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21.
Xiao‐Dong Pan 《Journal of Polymer Science.Polymer Physics》2004,42(13):2467-2478
For properly chosen elastomer compounds, thermorheological characterization is combined with an examination of the variation of the wet sliding friction with temperature. A conceptual argument leads to the assumption that the wet sliding friction should maximize at the energy dissipation peak associated with the dynamic softening transition at a characteristic frequency determined by the sliding speed and the effective smallest surface asperity scale. The dynamic softening transition is characterized with the peak in tan δ/G′n, where tan δ is the loss tangent, G′ is the elastic modulus, and n is a constant between 0 and 1. The William–Landel–Ferry transform is uncritically applied for extrapolating the position of the peak in tan δ/G′n at high frequencies. Even based on the criterion of tan δ, the results obtained on a concrete surface indicate that the effective smallest asperity scale is of order of 100 μm. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2467–2478, 2004 相似文献
22.
NianYuanTAN XiaoMingXIAO ZeLinLI TakekoMATSUMURA-INOUE 《中国化学快报》2004,15(6):687-690
A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra. 相似文献
23.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献
24.
Baker‘s yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently differentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products. 相似文献
25.
张(1884—1950),植物学家和生物学教育家.中国近代植物学的先驱、现代实验性植物生理学和植物生态学的奠基人.最先自编我国第一套植物学、植物形态学、植物解剖学、种子植物分类学、植物生态学和植物生理学教科书.长期从事植物学科的教学和研究工作,为我国的生物科学和教育事业的建立和发展,贡献了自己的一切知识和力量. 相似文献
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For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
28.
应用七级目测法对浙江中部地区27个夏熟作物田样点的杂草进行了优势等级调查,将所得数据转换成重要值,以杂草在27个样点中的重要值为运算指标,应用主成分分析法和图论聚类中的最小生成树法,对24种杂草的生态学相似性进行了比较,指出了长期使用单一的除草剂导致农田杂草种群迅速更迭的原因:杂草对除草剂的敏感性差异及不同杂草间的生态学特性的差异。 相似文献
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文章详细描述了航空兵机场塔台辅助指挥系统之通信分系统设计的特点与功能、硬件结构、软件设计原则以及接口通信协议等问题。该分系统设计已在航空兵塔台辅助指挥系统研究中得到应用 ,并达到了良好的控制效果。 相似文献