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151.
A Si-based light emitter has long been the final key component for electronic and photonic integrated circuits on Si, because Si has an indirect band gap. Atomistic and electronic structures and energy gains of formation of possible nitrogen (N) and fluorine (F) complexes in Si have been researched from first-principles, in order to engineer the band structure of Si for light emission. The calculated results show that the substitutional nitrogen NS and bond center fluorine FBC pair complex has large stabilization energy, and that the pair-complex-doped Si has direct band gap, which is reduced with respect to that of Si. These results lead to the possibilities of doping-based engineering of Si optical properties with introduction of deep-level impurity and charge compensation. 相似文献
152.
Lee Y Watanabe T Takata T Hara M Yoshimura M Domen K 《The journal of physical chemistry. B》2006,110(35):17563-17569
The photocatalytic activity of beta-Ge(3)N(4) powder for overall water splitting is successfully enhanced by ammonia treatment at 823 K for 5-24 h at ammonia pressures of 20 MPa or greater. The surface and bulk nitrogen content in the treated samples varies according to the treatment temperature and treatment time, related to the stability of beta-Ge(3)N(4) powder under pressurized ammonia. The change in nitrogen content resulted in a change in the photocatalytic activity for overall water splitting. A beta-Ge(3)N(4) powder treated at 823 K for 5 h under ammonia at 20 MPa exhibited a photocatalytic activity 4 times higher than that of the as-synthesized powder, attributable to a decrease in the density of anion defects in the bulk and surface. 相似文献
153.
Fumihiko Maekawa Okiru Komine Katsushige Sato Tomoyuki Kanamatsu Motoaki Uchimura Kohichi Tanaka Hiroko Ohki-Hamazaki 《BMC neuroscience》2006,7(1):1-13
Background
Results of the Women's Health Initiative Memory Study (WHIMS) raised concerns regarding the timing and formulation of hormone interventions. Conjugated equine estrogens (CEE), used as the estrogen therapy in the WHIMS trial, is a complex formulation containing multiple estrogens, including several not secreted by human ovaries, as well as other biologically active steroids. Although the full spectrum of estrogenic components present in CEE has not yet been resolved, 10 estrogens have been identified. In the present study, we sought to determine which estrogenic components, at concentrations commensurate with their plasma levels achieved following a single oral dose of 0.625 mg CEE (the dose used in the WHIMS trial) in women, are neuroprotective and whether combinations of those neuroprotective estrogens provide added benefit. Further, we sought, through computer-aided modeling analyses, to investigate the potential correlation of the molecular mechanisms that conferred estrogen neuroprotection with estrogen interactions with the estrogen receptor (ER).Results
Cultured basal forebrain neurons were exposed to either β-amyloid25–35 or excitotoxic glutamate with or without pretreatment with estrogens followed by neuroprotection analyses. Three indicators of neuroprotection that rely on different aspects of neuronal damage and viability, LDH release, intracellular ATP level and MTT formazan formation, were used to assess neuroprotective efficacy. Results of these analyses indicate that the estrogens, 17α-estradiol, 17β-estradiol, equilin, 17α-dihydroequilin, equilinen, 17α-dihydroequilenin, 17β-dihydroequilenin, and Δ8,9-dehydroestrone were each significantly neuroprotective in reducing neuronal plasma membrane damage induced by glutamate excitotoxicity. Of these estrogens, 17β-estradiol and Δ8,9-dehydroestrone were effective in protecting neurons against β-amyloid25–35-induced intracellular ATP decline. Coadministration of two out of three neuroprotective estrogens, 17β-estradiol, equilin and Δ8,9-dehydroestrone, exerted greater neuroprotective efficacy than individual estrogens. Computer-aided analyses to determine structure/function relationships between the estrogenic structures and their neuroprotective activity revealed that the predicted intermolecular interactions of estrogen analogues with ER correlate to their overall neuroprotective efficacy.Conclusion
The present study provides the first documentation of the neuroprotective profile of individual estrogens contained within the complex formulation of CEE at concentrations commensurate with their plasma levels achieved after an oral administration of 0.625 mg CEE in women. Our analyses demonstrate that select estrogens within the complex formulation of CEE contribute to its neuroprotective efficacy. Moreover, our data predict that the magnitude of neuroprotection induced by individual estrogens at relatively low concentrations may be clinically undetectable and ineffective, whereas, a combination of select neuroprotective estrogens could provide an increased and clinically meaningful efficacy. More importantly, these data suggest a strategy for determining neurological efficacy and rational design and development of a composition of estrogen therapy to alleviate climacteric symptoms, promote neurological health, and prevent age-related neurodegeneration, such as AD, in postmenopausal women. 相似文献154.
Fumihiko Maekawa Okiru Komine Katsushige Sato Tomoyuki Kanamatsu Motoaki Uchimura Kohichi Tanaka Hiroko Ohki-Hamazaki 《BMC neuroscience》2006,7(1):75
Background
Imprinting behavior is one form of learning and memory in precocial birds. With the aim of elucidating of the neural basis for visual imprinting, we focused on visual information processing. 相似文献155.
