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11.
We exploited the slow relaxation of methyl group rotational tunneling states to perform optical hole burning inn-alkane crystals. The dye probe used was dimethyl-s-tetrazine and its perdeuterated derivative. We investigatedn-octane, perdeuteratedn-octane andn-hexane as host crystals. By comparing the experimentally observed hole-antihole splitting of the protonated and perdeuterated dye probe, all parameters, i.e. the tunneling splitting in the ground-and in the electronically excited state as well as the respective heights of the potential can be determined, assuming a threefold rotational symmetry axis. We found that matrix deuteration has a severe influence on the potential heights, which increase by a factor of two. With these parameters determined, many features of the complex relaxation behavior of the tunneling states can be qualitatively understood: We found Raman-type conversion processes inn-octane-h
18, Orbach-type processes inn-octane-d
18 and inn-hexane we found, in addition, a relaxation regime governed by a Direct process. The experimental activation energies as well as the cross-over temperatures are in satisfying agreement with current theories. 相似文献
12.
Friedrich Leisch 《Computational Statistics》2007,22(4):555-555
13.
14.
Friedrich Otto 《Semigroup Forum》2007,75(3):520-535
We consider the problem of deciding Green's relations for various types of finitely presented automatic monoids.
We establish some decidability as well as some undecidability results. 相似文献
15.
16.
Th. Friedrich I. Kath A. Moroianu U. Semmelmann 《Journal of Geometry and Physics》1997,23(3-4):259-286
A nearly parallel G2-structure on a seven-dimensional Riemannian manifold is equivalent to a spin structure with a Killing spinor. We prove general results about the automorphism group of such structures and we construct new examples. We classify all nearly parallel G2-manifolds with large symmetry group and in particular all homogeneous nearly parallel G2-structures. 相似文献
17.
The ternary system CsCl?NaCl?LaCl3 was investigated by means of differential thermal analysis and X-ray powder diffraction analysis. There exists one congruently melting compound, Cs2NaLaCl6, crystallizing with the cubic elpasolite structure. No quasi-binary section exists for the whole system, however three binaries range from the ternary compound Cs2NaLaCl6 to NaCl, CsLa2Cl7 and Cs3LaCl6 resp., dividing the system in three areas of composition: one triangle, Cs3LaCl6?Cs2NaLaCl6?CsLa2Cl7, containing additionally a compound Cs2LaCl5 below 510°C, and the two areas CsCl?NaCl?Cs2NaLaCl6?Cs3LaCl6 and Cs2NaLaCl6?NaCl?LaCl3?CsLa2Cl7, containing a mixed crystal range between LaCl3 and Na3La5Cl18. These areas could be further divided in five triangles, so that the whole system contains six Alkemade triangles. 相似文献
18.
Renate Naumann Christine Alexander-Weber Friedrich G. K. Bauche 《Analytical and bioanalytical chemistry》1994,350(3):119-121
Thermogravimetric and X-ray powder diffraction analyses revealed that the pH reference material sodium tetraborate decahydrate (“borax”) is not a stable substance but, loosing some of its water of crystallization, transforms slowly into the pentahydrate. The connected pH changes of the solutions are opposite to and larger than, those expected according to the dilution value of the decahydrate as shown by differential potentiometric measurements. The transformation rate depends on the storing time in the closed original container, the time of and after the first exposure of the material to the atmosphere, the frequency of and the relative humidity during subsequent exposures, and the temperature. The transformation reaction is not understood in detail. However, the experiments showed that sodium tetraborate decahydrate is a reliable pH reference material, whose pH is constant within ΔpH=±0.005 within at least two years after preparation, even if occasionally exposed to the atmosphere. Further work will show whether this time limit can be somewhat extended. 相似文献
19.
20.
Friedrich Weil 《Fresenius' Journal of Analytical Chemistry》1872,11(1):284
Ohne Zusammenfassung 相似文献