Effects of downstream magnetic field collimation on ion behavior inelectron cyclotron resonance microwave plasma

Effects of a magnetic held collimation on ion behavior in the downstream region of an electron cyclotron resonance (ECR) plasma device are clarified experimentally using a directional ion energy analyzer. The drift energy and its spread of the ion beam observed in the downstream region decrease and the beam temperature increases with the collimating magnetic flux density. Then, the ion temperature measured perpendicular to the axis of the plasma stream slightly decreases. The ion beam is found to be almost parallel to the magnetic field lines, that is, the beam tends to be collimated     

Ion-size effects on the structure and superconductivity of La-214 compounds at 1/8 doping

A structural transition to a low-temperature tetragonal (TLT) phase occurs below T_d2≈60 K in La_2−xBa_xCuO₄ only around x=0.125, accompanied by sharp suppression of superconductivity. In this study we investigated the effects of partial substitution of smaller divalent cations for Ba²⁺ ions (Ba²⁺ > Sr²⁺ > Ca²⁺) on these anomalous low-temperature properties. The suppression of superconductivity is strongly affected by the appearance of the TLT phase for this carrier concentration. We also show that the variations of T_d2 and T_c are quantitatively scaled by the averaged size of cations at the La site. This dependence can be interpreted as chemical effects acting effectively as applied pressure. We discuss how our observation is related to recent reports which claim that the TLT structure itself does not necessarily destroy the superconductivity.     

57Fe Mössbauer study under high pressure; ε-Fe and Fe2O3

Using diamond anvil cell, the⁵⁷Fe Mössbauer spectra of pure iron foil and α-Fe₂O₃ powder under high pressure have been measured at room temperature.⁵⁷Fe Mössbauer spectra of α-Fe were measured from 15 GPa to 45 GPa. Isomer shift value decreased and the quadrupole splitting slightly increased as the pressure increased.⁵⁷Fe Mössbauer spectra of Fe₂O₃ under high pressure up to 72 GPa were observed. Above 52 GPa, the new lines appeared at the center portion of the spectrum corresponding to the new high pressure phase. The spectrum of new high pressure phase consisted of 6-line splitting and doublet, suggesting the existence of the two different kinds of iron states in it.     

Carbazole Dendrimers as Solution‐Processable Thermally Activated Delayed‐Fluorescence Materials

Recently, thermally activated delayed fluorescence (TADF) materials have received increasing attention as effective emitters for organic light‐emitting diodes (OLEDs). However, most of them are usually employed as dopants in a host material. In this report, carbazole dendrimers with a triphenyl‐s‐triazine core are reported, which are the first solution‐processable, non‐doped, high‐molecular‐weight TADF materials. The dendrimers were obtained by a new and facile synthetic route using the tert‐butyldimethylsilyl moiety as a protecting group. All dendrimers showed TADF in toluene. Measurements of the temperature‐dependent luminescence lifetime revealed that spin‐coated neat films also showed TADF with moderate quantum yields. OLED devices incorporating these dendrimers as spin‐coated emitting layers gave external quantum efficiencies of up to a 3.4 %, which suggests that this device is harvesting triplet excitons. This result indicates that carbazole dendrimers with attached acceptors are potential TADF materials owing to their polarized electronic structure (with HOMO–LUMO separation).     

Hydrogen Production from a Methanol–Water Solution Catalyzed by an Anionic Iridium Complex Bearing a Functional Bipyridonate Ligand under Weakly Basic Conditions

An efficient catalytic system for the production of hydrogen from a methanol–water solution has been developed using a new anionic iridium complex bearing a functional bipyridonate ligand as a catalyst. This system can be operated under mild conditions [weakly basic solution (0.046 mol L^?1 NaOH) below 100 °C] without the use of an additional organic solvent. Long‐term continuous hydrogen production from a methanol–water solution catalyzed by the anionic iridium complex was also achieved.     

