Phenolic Compound Profile by UPLC-MS/MS and Encapsulation with Chitosan of Spondias mombin L. Fruit Peel Extract from Cerrado Hotspot—Brazil

Taperebá (Spondias mombin L.) is a native species of the Brazilian Cerrado that has shown important characteristics such as a significant phenolic compound content and biological activities. The present study aimed to characterize the phenolic compound profile and antioxidant activity in taperebá peel extract, as well as microencapsulating the extract with chitosan and evaluating the stability of the microparticles. The evaluation of the profile of phenolic compounds was carried out by UPLC-MS/MS. The in vitro antioxidant activity was evaluated by DPPH and ABTS methods. The microparticles were obtained by spray drying and were submitted to a stability study under different temperatures. In general, the results showed a significant content of polyphenols and antioxidant activity. The results of UPLC-MS/MS demonstrated a significant content of polyphenols in taperebá peel, highlighting the high content of ellagic acid and quercetin compounds. There was significant retention of phenolic compounds when microencapsulated, demonstrating high retention at all evaluated temperatures. This study is the first to microencapsulate the extract of taperebá peel, in addition to identifying and quantifying some compounds in this fruit.     

CW laser-induced photothermal conversion and shape transformation of gold nanodogbones in hydrated chitosan films

We investigate the photothermal conversion and transformation of gold nanoparticles with an initial dogbone shape after dispersion in hydrated chitosan films, which is a representative model of biological tissue, and excitation by a CW diode laser for 1 min. Gold nanodogbones are observed to undergo a distinct modification above a sharp threshold of ~11 W cm⁻² and 110 °C. Surprisingly, the very same modification is achieved up to at least 36 W cm⁻² and 250 °C. We use an analytical model derived from Gans theory to associate the change in color of the films with the change in shape statistics of these gold nanoparticles. This model proves both convenient and dependable. We interpret the photothermal transformation as a rearrangement of particles with a dogbone shape and an aspect ratio of 4.1 into rods with an aspect ratio of 2.5, where material from the end lobes of the dogbones may relocate to the waists of the rods. In turn, additional transitions to stable gold nanospheres may exhibit fairly slower kinetics.     

Two techniques for PIV-based aeroacoustic prediction and their application to a rod-airfoil experiment

In this paper, we discuss techniques by which the aeroacoustic properties of the turbulent flow in a rod-airfoil benchmark experiment can be inferred from time-resolved PIV measurement. While acoustic measurements can be made directly using microphones, the proposed techniques provide a means to directly link acoustic waves with specific flow events, which is invaluable in devising noise mitigation strategies. The approaches are possible thanks to recent improvements in digital and camera technology that can provide time-resolved measurements in air flows, necessary for the determination of unsteady flow quantities related to aeroacoustic production. Both techniques are based on Curle’s acoustic analogy, where one is based on Lagrangian determination of the required quantities, while the other requires all flow quantities to be converted into Fourier modes. Application of both techniques yields results that are in reasonable agreement with microphone noise measurements for the rod-airfoil experiment.     

Studies on comblike polymers. X. Characterization of comblike polyesters by 13C NMR spectroscopy

The ¹³C NMR spectra of aromatic comblike polyesters obtained from 1,2-icosanediol and isomeric phthalic acids are reported and discussed. The analysis shows that the most informative spectral regions are those of the carbonyl and quaternary carbon resonances, whose peak multiplicities have been interpreted in terms of dyad and triad sequences. The results indicate that the extent of structural characterization possible for the polymers examined is dependent on the type of isomerism of the aromatic acid involved.     

Synthesis and ab-initio XRPD structure of group 12 imidazolato polymers

Two new 3D homoleptic binary imidazolates, Cd(im)2 and Hg(im)2 (Him = imidazole), as well as [Hg(im)]NO3, containing 1D polycations of [Hg(im)]n(n+) formulation, have been prepared and characterized by ab-initio XRPD methods.     

Maximal functions with polynomial densities in lacunary directions

Given a real polynomial in one variable such that , we consider the maximal operator in ,

0\,,\,i,j\in \mathbb{Z}}\frac{1... ...t f\big (x_{1}-2^{i}p(t),x_{2}-2^{j}p(t)\big )\big \vert\,dt . \end{displaymath}">

We prove that is bounded on for 1$"> with bounds that only depend on the degree of .

     

Convex curves, Radon transforms and convolution operators defined by singular measures

Let be a convex curve in the plane and let be the arc-length measure of Let us rotate by an angle and let be the corresponding measure. Let . Then This is optimal for an arbitrary . Depending on the curvature of , this estimate can be improved by introducing mixed-norm estimates of the form where and are conjugate exponents.