全文获取类型
收费全文 | 10272篇 |
免费 | 1528篇 |
国内免费 | 1287篇 |
专业分类
化学 | 7559篇 |
晶体学 | 93篇 |
力学 | 641篇 |
综合类 | 91篇 |
数学 | 1058篇 |
物理学 | 3645篇 |
出版年
2024年 | 20篇 |
2023年 | 189篇 |
2022年 | 291篇 |
2021年 | 350篇 |
2020年 | 376篇 |
2019年 | 355篇 |
2018年 | 273篇 |
2017年 | 253篇 |
2016年 | 431篇 |
2015年 | 394篇 |
2014年 | 585篇 |
2013年 | 685篇 |
2012年 | 856篇 |
2011年 | 918篇 |
2010年 | 618篇 |
2009年 | 601篇 |
2008年 | 703篇 |
2007年 | 598篇 |
2006年 | 513篇 |
2005年 | 520篇 |
2004年 | 385篇 |
2003年 | 354篇 |
2002年 | 387篇 |
2001年 | 307篇 |
2000年 | 258篇 |
1999年 | 241篇 |
1998年 | 214篇 |
1997年 | 189篇 |
1996年 | 181篇 |
1995年 | 136篇 |
1994年 | 158篇 |
1993年 | 104篇 |
1992年 | 126篇 |
1991年 | 102篇 |
1990年 | 78篇 |
1989年 | 79篇 |
1988年 | 44篇 |
1987年 | 26篇 |
1986年 | 39篇 |
1985年 | 27篇 |
1984年 | 17篇 |
1983年 | 20篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 8篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1975年 | 5篇 |
1974年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 109 毫秒
41.
Tetraalkyltin complexes, SnR4 (R = Me, Et, Pr, Bu) could react with Pt/HY at 193, 243, 273 and 333 K, respectively. The reactions occurred on the surface of the zeolite and the organotin grafted zeolites were characterized in detail. The framework and the microporous structure of the grafted Pt/HY zeolites were retained. However, the modified zeolites showed better size selectivity in the absorption of hydrocarbons. 相似文献
42.
酸糖蛋白手性柱分离6种手性化合物 总被引:3,自引:0,他引:3
通过考察缓冲液种类、浓度及其pH值对对映体在手性柱上的保留和分离行为的影响,以及流动相中加入不同种类、不同浓度的不带电荷的有机溶剂乙腈、甲醇、正丙醇、异丙醇、流动相流速和柱温对对映体分离能力的影响,优化了含碳手性中心的碱性药物苯丙哌林、酸性化合物MT-A5及MT-酸和含硫手性中心的质子泵抑制剂奥美拉唑、泮托拉唑、雷贝拉唑对映体分离条件,最佳手性分离条件为:苯丙哌林,0.05 mol/L磷酸二氢铵缓冲液(pH 3.0)-乙腈(95∶5,V/V)为流动相,流速为0.7 mL/m in,柱温为20℃;MT-A5及MT-酸,流动相为0.01 mol/L醋酸铵缓冲液(pH 5.0)-乙腈(74∶26,V/V),流速为0.9 mL/m in,柱温为20℃;泮托拉唑,流动相为10 mmol/L醋酸铵缓冲液(pH 5.5)-乙腈(93∶7,V/V),流速为0.9 mL/m in;柱温为20℃;奥美拉唑和雷贝拉唑,流动相为0.01 mol/L醋酸铵缓冲液(pH 3.0)-乙腈(95∶5,V/V),流速为0.7 mL/m in,柱温为20℃。实现了应用高效液相色谱法在α1-酸糖蛋白手性柱上对上述化合物的对映体分离,并成功用于手性药物合成中的对映体过量百分率的测定。 相似文献
43.
The growth mechanism of the peritectic η phase involving the peritectic reaction and peritectic transformation in Cu-70%Sn alloy was investigated under directional
solidification. The results show that a major growth mechanism in thickening of the peritectic η-layer is not the peritectic reaction but the peritectic transformation. The transformation temperature and isothermal time
play crucial roles in determining the volume fraction and the thickness of the peritectic η phase. With the increase of the temperature and isothermal time, the volume fraction of the peritectic η phase increases. The regressed data show that the relationship between the thickness of η phase (Δx) and the transformation temperature (T) meets the following equation In Δx=6.5−1673 1 / T. Additionally, there exists a relationship between the thickness of the η phase (Δx) and the isothermal time (t) at the 9 mm solidification distance below the peritectic reaction interface, Δx=0.72t
1/2, which is consistent with the theoretical model.
