利用严格模式理论分析光栅透镜的衍射特性

光栅透镜因其独特的光学性能而具有广泛的应用.根据光栅透镜的线宽和间距微小渐变的特点,建立了光栅透镜的物理模型,并利用严格模式理论对其衍射特性进行分析.该方法物理概念清晰、公式简洁.对光栅透镜实现谐波分离、聚焦功能时的衍射效率与槽深关系的计算结果表明,其计算速度快、数值计算结果准确可靠.并对加工误差的影响进行了模拟计算,说明了在当前的微细加工的工艺水平条件下,能够制作出满足ICF系统要求的光栅透镜.实验上制作了尺寸为100 mm的大面积光栅透镜,其衍射效率的实验测试结果与理论计算结果一致.     

Finite element beam propagation method for analysis of plasmonic waveguide

The basic idea of the finite element beam propagation method (FE-BPM) is described. It is applied to calculate the fundamental mode of a channel plasmonic polariton (CPP) waveguide to confirm its validity. Both the field distribution and the effective index of the fundamental mode are given by the method. The convergence speed shows the advantage and stability of this method. Then a plasmonic waveguide with a dielectric strip deposited on a metal substrate is investigated, and the group velocity is negative for the fundamental mode of this kind of waveguide. The numerical result shows that the power flow direction is reverse to that of phase velocity.     

Spheric long-focal-depth lens

Spheric lens designed by nonlinear phase fitting method is proposed to duplicate the performance of logarithmic axicon, which can obtain a beam with long-focal-depth, small focal spot and side lobe. Moreover, the spheric lens is easier and less expensive for manufacture than logarithmic or aspherical elements. Based on this method, a simple lens is designed for the plasma diagnostic system in inertial confinement fusion. It is verified through Fresnel diffraction integral and an initial experiment that the performance of the lens can satisfy the requirements of the plasma measurements.     

几种三相催化剂在氰代、碘代和二氯卡宾反应中的催化行为

本工作研究了带含氧冠醚、氮杂冠醚、酚醛型冠醚、开链冠醚的四种聚合物作为三相催化剂在氰代、碘代和二氯卡宾反应中的催化活性,其中以冠醚环上带有叔胺氮原子的氮杂冠醚聚合物催化活性最好。     

Characteristic Volatile Fingerprints and Odor Activity Values in Different Citrus-Tea by HS-GC-IMS and HS-SPME-GC-MS

Citrus tea is an emerging tea drink produced from tea and the pericarp of citrus, which consumers have increasingly favored due to its potential health effects and unique flavor. This study aimed to simultaneously combine the characteristic volatile fingerprints with the odor activity values (OAVs) of different citrus teas for the first time by headspace gas chromatography-ion mobility spectrometry (HS-GC-IMS) and headspace solid-phase microextraction-gas chromatography-mass spectrometry (HS-SPME-GC-MS). Results showed that the establishment of a citrus tea flavor fingerprint based on HS-GC-IMS data can provide an effective means for the rapid identification and traceability of different citrus varieties. Moreover, 68 volatile compounds (OAV > 1) were identified by HS-SPME-GC-MS, which reflected the contribution of aroma compounds to the characteristic flavor of samples. Amongst them, the contribution of linalool with sweet flower fragrance was the highest. Odorants such as decanal, β-lonone, β-ionone, β-myrcene and D-limonene also contributed significantly to all samples. According to principal component analysis, the samples from different citrus teas were significantly separated. Visualization analysis based on Pearson correlation coefficients suggested that the correlation between key compounds was clarified. A comprehensive evaluation of the aroma of citrus tea will guide citrus tea flavor quality control and mass production.     

Sensitive determination of organic acid preservatives in juices and soft drinks treated by monolith-based stir cake sorptive extraction and liquid chromatography analysis

A simple, efficient, and sensitive method for simultaneous determination of sorbic acid (SA), benzoic acid (BA), and cinnamic acid (CA) in juices and soft drinks was developed by stir cake sorptive extraction (SCSE) coupling to high-performance liquid chromatography with diode array detection. The SCSE based on polymeric ionic liquid-based monolith (PILM) as extractive medium was used to concentrate these three organic acid preservatives. Because hydrophobic and ion-exchange interactions co-contributed to the extraction, the PILM-SCSE exhibited a high extractive capability towards analytes. To obtain optimum extraction performance, several SCSE parameters were investigated and discussed, including desorption solvent, pH value, ionic strength in the sample matrix, and the extraction and desorption time. Under the optimized extraction conditions, limits of detection of 0.16, 1.08, and 0.18 μg/L (S/N?=?3) and quantification limits of 0.52, 3.42, and 0.61 (S/N?=?10) were obtained for SA, BA, and CA, respectively. The method also showed good linearity and reproducibility, as well as advantages such as simplicity, low cost, and high feasibility. Finally, the proposed method was successfully applied to the determination of SA, BA, and CA in real juices and soft drinks, and the recoveries ranged from 63.0 to 107 %.     

Theoretical investigation of excited-state proton transfer (ESPT) for 2,5-bis(2-benzothiazolyl)hydroquinone: single or double?

ABSTRACT

In this work, the single and double proton transfer dynamic process in the first excited state of 2,5-bis(2-benzothiazolyl)hydroquinone (BBTHQ) were theoretically investigated based on the time-dependent density functional theory (TD-DFT) method. The calculations of primary bond lengths, bond angles, IR vibrational spectra and NCI analysis reveal that two intramolecular hydrogen bonds of BBTHQ are strengthened in the first excited state, which provides a driving force for excited state proton transfer. The frontier molecular orbitals (FMOs) indicate the nature of intramolecular charge transfer. In addition, the potential energy surfaces (PESs) of the ground state and first excite state were also constructed to further elucidate the mechanism of intramolecular proton transfer of BBTHQ.     

关于超曲面的切面公式及其应用

本文给出任意ｎ维超曲面上任意一点的超切面方程的简洁的统一求法，将曲面方程微分即得切面方程．此法侧重对微分本质的理解，不需死记任何公式，计算简便．本文还讨论了此方法的理论意义，分别列举了到各种类型曲面的应用．     

First order absolute moment of Meyer-König and Zeller operators and their approximation for some absolutely continuous functions

A sharp estimate is given for the first order absolute moment of Meyer-König and Zeller operators M _n . This estimate is then used to prove convergence of approximation of a class of absolutely continuous functions by the operators M _n . The condition considered here is weaker than the condition considered in a previous paper and the rate of convergence we obtain is asymptotically the best possible.     

误差扩散法设计用于惯性约束聚变驱动器的色分离光栅-光束采样光栅集成元件

针对多次曝光法制作集成衍射光学元件时存在的加工制作复杂,会引入较大的对位误差等问题,基于计算全息中的误差扩散编码原理及部分相干光成像理论,提出采用误差扩散编码方法来设计用于制作浮雕结构集成元件的编码掩模的新方法。给出了利用误差扩散法设计的色分离光栅-光束采样光栅(CSG-BSG)集成元件编码掩模,模拟计算了经部分相干成像系统后的空间像光强分布,并与理想的集成元件面形进行了比较。结果表明,校正后均方差为7.5%,体积偏差为10.2%。