全文获取类型
收费全文 | 789篇 |
免费 | 10篇 |
国内免费 | 4篇 |
专业分类
化学 | 631篇 |
晶体学 | 18篇 |
力学 | 4篇 |
数学 | 58篇 |
物理学 | 92篇 |
出版年
2020年 | 6篇 |
2016年 | 4篇 |
2015年 | 9篇 |
2014年 | 10篇 |
2013年 | 24篇 |
2012年 | 17篇 |
2011年 | 24篇 |
2010年 | 12篇 |
2009年 | 18篇 |
2008年 | 37篇 |
2007年 | 49篇 |
2006年 | 46篇 |
2005年 | 36篇 |
2004年 | 38篇 |
2003年 | 27篇 |
2002年 | 30篇 |
2001年 | 28篇 |
2000年 | 21篇 |
1999年 | 17篇 |
1998年 | 20篇 |
1997年 | 21篇 |
1996年 | 9篇 |
1995年 | 15篇 |
1994年 | 17篇 |
1993年 | 18篇 |
1992年 | 10篇 |
1991年 | 14篇 |
1990年 | 11篇 |
1989年 | 17篇 |
1988年 | 6篇 |
1987年 | 10篇 |
1986年 | 3篇 |
1985年 | 18篇 |
1984年 | 17篇 |
1983年 | 6篇 |
1982年 | 20篇 |
1981年 | 14篇 |
1980年 | 25篇 |
1979年 | 8篇 |
1978年 | 11篇 |
1977年 | 6篇 |
1976年 | 7篇 |
1975年 | 7篇 |
1974年 | 8篇 |
1973年 | 7篇 |
1972年 | 3篇 |
1971年 | 4篇 |
1970年 | 3篇 |
1969年 | 2篇 |
1967年 | 3篇 |
排序方式: 共有803条查询结果,搜索用时 15 毫秒
61.
Yuzuru Uchida Katsumi Onoue Nobuaki Tada Fumio Nagao Hideaki Kozawa Shigeru Oae 《Heteroatom Chemistry》1990,1(4):295-306
Phosphine oxides bearing two or three 2-pyridyl groups react with organometallic reagents affording 2,2′-bipyridyl, 2-substituted pyridines and pyridine in good yields. Phosphonium salts and phosphine oxides, bearing at least two 2-pyridyl or substituted 2-pyridyl groups also give the corresponding 2,2′-bipyridyls and pyridines upon treatment with acid or neutral solvents such as water and alcohols in substantial yields. The 2,2′-bipyridyls are considered to be formed by ligand coupling within the pentacoordinated phosphorus intermediate formed incipiently during the reaction. 相似文献
62.
Yoshitake T Ichinose F Yoshida H Todoroki K Kehr J Inoue O Nohta H Yamaguchi M 《Biomedical chromatography : BMC》2003,17(8):509-516
A highly sensitive, selective and simple method is described for the determination of histamine by high-performance liquid chromatography (HPLC) with fluorescence detection. The method is based on an intramolecular excimer-forming fluorescence derivatization of histamine with 4-(1-pyrene)butyric acid N-hydroxysuccinimide ester (PSE), followed by reversed-phase HPLC. Histamine, having two amino moieties in a molecule, was converted to the dipyrene-labeled derivative by reaction with PSE. The derivative afforded intramolecular excimer fluorescence (450-540 nm), which can clearly be discriminated from the monomer fluorescence (370-420 nm) emitted from PSE. Typically, a 10 micro L sample solution was mixed with 100 micro L of derivatization reagent solution, which was a mixture of 0.5 mm PSE in acetonitrile and 0.5 mm potassium carbonate in water (8:2, v/v). The derivatization was carried out at 100 degrees C for 90 min. The PSE derivative of histamine could be separated by reversed-phase ODS column with isocratic elution using acetonitrile:water (82:18, v/v) containing 0.03% triethylamine. The detection limit (singnal-to-noise ratio = 3) of histamine was 0.5 fmol for a 30 micro L injection. The method was successfully applied to the determination of histamine in human urine, and had enough selectivity and sensitivity for urinary histamine quantification. 相似文献
63.
Kato D Masaike M Majima T Hirata Y Mizutani F Sakata M Hirayama C Kunitake M 《Chemical communications (Cambridge, England)》2002,(22):2616-2617
Novel two-dimensional (2D) cross-linked polysiloxane LB films were prepared and applied for glucose sensing as H2O2-permselective films in order to block other electroactive interferences, such as L-ascorbic acid, L-cysteine, uric acid and acetaminophen; the 2D cross-linked polysiloxane monolayers were remarkably effective in eliminating interfering responses and had a rapid response for glucose, even though the films were only a monolayer thick. 相似文献
64.
We demonstrate that significant improvements in kinetics of co-crystal formation by grinding can be achieved by the addition of minor amounts of appropriate solvent. 相似文献
65.
A polymer having a trithiocarbonate moiety in the main chain was applied as a polymeric precursor to the synthesis of a sequence ordered polymer by insertion polymerization of styrene into the main chain by a RAFT mechanism. 相似文献
66.
67.
Masahiro Ueda Sanae Mizuno Akio Matsumura Fumio Tohjyo 《Optics and Lasers in Engineering》1996,24(4):339-350
An optical method for measuring the thickness of heterogeneous materials has been studied. The method is based on the light attenuation theory. A complete system has been constructed in order to demonstrate the applicability of the present method for industrial use. The experimental set-up consists of semiconductor lasers, focusing lenses, photo-diodes serving as a power meter and a personal computer with an A/D converter for data acquisition. Averaging of numerous measurements is required in the present method because the heterogeneous cell structure of the foam material yields large fluctuations in transmitted light levels. The fluctuations can be reduced to below 1% of the transmitted light power by 80 times averaging. The error of the measurement is considered to be a few tens of micrometers in thickness. The present system is capable of sampling data at a rate of 400 Hz and has been successfully applied to a manufacturing process. 相似文献
68.
69.
Tatsuo Iwasa Fumio Tokunaga Tôru Yoshizawa Thomas G. Ebrey 《Photochemistry and photobiology》1980,31(1):83-85
Abstract— Quantum efficiencies for photoconversion of bacteriorhodopsin (trans-bR) to a bathochromic product (batho-bRt ) and its photoreversion in purple membrane at 77 and 9 K were investigated with low temperature spectrophotometry. The kinetics of the photoconversion and its photoreversion cannot be expressed by a single exponential curve. The photoconversions at 77 and 9 K showed the same slope in the early stage. The kinetics of the photoreversions were identical at the two temperatures. These results indicate that the quantum efficiencies for the conversion of trans-bR to batho-bRt or for its photoreversion are identical at the two temperatures.
The fact that the photoreversion cannot be expressed by a single exponential curve suggests the existence of several conformational states of batho-bRt due to the trimer structure of the purple membrane. 相似文献
The fact that the photoreversion cannot be expressed by a single exponential curve suggests the existence of several conformational states of batho-bR
70.
Mathematische Annalen - 相似文献