Supported by the National Science Foundation of China (Grant No. 50395102) 相似文献
44.
45.
本文报道了一种测角单晶NMR探头。该探头采用单线圃双调谐电路,工作频率在90MHz-110 MHz连续可调,可进行交叉极化大功率去耦实验。文中提出了一种简单而有效的测角装置,可使单晶绕三个互相垂直轴转动实现单晶的NMR测量。作为典型的应用例子,本文利用该探头实现了单晶DGO(2NH2CH2COOH·H2C2O4)屏蔽张量的测量。 相似文献
46.
平衡规划问题的熵函数方法及其在混合交通流中的应用 总被引:1,自引:0,他引:1
将参变极值问题的极大熵函数方法应用到求解平衡规划问题中,通过先验分布信息和Kullback熵概念,给出了平衡规划问题基于Kullback熵表示的熵函数求解方法,并将平衡规划的极大熵函数方法应用于求解混合交通平衡分配问题. 相似文献
47.
Xun Fu Danmei Wu Xiaodong Zhou Huaqiang Shi Zhengshui Hu 《Journal of nanoparticle research》2007,9(4):675-681
Hollow spherical molybdenum disulfide has been successfully synthesized via a solvothermal method using Cyanex 301 as sulfur
source and modification agent. The hollow spheres are characterized by transmission electron microscopy, scanning electron
microscopy, X-ray diffraction and Energy-Dispersive X-ray analysis. The influences of reaction conditions are also discussed
while a mechanism is proposed to explain the formation of the peculiar morphology. 相似文献
48.
Bifurcations of Invariant Tori and Subharmonic Solutions of Singularly Perturbed System 总被引:1,自引:1,他引:0
下载免费PDF全文
![点击此处可从《数学年刊B辑(英文版)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
This paper deals with bifurcations of subharmonic solutions and invariant tori generated from limit cycles in the fast dynamics for a nonautonomous singularly perturbed system. Based on Poincare map, a series of blow-up transformations and the theory of integral manifold, the conditions for the existence of invariant tori are obtained, and the saddle-node bifurcations of subharmonic solutions are studied. 相似文献
49.
S.G. Li G. Fu I. Reading S.B. Tor N.H. Loh P. Chaturvedi S.F. Yoon K. Youcef-Toumi 《Applied Physics A: Materials Science & Processing》2007,89(3):721-728
Micro powder injection molding (μPIM) is one of the potential processes for the mass production of metallic microstructures
and micro components. Here, μPIM is the miniaturization of conventional PIM, which involves four processing steps: mixing,
injection molding, debinding and sintering. This paper looks into the feasibility and effectiveness of μPIM as a key mass
production process for the fabrication of metallic micro components. For it to be an effective re-production process, it is
imperative to examine how well parts can be duplicated/fabricated from a master mold. In this work, the dimensional variation
of high-aspect-ratio micro-pillars arrays, in particular the dimensional shrinkage, global warpage, and surface roughness
at each stage of the μPIM process for a range of molding pressures, are quantified and compared in detail. The sensitivity
of the dimensional variation of the microstructures to the packing pressure is reported. The mechanism behind the dimensional
variation is analyzed.
PACS 81.20.Ev; 81.20.Hy; 81.70.Fy; 07.60.Ly; 81.05.-t 相似文献
50.
Tsow-Chang Fu 《Applied Surface Science》2006,253(3):1260-1264
Cr1−xAlxC films were deposited on high-speed steel by RF reactive magnetron sputtering. In this study, we aimed to identify the effect of the Al content on the properties of Cr1−xAlxC films. We found that Cr1−xAlxC films exhibited a fine columnar grain microstructure with some special characteristics, such as high hardness of Hv 1426, a low friction coefficient of 0.29, and a large contact angle of 90° for x = 0.18. Furthermore, an increase in Al content resulted in a decrease in film hardness and an increase in contact angle. Moreover, on annealing at 923 K, the mechanical properties of the films improved and a dense protective film of complex Cr2O3 and Al2O3 oxides was formed on the surface for better wear resistance, which will ultimately increase the lifetime of the high-speed steel substrate. 相似文献