Graphitization of activated carbon under high pressures and high temperatures

Activated carbon was treated at 5.0 GPa up to 1600 ^°C and the structural evolution in the graphitization process was investigated. The graphitization temperature is reduced to 1200 ^°C at 5 GPa, as reflected by x-ray diffraction patterns. Honeycomb-like structures come into being in the high-pressure sintering temperature range of 1000–1100 ^°C and slice-like structures appear after graphitization. Raman frequency and half width drop drastically near the graphitization temperature, and the appearance of D and D′ lines indicates there are still some disorder structures in the graphitized activated carbon.     

物联网云平台ZigBee无线通信网络节点设计

随着科学技术的发展,无线通信技术不断成为当今社会的通信方面的主流发展方向;对于一种可以集所有通讯方式的优点为一体,并且可以实现远距离网络通信传输的方式成为现在通讯技术行业的主要研究方向;而文章根据一种基于ZigBee协议的无线网络通信架构进行研究,设计出一种可以满足当今通信需求的硬件平台;其中应用到ZigBee协议中的短距离传输技术和将其与SPI接口连接完成的一种通信技术手段;最后将ZigBee单片机通过USB接口与计算机相连接完成通信无线传输工作;文章中提出了这种平台设计的软件设计方案和硬件设计方案,并且通过软硬件设计,分析出其所具备的优点和未来发展能力;通过对比试验,得出这种无线传播方式有更好的传播效率和节省能源的优势。     

A horn ridge waveguide DFB laser with reduced spatial hole burning for high-speed modulation

In this paper, we propose a DFB laser with a horn ridge waveguide (HRW) to suppress the longitudinal spatial hole burning (LSHB) effect in the lasers cavity, thus to reduce the rolloff at low frequency. The simulation result shows that HRW DFB lasers could significantly suppress the LSHB effect and its modulation bandwidth is increased by 14% comparing with the conventional straight ridge waveguide (RW) DFB lasers when the normalized coupling coefficient (κL) is 3.0. The calculated eye diagrams of HRW DFB lasers under direct 25 Gbps modulation have clearer opening than that of the conventional RW DFB lasers. These superior properties are due to the suppression of the LSHB effect by the HRW structure.     

Variation of the Payne Effect in Natural Rubber Reinforced by Graft-Modified Carbon Black

Carbon black (CB) was modified by liquid grafting and used for natural rubber (NR) reinforcement. Payne effects during NR reinforcement by the graft-modified carbon black (GCB) were analyzed in this paper. The results showed a proportional relationship between filler content and the Payne effect. Rubber compounds with GCB presented weaker Payne effects than their non-modified counterparts. Qualitative analysis of the correlation between filler network structure and filler content was conducted according to the relationship between bound rubber of a rubber compound and shear modulus. The impact of the storage period on the Payne effect was further studied, and the results demonstrated that the longer the storage period of the rubber compound, the stronger the Payne effect tended to be. The mechanisms by which the Payne effects were manifested differed according to the content of the filler in the rubber.     

A tunable infrared plasmonic polarization filter with asymmetrical cross resonator

A tunable infrared plasmonic polarization filter is proposed and investigated in this paper. The filter is based on the sandwich absorption structure which consists of three layers. The top layer is an array of asymmetrical cross resonator.The middle and bottom layers are dielectric spacer and metal film respectively. By absorbing specific wavelength of the incident light perfectly, the reflection spectrum of the structure shows filter performance. The calculated results show that the absorption wavelength is strongly dependent on the length of branch of the asymmetrical cross resonator which is parallel to the light polarization and independent of the length of the vertical one. Therefore, the asymmetrical cross resonator filter structure opens the way for freely tuning the filtering wavelength for a different light polarization. We can fix a resonant wavelength(absorption wavelength) corresponding to one polarization and change the resonant wavelength for the other polarization by adjusting the corresponding branch length of the asymmetrical cross resonator, or change the two resonant wavelengths of both two polarizations at the same time.     

