全文获取类型
收费全文 | 116篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 63篇 |
晶体学 | 5篇 |
力学 | 5篇 |
数学 | 16篇 |
物理学 | 30篇 |
出版年
2021年 | 2篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2016年 | 1篇 |
2015年 | 3篇 |
2014年 | 6篇 |
2013年 | 7篇 |
2012年 | 7篇 |
2011年 | 13篇 |
2010年 | 5篇 |
2009年 | 3篇 |
2008年 | 10篇 |
2007年 | 6篇 |
2006年 | 4篇 |
2005年 | 7篇 |
2004年 | 8篇 |
2003年 | 2篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1990年 | 3篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有119条查询结果,搜索用时 46 毫秒
31.
32.
Comparison of Linear and Nonlinear Forms of Isotherm Models for Strontium Sorption on a Sodium Bentonite 总被引:2,自引:0,他引:2
Sorption on bentonite will play an important role in retarding the migration of radionuclides from a waste repository. Bentonite is characterized by low permeability, water swelling capability and excellent sorption potential for cationic radionuclides. To correctly assess the sorption potential of radionuclides on bentonite is essential for the development of predictive migration models. The sorption isotherm model is usually used to describe the sorption behavior and assess the sorption potential of radionuclides on bentonite. However, there are few studies to investigate the feasibility of isotherm models for the sorption of radionuclides on bentonite. Thus, in this study, we compared the goodness-of-fit of linear and nonlinear forms of two common isotherm models, Langmuir and Freundlich equations. The experimental sorption isotherms of strontium (Sr) on Wyoming bentonite, MX-80, were used for illustration. The results showed that the nonlinear forms of Langmuir and Freundlich isotherm models are more suitable for fitting the experimental sorption isotherms of Sr on MX-80 than are the linear forms. Thus, the nonlinear forms of isotherm models should be primarily adopted to fit experimental isotherms. On the other hand, we also found that the goodness-of-fit of Langmuir model is better than that of Freundlich model. Moreover, based on the theoretical assumptions of Langmuir isotherm model, the parameters M and K
L
represent the sorption capacity and affinity, respectively. One can use the values of M and K
L
, obtained from fitting the experimental isotherms, to assess the sorption potential of radionuclides in bentonite. Thus, we suggested that the Langmuir isotherm model is more useful for investigating the sorption behavior of radionuclides on bentonite. 相似文献
33.
Po-Hsun Lei Shun-Hsi Wang Fuh Shyang Juang Yung-Hsin Tseng Meng-Jung Chung 《Optics Communications》2010,283(9):1933-1937
In this article, we report on the effect of SiO2/Si3N4 dielectric distributed Bragg reflectors (DDBRs) for Alq3/NPB thin-film resonant cavity organic light emitting diode (RCOLED) in increasing the light output intensity and reducing the linewidth of spontaneous emission spectrum. The optimum DDBR number is found as 3 pairs. The device performance will be bad by further increasing or decreasing the number of DDBR. As compared to the conventional Alq3/NPB thin-film organic light emitting diode (OLED), the Alq3/NPB thin-film RCOLED with 3-pair DDBRs has the superior electrical and optical characteristics including a forward voltage of 6 V, a current efficiency of 3.4 cd/A, a luminance of 2715 cd/m2 under the injection current density of 1000 A/m2, and a full width at half maximum (FWHM) of 12 nm for emission spectrum over the 5-9 V bias range. These results represent that the Alq3/NPB thin-film OLED with DDBRs shows a potential as the light source for plastic optical fiber (POF) communication system. 相似文献
34.
M. Phan L. G. Horta J. N. Juang R. W. Longman 《Journal of Optimization Theory and Applications》1993,79(1):59-86
This paper presents a formulation for identification of linear multivariable systems from single or multiple sets of input-output data. The system input-output relationship is expressed in terms of an observer, which is made asymptotically stable by an embedded eigenvalue assignment procedure. The prescribed eigenvalues for the observer may be real, complex, mixed real and complex, or zero corresponding to a deadbeat observer. In this formulation, the Markov parameters of the observer are first identified from input-output data. The Markov parameters of the actual system are then recovered from those of the observer and used to realize a state space model of the system. The basic mathematical formulation is derived, and numerical examples are presented to illustrate the proposed method. 相似文献
35.