Rattling in the Quadruple Perovskite CuCu3V4O12

Of particular interest is a peculiar motion of guest atoms or ions confined to nanospace in cage compounds, called rattling. While rattling provides unexplored physical properties through the guest–host interactions, it has only been observed in a very limited class of materials. Herein, we introduce an A‐site‐ordered quadruple perovskite, CuCu₃V₄O₁₂, as a new family of cage compounds. This novel AA′₃B₄O₁₂‐type perovskite has been obtained by a high‐pressure synthesis technique and structurally characterized to have cubic Im$\bar 3$ symmetry with an ionic model of Cu²⁺Cu²⁺₃V⁴⁺₄O₁₂. The thermal displacement parameter of the A‐site Cu²⁺ ion is as large as U_iso≈0.045 Ų at 300 K, indicating its large‐amplitude thermal oscillations in the oversized icosahedral cages. Remarkably, the presence of localized phonon modes associated with rattling of the A‐site Cu²⁺ ion manifests itself in the low‐temperature specific heat data. This work sheds new light on the structure–property relations in perovskites.     

High Catalytic Activity of Nitrogen and Sulfur Co‐Doped Nanoporous Graphene in the Hydrogen Evolution Reaction

Chemical doping has been demonstrated to be an effective way to realize new functions of graphene as metal‐free catalyst in energy‐related electrochemical reactions. Although efficient catalysis for the oxygen reduction reaction (ORR) has been achieved with doped graphene, its performance in the hydrogen evolution reaction (HER) is rather poor. In this study we report that nitrogen and sulfur co‐doping leads to high catalytic activity of nanoporous graphene in HER at low operating potential, comparable to the best Pt‐free HER catalyst, 2D MoS₂. The interplay between the chemical dopants and geometric lattice defects of the nanoporous graphene plays the fundamental role in the superior HER catalysis.     

Striking Differences in Properties of Geometric Isomers of [Ir(tpy)(ppy)H]+: Experimental and Computational Studies of their Hydricities,Interaction with CO2, and Photochemistry

We prepared two geometric isomers of [Ir(tpy)(ppy)H]⁺, previously proposed as a key intermediate in the photochemical reduction of CO₂ to CO, and characterized their notably different ground‐ and excited‐state interactions with CO₂ and their hydricities using experimental and computational methods. Only one isomer, C‐trans‐[Ir(tpy)(ppy)H]⁺, reacts with CO₂ to generate the formato complex in the ground state, consistent with its calculated hydricity. Under photocatalytic conditions in CH₃CN/TEOA, a common reactive C‐trans‐[Ir(tpy)(ppy)]⁰ species, irrespective of the starting isomer or monodentate ligand (such as hydride or Cl), reacts with CO₂ and produces CO with the same catalytic efficiency.     

Experimental comparison of two laser-based velocimeters for flows with alluvial sand

 Nonintrusive measurements in a sediment-laden flow using two laser-based techniques, Discriminator Laser-Doppler Velocimetry (DLDV) and Particle Tracking Velocimetry (PTV), are compared. DLDV was previously developed at the Iowa Institute of Hydraulic Research, while PTV was specially configured for this application. Mean and fluctuating velocity components for both flow fractions were simultaneously measured in a laboratory-scale, submerged water jet loaded with alluvial sand. This information cannot be obtained using existing measurement techniques. The jet Reynolds number was 6120, and the sediment sieve diameter ranged from 0.5 to 0.6 mm. Small mass loadings of sand with inertial time constant τ _p of 0.6 ms were examined. The configuration, operation, and results obtained using the DLDV and PTV are presented. For each technique, means to precisely distinguish between the light scattered by suspended sand and that originating from seed-particles following the water were implemented. The agreement in measurement for the two methods validates one another since they are based on completely different principles of operation. The capabilities of DLDV and PTV to reliably measure sand and water velocities in sediment-laden flows are further indicated by the agreement of the present findings with those obtained previously in similar studies. The comparison suggests that PTV, due to its whole field nature, could become a powerful tool for flow and particle-related diagnostics, yielding fundamental information in an area with a long history of conflicting experimental evidence. Received: 27 August 1996 / Accepted: 25 June 1997