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101.
Manabu Yamada Muniyappan Rajiv Gandhi Yoshihiko Kondo Fumio Hamada 《Supramolecular chemistry》2014,26(7-8):620-630
The ability of chloroform solutions of p-diethylaminomethylthiacalix[4]arene 1 to extract platinum from HCl media was tested. As an ion-pair extractant, compound 1 had the highest platinum extraction ability among all the thiacalix[n]arene derivatives tested in this study. Compound 1 was a highly specific extractant for Pt(IV) ions from single-metal solutions and platinum-group metal solutions from automotive catalyst residue. Various conditions such as contact time, pH, concentration of 1, effect of chloride ions, effect of acidity and Pt(IV) concentration were studied. The distribution ratio of platinum ions (D) was calculated. The platinum complex stoichiometry ratio was obtained using slope analysis. The 1–Pt(IV) complex was characterised using X-ray photoelectron spectroscopy, FT-IR and 1H NMR. Finally, the Pt(IV) extraction percentage of compound 1 was compared with that of previously reported thiacalix[n]arene-based extractants. 相似文献
102.
Yasumasa Hamada 《Chemical record (New York, N.Y.)》2014,14(2):235-250
This review describes our recent works on the diastereo‐ and enantioselective synthesis of anti‐β‐hydroxy‐α‐amino acid esters using transition‐metal–chiral‐bisphosphine catalysts. A variety of transition metals, namely ruthenium (Ru), rhodium (Rh),iridium (Ir), and nickel (Ni), in combination with chiral bisphosphines, worked well as catalysts for the direct anti‐selective asymmetric hydrogenation of α‐amino‐β‐keto ester hydrochlorides, yielding anti‐β‐hydroxy‐α‐amino acid esters via dynamic kinetic resolution (DKR) in excellent yields and diastereo‐ and enantioselectivities. The Ru‐catalyzed asymmetric hydrogenation of α‐amino‐β‐ketoesters via DKR is the first example of generating anti‐β‐hydroxy‐α‐amino acids. Complexes of iridium and axially chiral bisphosphines catalyze an efficient asymmetric hydrogenation of α‐amino‐β‐keto ester hydrochlorides via dynamic kinetic resolution. A homogeneous Ni–chiral‐bisphosphine complex also catalyzes an efficient asymmetric hydrogenation of α‐amino‐β‐keto ester hydrochlorides in an anti‐selective manner. As a related process, the asymmetric hydrogenation of the configurationally stable substituted α‐aminoketones using a Ni catalyst via DKR is also described. 相似文献
103.
Lung cancer is the leading type of cancer worldwide in terms of the number of new cases and is responsible for the largest number of deaths due to poor prognosis and difficult early detection. Due to its ability to detect numerous small molecular metabolites simultaneously, metabolomics has been widely used for the assessment of global metabolic changes in a living organism to discover candidate biomarkers for cancer diagnosis, investigate the development of cancer, and provide insights into the underlying pathophysiology. This review will mainly describe recent developments in lung cancer metabolomics in terms of early‐stage detection, biomarker discovery and mechanism exploration by using nuclear magnetic resonance, liquid chromatography–mass spectrometry, gas chromatography–mass spectrometry, and capillary electrophoresis–mass spectrometry in the last 10 years. The sample collection and metabolite extraction methods are also summarized. 相似文献
104.
Kato D Masaike M Majima T Hirata Y Mizutani F Sakata M Hirayama C Kunitake M 《Chemical communications (Cambridge, England)》2002,(22):2616-2617
Novel two-dimensional (2D) cross-linked polysiloxane LB films were prepared and applied for glucose sensing as H2O2-permselective films in order to block other electroactive interferences, such as L-ascorbic acid, L-cysteine, uric acid and acetaminophen; the 2D cross-linked polysiloxane monolayers were remarkably effective in eliminating interfering responses and had a rapid response for glucose, even though the films were only a monolayer thick. 相似文献
105.
We demonstrate that significant improvements in kinetics of co-crystal formation by grinding can be achieved by the addition of minor amounts of appropriate solvent. 相似文献
106.
A polymer having a trithiocarbonate moiety in the main chain was applied as a polymeric precursor to the synthesis of a sequence ordered polymer by insertion polymerization of styrene into the main chain by a RAFT mechanism. 相似文献
107.
The fast potential change near the separatrix is measured directly at the L-H transition by a heavy-ion-beam probe. The potential changes with two different time scales at the L-H transition triggered by a sawtooth crash: it drops at first with the time scale of 10--100 mus just after the arrival of the heat pulse due to the sawtooth crash. Then, it decreases again at a few 100 mus after the first drop at a time scale of about 200 mus. 相似文献
108.
Hashi K Shimizu T Goto A Kiyoshi T Matsumoto S Wada H Fujito T Hasegawa K Yoshikawa M Miki T Ito S Hamada M Hayashi S 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2002,156(2):318-321
We have developed a 920-MHz NMR system and performed the proton NMR measurement of H(2)O and ethylbenzene using the superconducting magnet operating at 21.6 T (920 MHz for proton), which is the highest field produced by a superconducting NMR magnet in the persistent mode. From the NMR measurements, it is verified that both homogeneity and stability of the magnet have a specification sufficient for a high resolution NMR. 相似文献
109.
110.
Masahiro Ueda Sanae Mizuno Akio Matsumura Fumio Tohjyo 《Optics and Lasers in Engineering》1996,24(4):339-350
An optical method for measuring the thickness of heterogeneous materials has been studied. The method is based on the light attenuation theory. A complete system has been constructed in order to demonstrate the applicability of the present method for industrial use. The experimental set-up consists of semiconductor lasers, focusing lenses, photo-diodes serving as a power meter and a personal computer with an A/D converter for data acquisition. Averaging of numerous measurements is required in the present method because the heterogeneous cell structure of the foam material yields large fluctuations in transmitted light levels. The fluctuations can be reduced to below 1% of the transmitted light power by 80 times averaging. The error of the measurement is considered to be a few tens of micrometers in thickness. The present system is capable of sampling data at a rate of 400 Hz and has been successfully applied to a manufacturing process. 相似文献