Jonq Juang 《Journal of Mathematical Analysis and Applications》2008,341(2):1055-1067
A concept related to total variation termed H1 condition was recently proposed to characterize the chaotic behavior of an interval map f by Chen, Huang and Huang [G. Chen, T. Huang, Y. Huang, Chaotic behavior of interval maps and total variations of iterates, Internat. J. Bifur. Chaos 14 (2004) 2161-2186]. In this paper, we establish connections between H1 condition, sensitivity and topological entropy for interval maps. First, we introduce a notion of restrictiveness of a piecewise-monotone continuous interval map. We then prove that H1 condition of a piecewise-monotone continuous map implies the non-restrictiveness of the map. In addition, we also show that either H1 condition or sensitivity then gives the positivity of the topological entropy of f. 相似文献
36.
37.
The Sm-modified lead titanate ceramics with a composition of (Pb(0.88-x)Sr(x)Sm(0.08))(Ti(0.98)Mn(0.02))O(3); x = 0.05-0.25 were prepared by conventional mixed-oxide method. Surface acoustic wave (SAW) properties, including phase velocity, electromechanical coupling coefficient and temperature coefficient of frequency, were measured. The experiments successfully showed that Sr additive is helpful to obtain higher phase velocity and high electromechanical coupling coefficient. The SAW properties of our samples (V(p),k(2)) are better than some commercially-made PZT and PT samples. 相似文献
38.
Mechanism of Adsorption of Dyes and Phenols from Water Using Activated Carbons Prepared from Plum Kernels 总被引:3,自引:0,他引:3
The kinetics and mechanism of adsorption of two commercial dyes (BR22, AB25), phenol, and 3-chlorophenol from water on activated carbons were studied at 30 degrees C. The activated carbons were prepared from plum kernels, and the activation temperature and time tested were in the ranges 750-900 degrees C and 1-4 h, respectively. Three simplified kinetic models including a pseudo-first-order, a pseudo-second-order, and an intraparticle diffusion model were tested. It was shown that the adsorption of both phenols could be fitted to a pseudo-second-order rate law, and that of both dyes could be fitted to an intraparticle diffusion model. Kinetic parameters were calculated and correlated with the physical properties of the adsorbents. Copyright 2000 Academic Press. 相似文献
39.
Sorption of phenols from water in column systems using surfactant-modified montmorillonite 总被引:1,自引:0,他引:1
The sorption of phenol, m-nitrophenol (m-NP), and o-cresol from water onto montmorillonite modified with cetyltrimethylammonium bromide (CTAB) in a column was studied. The sorption isotherms were fitted by the Langmuir equation. Column experiments were performed at 25 degrees C to determine the breakthrough curves at different flow rates, feed sorbate concentrations, and bed lengths. It was shown that the proposed constant-pattern wave approach with the Langmuir model could well describe the breakthrough curves. The time required when the effluent concentration reached half of the feed concentration (t(1/2)) decreased with increasing feed flow rate, but the mass transfer coefficient (KLa) increased. In addition, an increase in feed sorbate concentration led to a decrease of both values of t(1/2) and KLa. The effect of axial dispersion on breakthrough dynamics in these sorption systems was finally discussed. 相似文献
40.
The amount of adsorption of sulfate and Cu(II) from single- and binary-adsorbate systems on goethite were measured. All experiments were carried out with and without supporting electrolyte (0.01 M NaNO(3)) as a function of equilibrium pH (2 - 7), adsorbate concentration (0.21 - 1.57 mM), and temperature (15 - 35 degrees C). At a given equilibrium pH, it was shown that the adsorption isotherms of single sulfate, rather than Cu(II), could be well described by the Langmuir equation. The isosteric enthalpy of sulfate adsorption was also evaluated. In contrast to a single-adsorbate system, the adsorption of Cu(II) was enhanced and that of sulfate was inhibited in binary adsorbate systems under the conditions studied. Finally, the changes in zeta potentials of the goethite suspensions with solution pH before and after adsorption were measured, which could be macroscopically related to the amount of sulfate adsorption even in binary-adsorbate systems. 相似文献