Compare study CaCO3 crystals on the cellulose substrate by microwave-assisted method and ultrasound agitation method

The purposes of this article were to investigate the influences of synthesis strategy on the CaCO₃ crystals on the cellulose substrate. In this study, CaCO₃ crystals were synthesized using cellulose as matrix by the microwave-assisted method and ultrasound agitation method, respectively. The CaCO₃ crystals on the cellulose substrate were characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Experimental results demonstrated that the synthesis strategy had a dramatically influences on the phase, microstructure, morphology, thermal stability, and biological activity of the CaCO₃ crystals. The pure phase of vaterite spheres with the diameter of about 320–600 nm were obtained by ultrasound agitation method, meanwhile, the mixed phases of calcite and vaterite with the diameter of about 0.82–1.24 μm were observed by microwave-assisted method. In view of experimental results, one can conclude that the ultrasound agitation method do more favors to the synthesis of CaCO₃ crystals with uniform morphology and size, compared with microwave-assisted method. Furthermore, cytotoxicity experiments indicated that the CaCO₃ crystals on the cellulose substrate had good biocompatibility and could be a candidate for the biomedical applications.     

MgnLa(n=2-6)掺杂团簇的密度泛函研究

采用密度泛函(DFT)中的B3LYP方法,选择CEP-31g基组,优化并得到了MgnLa(n=2- 6)小团簇的基态平衡结构,计算出了掺杂团簇的基态结构的平均键长、对称性、费米能级、能级间隙、束缚能、总能的二阶差分．结果表明,随着团簇原子数的增加,La原子更容易趋于团簇表面位置. 与未掺杂Mg团簇相比,La原子多采用取代其稳定基态结构的一个Mg原子形成掺杂团簇的稳定结构. 从有限的结果看,其中 Mg3La和 Mg6La的结构更为稳定．     

A THEOREM OF UNIFORMLY ASYMPTOTIC STABILITY FOR DELAY DIFFERENCE SYSTEM

In this paper, we establish a criterion of unformly asymptotic stability for finite delay difference systems in terms of two measures by employing Lyapunov functionals method.     

离散忆阻混沌系统的Simulink建模及其动力学特性分析

为拓广离散忆阻器的研究与应用,基于差分算子,构建了具有平方非线性的离散忆阻模型,并实现了Simulink仿真.仿真结果表明,设计的忆阻器满足广义忆阻定义.将得到的离散忆阻引入三维混沌映射中,设计了一种新型四维忆阻混沌映射,并建立了该混沌映射的Simulink模型.通过平衡点、分岔图、Lyapunov指数谱、复杂度、多稳态分析了系统复杂动力学特性.本文从系统建模角度出发,构建离散忆阻与离散忆阻混沌映射,进一步验证了离散忆阻的可实现性,为离散忆阻应用研究奠定了基础.     

V掺杂二维MoS_2体系气体吸附性能的第一性原理研究

以芥子气和沙林为代表的毒剂具有毒性强、扩散快的特点,是一类杀伤力强、难以防护的化学战剂,对其快速高效检测是一项具有挑战性的课题.本文基于第一性原理计算方法研究了V掺杂对二维MoS_2气敏性能影响的机理,发现V原子向二维MoS_2的掺杂过程为自发的放热反应, V原子可以稳定掺杂于二维MoS_2超胞结构中的S空位上.掺杂进入二维MoS_2体系的V原子作为施主中心向周围Mo原子给出电子,从而提高了材料的导电能力.吸附能、吸附距离和吸附过程中的电子转移计算结果表明V的掺杂提高了二维MoS_2对气体分子的吸附能力,增强了吸附质分子与基底表面的电子相互作用,从而提高了二维MoS_2的气敏性能.     

冷气喷射对直叶栅型面压力及气动损失分布影响的实验研究

提高燃气涡轮比功率，降低比油耗要通过升高涡轮入口温度和压气机压比实现，但必须对涡轮叶片实施诸如气膜冷却等保护措施。Ito和Goldstein[1]，Yamamoto[2]等分别研究了冷气喷射对在叶栅气动性能的影响。本文通过实验研究了冷气喷射对叶型型面压力和叶栅流道内气动损失的影响，并得出了一些有意义的结论。1实验装置实验在哈尔滨工业大学发动机气体动力研究中心低速风洞实验台[3]上进行。图1及表1给出了实验用叶片型线（取自一典型涡轮导向器叶型），冷气喷射孔位置及静压孔分布。叶片表面前缘、吸力面后部和压力面后部开了三列孔，每列孔…     

A Line Search SQP-type Method with Bi-object Strategy for Nonlinear Semidefinite Programming

We propose a line search exact penalty method with bi-object strategy for nonlinear semidefinite programming. At each iteration, we solve a linear semidefinite programming to test whether the linearized constraints are consistent or not. The search direction is generated by a piecewise quadratic-linear model of the exact penalty function. The penalty parameter is only related to the information of the current iterate point. The line search strategy is a penalty-free one. Global and local converg...     

Research on front-end electronics gain compensation of MCP imaging detector北大核心CSCD

基于微通道板电子倍增电荷分割型阳极的成像探测器常用于行星大气、气辉等微弱信号探测。针对探测器读出电路增益不相等导致探测器成像产生畸变的问题,利用理论分析结合MATLAB仿真揭示了不同畸变图像的形成机制,在该基础上提出了一种探测器读出电路增益补偿方法减小探测器成像畸变。通过MATLAB仿真和实验测试结果表明该文提出的方法能够有效减小由于读出电路增益不相等导致的探测器成像畸变。     

Ambient effect on optical absorption of Au nanoparticles dispersed within pores of mesoporous SiO2

A gold nanoparticles/monolithic mesoporous silica assembly was synthesized by ultrasonic irradiation of monolithic porous silica presoaked with precursor solution. Subsequent exposure to ambient air (ageing) and then drying at 120°C induce a new optical absorption peak around 470?nm (falling into the range from 460 to 475?nm) which is stable at room temperature, in addition to the normal surface plasmon resonance (SPR) of Au nanoparticles. Further drying results in the decline and disappearance of this peak, accompanied by increase of the normal SPR. If the sample, in which the new peak has disappeared due to long drying at 120°C, is exposed to the ambience once more, this peak will appear again after subsequent drying at 120°C, showing reversibility. Further experiments indicate that ambient ageing for a certain time plays a crucial role in the appearance of the new peak after subsequent drying at 120°C. Increased ageing time increases this peak. In addition, the ambient relative humidity and temperature during exposure are also important to the appearance of this peak. This peak may be associated with Au clusters with a size less than 1.5?nm. Based on the porous structure of the assembly and hydrophilicity of its pore wall, a nanodroplet formation and evaporation model is presented which can well explain all evolution behaviours of this peak. The model predicts the existence of the peak at 470?nm in the Au/silica assembly prepared by methods other than ultrasonic irradiation, which has also been confirmed by further experiments.