Orientation dependence of the electrocaloric effect of ferroelectric bilayer thin films

An analytical thermodynamic theory is applied to investigate the electrocaloric effect of ferroelectric BaTiO₃/SrTiO₃ bilayer thin films with different orientations at room temperature. Theoretical analysis indicates that the strong electrostatic coupling between the layers results in the suppression of ferroelectricity at a critical relative thickness which occurs approximately at 50%, 23%, and 12% of SrTiO₃ fraction in the (001), (110), and (111) bilayer thin films, respectively. The ferroelectric bilayer thin films are respected to have the largest electrocaloric effect at this critical relative thickness. Moreover, the electrocaloric effect strongly depends on the orientation and the (110) oriented bilayer thin films have the largest electrocaloric effect. Consequently, control of the orientation and the relative thickness of SrTiO₃ layer can be used to adjust the electrocaloric effect of ferroelectric bilayer thin films, which may provide the potential for practical application in refrigeration devices.     

Metal/semiconductor hybrids consisting of self-assembled CdS nanoparticles on Cd nanowires

We report on the synthesis and the characterisation of metal/semiconductor hybrids consisting of self-assembled CdS nanoparticles on Cd nanowires, which are grown by thermal evaporation of the mixture of CdS and Cr. The growth of the hybrids is attributed to the decomposition of CdS at high temperature and the strain relieving that arises mainly from the lattice mismatch between Cd and CdS. Temperature dependence of zero-field resistance of single nanohybrid indicates that the as-produced Cd/CdS nanohybrid undergoes a metal--semiconductor transition as a natural consequence of hybrid from metallic Cd and semiconducting CdS. The metal/semiconductor hybrid property provides a promising basis for the development of novel nanoelectronic devices.     

High temperature thermoelectric properties of highly c-axis oriented Bi₂Sr₂Co₂O_y thin films fabricated by pulsed laser deposition

High-temperature thermoelectric transport property measurements have been performed on the highly c-axis oriented Bi2Sr2Co2Oy thin films prepared by pulsed laser deposition on LaAlO3(001).Both the electric resistivity ρ and the seebeck coefficient S of the film exhibit an increasing trend with the temperature from 300 K-1000 K and reach up to 4.8 m·Ω· cm and 202 μV/K at 980 K,resulting in a power factor of 0.85 mW/mK which are comparable to those of the single crystalline samples.A small polaron hopping conduction can be responsible for the conduction mechanism of the film at high temperature.The results demonstrate that the Bi2Sr2Co2Oy thin film has potential application in high temperature thin film thermoelectric devices.     

Quantization of spin direction for solitary waves in a uniform magnetic field

It is known that there are nonlinear wave equations with localized solitary wave solutions. Some of these solitary waves are stable (with respect to a small perturbation of initial data) and have nonzero spin (nonzero intrinsic angular momentum in the center of momentum frame). In this paper we consider vector-valued solitary wave solutions to a nonlinear Klein-Gordon equation and investigate the behavior of these spinning solitary waves under the influence of an externally imposed uniform magnetic field. We find that the only stationary spinning solitary wave solutions have spin parallel or anti-parallel to the magnetic field direction.     

Structural characterization of β-V2O5 films prepared by DC reactive magnetron sputtering

β-V₂O₅ films were successfully prepared on silicon substrates by direct current (DC) reactive magnetron sputtering. X-ray diffraction (XRD), Raman spectra and field emission scan electron spectroscopy (SEM) were used to characterize the samples. Results revealed that the deposition temperature significantly influenced on the crystal structure of V₂O₅ films in the growth process. When the deposition temperature was below 500 °C, the sputtered film exhibited the α-V₂O₅ structure. However, β-V₂O₅ film was successfully obtained at 550 °C. High deposition temperature might provide V and O ions high mobility and energy in the reactive sputtering process, which induced the metastable β-V₂O₅ phase formed. The thermal stability of β-V₂O₅ film was studied by micro-Raman spectroscopy. The structure of sputtered β-V₂O₅ film was unstable under high temperature conditions (beyond 500 °C).