Yukihiro Yoshimura 《高压研究》2013,33(1):172-177
I have examined the changes in in situ Raman spectra of ice in aqueous LiOH solution as a function of pressure at liquid nitrogen temperature (77 K). Here, I have shown the possibility that ice in aqueous LiOH solution transforms to a high-density amorphous like phase at around 0.9 GPa. I have mentioned that the results show differences strongly depending on the salts dissolved in the aqueous solutions. 相似文献
156.
The energy dependence of crystalline structures in Au thin-film deposition processes was investigated with the use of a low-energy mass-selected ion beam system. Au films deposited on Si(100) untreated wafer surfaces by the beam system at different ion energies in the range of 20–200?eV were analyzed by atomic force microscopy (AFM), X-ray diffraction (XRD) and in-situ reflection high-energy electron diffraction (RHEED). The XRD results show that the kinetic energy provided by ion bombardment can facilitate crystal growth with specific orientations such as (100) or (110), the surfaces of which have relatively high surface energies. Our observations also suggest that each crystalline orientation appears only in a specific energy range of ion bombardment. These results indicate that Au crystalline orientations may be controlled by the ion irradiation energy during deposition processes. 相似文献
157.
Shiro Aizawa Etsuro Yoshimura Miwako Hamachi Hiroki Haraguchi Yukiko Dokiya Keiichiro Fuwa 《光谱学快报》2013,46(4):191-202
Flame emission determination of Sr in sea water is studied using an ordinary atomic absorption apparatus. The analytical line 4607 A is used with background correction at 4616 A. The ionization is found to be negligible in air acetylene flame with sea water, and the interference of H2SO4 is elimentated using the higher part of the flame. 相似文献
158.
M. Hidaka M. Yoshimura H. Nishimori H. Fujii Jae-Young Choi Yong Jun Park 《Phase Transitions》2013,86(4):503-522
The structural phase transitions of the layer compound BaMnF4 were studied by high-resolution X-ray diffraction using synchrotron radiation. The intensities and profiles of two kinds of superlattice reflections having incommensurate reduced wave vectors q 1= (~ ± 1/5,0,0) p and q 2 =(~ ± 2/5,1/2,1/2)p, respectively, were measured as a function of temperature from 25 K to 280 K. These temperature dependencies show that incommensurate structural phase transitions of second order occur at 234 K and 244 K. These structural phase transitions are interpreted as successive condensations of a folding-screen-like incommensurate plane-distortion mode and a commensurate anti-ferro-distortive tilting mode of the MnF6 octahedra around the primitive a0 - and b0 -axes, when cooled down. It is also found that there is another structural phase transition at about 45 K related to a precursor structural distortion for the antiferromagnetic transition occurring at about 26 K. 相似文献
159.
T. Yamamoto S. Maruyama S. Nishiwaki M. Yoshimura 《Journal of sound and vibration》2008,318(1-2):109-130
This paper describes a new design method to optimize thickness distribution of a multilayered structure which is located on the coupling surface between a structure and an acoustic cavity. The design method is based on the concept of the density approach in topology optimization incorporating a transfer matrix for a multilayered structure that includes a poroelastic media layer. The one-dimensional transfer matrix adopted here is an approximate representation addressing vibro-acoustic effects inherent in a multilayered structure, and balances calculation resources and desired accuracy. Applying the transfer matrix representation as boundary conditions on the coupling surface between a structure and an acoustic cavity, the modified equilibrium equation of the vibro-acoustic system is derived which is approximately but efficiently solved by the modal approach. In this study, the problem of minimizing the acoustic pressure within the cavity over the prescribed frequency range is formulated under the volume constraint of the poroelastic media layer. The continuous approximation of thickness distribution is assumed, and the thickness of the poroelastic media layer at each nodal point is chosen as design variables. Numerical results show that an acoustic response is significantly reduced by the optimal thickness distribution having a total weight equal to or less than that in the initial uniform thickness. These demonstrate that the proposed method is effective to design the optimal thickness distribution of a multilayered structure. 相似文献
160.
A simulator for self-organized lightwave network (SOLNET) is developed. The simulator is based on the finite difference time domain method. SOLNET enables us to construct self-aligned coupling waveguides between misaligned micro/nanometer-scale optical devices by self-focusing, which arises from an increase in refractive index induced by write beams in photo-refractive materials. The SOLNET simulator reveals that an L-shaped nanometer-scale optical waveguide of SOLNET is grown from a 0.5-μm-wide optical waveguide when write beams are introduced from the optical waveguide into photo-refractive materials, where a wavelength filter is embedded. The SOLNET simulator also reproduces coupling path construction between a 2-μm-wide optical waveguide and a 0.5-μm-wide optical waveguide having a wavelength filter on the core edge. The optical waveguides are placed with misalignment of 0.5-μm offset. By introducing write beams from the 2-μm-wide optical waveguide, the incident write beams and reflected write beams from the wavelength filter merge into one optical waveguide in the photo-refractive materials, constructing a self-aligned coupling waveguide. 相似文献