X射线散射法测量超光滑平面

介绍了掠入射X射线散射法(GXRS法)测量超光滑表面的原理及基于商业用X射线衍射仪改造而成的实验装置。以3片不同粗糙度的硅片作为实验样品,分别应用一级矢量微扰理论和改进的Harvey-Shack理论对其散射分布进行处理,所得结果与原子力显微镜测量结果基本相符。分析了探测器接收狭缝的宽度和入射光发散度对实验结果的影响,随着探测器接收狭缝宽度和入射光发散度的减小,测量误差呈指数迅速减小。在所测量的空间频率范围内,功率谱密度（PSD）函数的误差随频率的增加而减小。     

EAST外杜瓦协同仿真技术的研究

为验证EAST(Experimental and Advanced Superconducting Tokamak)外杜瓦工程设计的可靠性,借助三维设计软件CATIA和有限元分析软件ANSYS,基于协同仿真技术对其进行了研究,结果与EAST运行过程中外杜瓦的实验数据较好的吻合,进行的研究为同类装置外杜瓦的研发提供了有益的参考。     

An efficient synthesis of 3-substituted indole derivates under ultrasound irradiation

A solvent-free procedure for the synthesis of 3-substituted indole derivates from indoles and nitroalkenes under ultrasound irradiation is described. Control experiments disclosed besides mechanical effects, namely agitation, sonochemical effects are the main forces to drive the reaction. In the method, 2-chloroethanol was used to prepare a wide variety of 3-substituted indole derivates. This procedure only need equimolar amounts of reaction substrates and can be readily scaled up.     

Contact welding study of carbon nanotube with ZnO nanowire

Study of proton beam induced welding of multiwall carbon nanotubes (MWCNTs) with ZnO nanowires (NWs) has been carried out by proton (H⁺) beam irradiation. The samples were irradiated by 70-keV proton (H⁺) ion beams at different substrate temperatures. The irradiation-induced defects in CNTs and ZnO NWs were greatly reduced at elevated temperature. The crystalline structure of ZnO NWs and MWCNTs were found to remain stable after the irradiation at 700 K. As a preparation step, a coupling of two parallel ZnO NWs with irradiation has also been demonstrated. The welding mechanisms of MWCNTs and ZnO NWs were also been suggested. These two welding processes between same and distinct nanostructures to form homo- and hetero-junctions have provided an opportunity to mass produce interconnecting one-dimensional structures used for the manufacturing of future nanowire-based electronic circuits and devices.     

Assembly,characterization, and photocatalytic activities of TiO<Subscript>2</Subscript> nanotubes/CdS quantum dots nanocomposites

The semiconductor quantum dots (QDs) can be very efficient to tune the response of photocatalyst of TiO₂ to visible light. In this study, CdS QDs formed in situ with about 8 nm have been successfully deposited onto the surfaces of TiO₂ nanotubes (TNTs) to form TNTs/CdS QDs nanocomposites by use of a simple bifunctional organic linker, thiolactic acid. The diffuse reflectance spectroscopy (DRS) spectra of as prepared samples showed that the absorption edge of the TNTs/CdS composite is extended to visible range, with absorption edge at 530 nm. The photocatalytic activity and stability of TNTs/CdS were also evaluated for the photodegradation of rhodamine B. The results showed that when TNTs/CdS QDs was used, photocatalytic degradation of RhB under visible light irradiation reached 91.6%, higher than 45.4 and 30.5% for P25 and TNTs, respectively. This study indicated that the TNTs/CdS QDs nanocomposites were superior catalysts for photodegradation under visible light irradiation compared with TNTs and P25 samples, which may find wide application as a powerful photocatalyst in environmental field.     

Systematic study on visible light collimation nanostructured slits in the metal surface

We present a systematic experimental investigation on visible light collimation by a nanostructured slit flanked with a pair of periodic array of grooves in gold thin film. A wide variety of aspects are considered, such as the polarization state, the transport path of incident light, the groove-groove spacing, the groove width and depth. Our results clearly show that the relationship between the collimation wavelength and the periodicity of the slit-groove structure accords well with the surface plasmon dispersion model proposed by previous researchers. Furthermore, the surface plasmon wave phase retardation effect induced by the surface structure is also verified via the measurement for samples with different groove widths and depths. These results indicate that the detailed geometry of the groove structure has obvious impacts on the collimation effect and the angular distribution of the diffraction light in the subwavelength plasmonic system.     

磁石的傅里叶变换红外光谱指纹图谱研究

对不同产地和批次的13个生磁石样品的红外光谱法进行分析,建立磁石的红外光谱指纹图谱,并将炮制品和生品进行分析比较.发现所有生磁石样品指纹图谱的相似度均大于0.97;磁石炮制后相似度和相关系数均降低.傅里叶变换红外光谱指纹图谱可用于商品磁石的分析与品质评价.     

发红色荧光铽配合物的合成及荧光性能的研究

以二苯甲酰甲烷(HDBM)为第一配体,邻菲罗啉(phen)和二吡啶并[3,2-a:2',3'-c]哇喔啉(dpq)为第二配体合成两种三元铽配合物,并进行元素分析、稀土络合滴定、摩尔电导率、红外光谱、紫外光谱、荧光激发和发射光谱的测定,推测化合物的组成分别为:Tb(DBM)3phen,Tb(DBM)3dpq.DBM通过氧...     

碳纳米管辐射太赫兹波的理论分析与数值验证

基于简单紧束缚方法理论,利用一维碳纳米管的量子化周期边界条件得到了碳纳米管的电子能级结构关系.并结合已报道的碳纳米管中电子与声子相互作用的实验结果,得到了碳纳米管能够辐射太赫兹波的结论.通过数值结果验证了碳纳米管在外场作用下能够产生太赫兹波,并对数值计算结果中太赫兹波的振荡现象给予合理的解释.其结果为进行碳纳米管产生太赫兹辐射的实验研究提供深入的理论基础. 关键词： 太赫兹波 碳纳米管     

铒离子注入碳化硅的射程和退火行为研究

用300—500 keV能量的铒(Er)离子注入碳化硅(6H-SiC)晶体中,利用卢瑟福背散射技术研究了剂量为5×10¹⁵ cm^-2 的Er离子注入6H-SiC晶体的平均投影射程R_p和射程离散ΔR_p,将测出的实验值和TRIM软件得到的理论模拟值进行了比较,发现R_p的实验值与理论值符合较好,ΔR_p的实验值和理论值差别大一些 关键词： 离子注入 投影射程和射程离散 退火行为 卢瑟福背散射技术