全文获取类型
收费全文 | 401篇 |
免费 | 17篇 |
国内免费 | 1篇 |
专业分类
化学 | 296篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 7篇 |
物理学 | 114篇 |
出版年
2023年 | 2篇 |
2021年 | 7篇 |
2020年 | 6篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2016年 | 8篇 |
2015年 | 6篇 |
2014年 | 5篇 |
2013年 | 12篇 |
2012年 | 17篇 |
2011年 | 24篇 |
2010年 | 13篇 |
2009年 | 13篇 |
2008年 | 19篇 |
2007年 | 29篇 |
2006年 | 34篇 |
2005年 | 20篇 |
2004年 | 19篇 |
2003年 | 7篇 |
2002年 | 14篇 |
2001年 | 11篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 10篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 9篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1976年 | 1篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1972年 | 1篇 |
排序方式: 共有419条查询结果,搜索用时 31 毫秒
91.
Iida A Takai K Okabayashi T Misaki T Tanabe Y 《Chemical communications (Cambridge, England)》2005,(25):3171-3173
We have developed a practical crossed Claisen condensation between ketene silyl acetals and methyl esters using catalytic NaOH to obtain alpha-monoalkylated beta-keto esters and inaccessible alpha,alpha-dialkylated beta-keto esters. 相似文献
92.
A method for measuring specific activities of 14C-labelled compounds by gas chromatography-mass spectrometry-computer system (GC-MS-CPU) was developed. This method was proved to provide practically precise and accurate specific activities of various 14C-labelled compounds with such merits as requirement of small amount of samples, being applicable to volatile compounds, and convenience. The C.V. percent obtained for tested compounds was within 3.9 and the reliable sensitivity should be over 37 MBq/mM (1 mCi/mM). This method was also useful for obtaining information on the labelling pattern and the synthetic procedures applied. 相似文献
93.
The separation of cold drugs and neuroleptics by high-performance liquid chromatogarphy with the porous polymer resin DVB-MCL-O (or 11-30-0), which is a styrene-divinylbenzene-methyl methacrylate copolymer substituted with hydroxymethyl groups, was studied. This copolymer was compared with the commercial porous polymers Hitachi gel 3011, 3011-0 and 3030. A very small theoretical plate height was obtained by using DVB-MCL-O and methanol-ammonia solution (99:1) as the stationary and mobile phases, respectively. This combination was found to be the most suitable for the rapid separation of condensed aromatic ring compounds. 相似文献
94.
95.
Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described. 相似文献
96.
97.
Cover Picture: Controlled Synthesis of Nanoporous Nickel Oxide with Two‐Dimensional Shapes through Thermal Decomposition of Metal–Cyanide Hybrid Coordination Polymers (Chem. Eur. J. 9/2015) 下载免费PDF全文
98.
99.
Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate
Treatment of tertiary amines with diazoacetate in the presence of a catalytic amount of an iron salt, FeCl(3), in ethanol gave glycine derivatives. In this reaction, a carbon-nitrogen single bond of the amine was cleaved. 相似文献
100.
The synthesis of unsymmetric functionalized pentacenes from 1,4-anthraquinones and functionalized isobenzofurans, which were prepared by transformation via C-H bond activation, was successfully accomplished. Examples of the synthesis of pentacenes with functional groups at the 5-position are still rare. These obtained functionalized pentacenes are highly soluble in hexane, toluene, and THF. 相似文献