-98
X-Ray crystal structures of the mono-, di-, and tri(p-tert-butyl)-substituted thiacalix[4]arenes (TC4As; 1, 2, and 3, respectively) have beendetermined. TC4As 1–3 adopt a cone conformation and form dimeric self-inclusion units in such a manner that phenol moieties are inserted into the cavity of each molecule. In all the crystal structures of 1–3, lateralface-to-face interactions exist between the phenol rings that do not bear a tert-butyl substituent, and seemingly, this molecular assembly stabilizes the formation of self-inclusion. TC4As 1 and 2 adopt a cone conformation with C2 symmetry, leading to the formation of rim-to-rim intermolecular hydrogenbonds so as to link the dimeric units up and down. On the other hand, 3 adopts a regular cone conformation with C4 symmetry to form cyclic hydrogen bonds withinthe rim part of TC4A. 相似文献
73.
Fareha Zafar Khan Masashi Shiotsuki Fumio Sanda Yoshiyuki Nishio Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2008,46(7):2326-2334
The amino acid esters of hydroxypropyl cellulose (HPC) [R′ = H ( 2a ), CH3 ( 2b ), CH2CH(CH3)2 ( 2c ), CH2CONH2 ( 2d ), CH2CH2CONH2 ( 2e ), CH2CH2CH2CH2 NHOCOC(CH3)3 ( 2f )] were synthesized in good yield by the reaction of t‐butoxycarbonyl (t‐Boc)‐protected amino acids with hydroxy groups of HPC ( 1 ; molar substitution (MS), 4.61). The amino acid functionalities displaying varied chemical nature, shape, and bulk were utilized and the bulk of the substituent on the α‐carbon of amino acids was elucidated to be of vital significance for the observed degree of incorporation (DSEst). The 1H NMR spectra and elemental analysis were employed to determine the degree of incorporation of amino acid moiety (DSEst) and almost complete substitution of the hydroxy protons was revealed for 2a , 2b , and 2f . The presence of the peaks characteristic of the carbonyl group in the FTIR spectra furnished further evidence for the successful esterification of HPC. The starting as well as the resulting polymers ( 1 and 2a – f ) were soluble in polar organic solvents; however, the esterification of 1 with bulky organic moieties resulted in an increased hydrophobicity as all of the amino acid‐functionalized polymers ( 2a – f ) were insoluble in water. The onset temperatures of weight loss of 2a – f were 175–230 °C, indicating fair thermal stability. The amino acid functionalization led to the enhanced polymer chain stiffness, and the glass transition temperatures of the derivatized polymers were 30–40 °C higher than that of 1 (Tg 3.9 °C; cf. Tg of 2a – f , 35.1–43.3 °C). © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2326–2334, 2008 相似文献
74.
Ruiyuan Liu Fumio Sanda Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2008,46(12):4175-4182
Copolymerization of ornithine‐ and lysine‐derived N‐propargylamides, N‐α‐tert‐butoxycarbonyl‐N‐δ‐fluorenylmethoxycarbonyl‐L ‐ornithine N′‐propargylamide ( 1 ), N‐α‐tert‐butoxycarbonyl‐N‐ε‐fluorenylmethoxycarbonyl‐L ‐lysine N′‐propargylamide ( 2 ), N‐α‐fluorenylmethoxycarbonyl‐N‐δ‐tert‐butoxycarbonyl‐L ‐ornithine N′‐propargylamide ( 3 ), and N‐α‐fluorenylmethoxycarbonyl‐N‐ε‐tert‐butoxycarbonyl‐L ‐lysine N′‐propargylamide (4) with dipropargyl adipate was carried out using (nbd)Rh+[η6‐C6H5B?(C6H5)3] as a catalyst in THF to obtain polymer gels in 80–93% yields. The gels adsorbed N‐benzyloxycarbonyl L ‐alanine, N‐benzyloxycarbonyl L ‐alanine methyl ester, and (S)‐(+)‐1‐phenyl‐1,2‐ethanediol preferably than the corresponding optical isomers. The order of chiral discrimination was poly( 1 ) > poly( 4 ) > poly( 2 ), poly( 3 ) gels. The fluorenylmethoxycarbonyl groups of the gels could be partly removed by piperidine treatment, leading to increase of adsorptivity but decrease of chiral recognition ability. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4175–4182, 2008 相似文献
75.
76.
Kayo Terada Toshio Masuda Fumio Sanda 《Journal of polymer science. Part A, Polymer chemistry》2009,47(19):4971-4981
Novel optically active ethynyl monomers were synthesized from L ‐valine and N‐methyl‐L ‐valine, and polymerized with a rhodium catalyst to provide the polymers with number‐average molecular weights over 200,000 in good yields. The CD and UV‐vis spectra of the polymers indicated that they took helical structures with predominantly one‐handed screw sense in solution. The polymers served as catalysts of asymmetric reduction of aromatic ketimines to afford optically active amines in moderate yields. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4971–4981, 2009 相似文献
77.
Christian Gérard Fumio Hiroshima Annalisa Panati Akito Suzuki 《Communications in Mathematical Physics》2011,308(2):543-566
We consider the Nelson model on some static space-times and investigate the problem of existence of a ground state. Nelson
models with variable coefficients arise when one replaces in the usual Nelson model the flat Minkowski metric by a static
metric, allowing also the boson mass to depend on position. We investigate the existence of a ground state of the Hamiltonian
in the presence of the infrared problem, i.e. assuming that the boson mass m(x) tends to 0 at spatial infinity. We show that if m(x) ≥ C |x|−1 at infinity for some C > 0 then the Nelson Hamiltonian has a ground state. 相似文献
78.
Susan A. Bourne Katherine L Gifford Nash Fumio Toda 《Journal of inclusion phenomena and macrocyclic chemistry》1999,34(2):169-187
The 2-hexanone inclusion compounds of hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)benzene and 1,2,3,5,6,7-hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)naphthalene have been prepared and characterised by single crystal X-ray diffraction and thermal analysis. The kinetic parameters and mechanisms for the desolvation reaction have also been determined for both compounds. 相似文献
79.
Masashi Shiotsuki Atsushi Nakagawa Jesus Rodriguez Castañon Naoya Onishi Tatsurou Kobayashi Fumio Sanda Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2010,48(23):5549-5556
End‐functionalized poly(phenylacetylene)s were synthesized by the polymerization of phenylacetylene (PA) using the well‐defined palladium catalysts represented as [(dppf)PdBr(R)] {dppf = 1,1′‐bis(diphenylphosphino)ferrocene}. The Pd catalysts having a series of R groups such as o‐tolyl, mesityl, C(Ph)?CPh2, C6H4‐o‐CH2OH, C6H4‐p‐CN, and C6H4‐p‐NO2 in conjunction with silver triflate polymerized PA to give end‐functionalized poly(PA)s bearing the corresponding R groups in high yields. The results of IR and NMR spectroscopies and MALDI‐TOF mass analyses proved the introduction of these R groups at one end of each polymer chain. The poly(PA) bearing a hydroxy end group was applied as a macroinitiator to the synthesis of a block copolymer composed of poly(PA) and poly(β‐propiolactone) moieties. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
80.
We consider a massless scalar Bose field interacting with two particles, one of them infinitely heavy. Neither an infrared nor an ultraviolet cutoff is imposed. In case the charge of the particles is of the same sign and sufficiently small, we prove the existence of a ground state. 相似文献