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排序方式: 共有390条查询结果,搜索用时 15 毫秒
81.
82.
Iodoplumbates with Tetra‐ and Penta‐coordinated Pb2+ Ions In contrast to all known iodoplumbates with octahedrally coordinated Pb2+ ions, square pyramidal geometry is observed in the iodoplumbate chains of (Pr4N)[PbI3] ( 1 ) and [Mg(dmf)6][PbI3]2 ( 2 ), whereas the isolated anions in (Ph4P)2[Pb2I6] ( 3 ) and [Bu3N–(CH2)3–NBu3][PbI4] ( 4 ) contain tetra‐coordinated lead atoms. (Pr4N)[PbI3] ( 1 ): a = 910.86(6), b = 1221.46(7), c = 1907.7(1) pm, V = 2122.5(2) · 106 pm3, space group P212121; [Mg(dmf)6][PbI3]2 ( 2 ): a = 891.24(9), b = 1025.34(7), c = 1234.82(9) pm, α = 92.938(8), β = 106.457(8), γ = 98.100(7)°, V = 1066.4(2) · 106 pm3, space group P1; (Ph4P)2[Pb2I6] ( 3 ): a = 1174.5(1), b = 722.29(7), c = 3104.8(4) pm, β = 100.50(1)°, V = 2589.8(5) · 106 pm3, space group P21/n; [Bu3N–(CH2)3–NBu3][PbI4] ( 4 ): a = 2178.3(1), b = 1008.63(5), c = 1888.3(1) pm, β = 110.003(5)°, V = 3898.6(4) · 106 pm3, space group P2/c. 相似文献
83.
Dr. Philipp Niermeier Dr. Jan-Hendrik Lamm Dr. Andreas Mix Beate Neumann Dr. Hans-Georg Stammler Prof. Dr. Norbert W. Mitzel 《ChemistryOpen》2019,8(3):304-315
α,ω-Bis(1,8-dichloroanthracen-10-yl)alkanes with (CH2)n-linker units (n=1–4) were synthesized starting from 1,8-dichloroanthracen-10(9H)-one. This was transformed into anthracenes with allyl, bromomethyl and propargyl substituents in position 10; these were converted in various C−C-bond formation reactions (plus hydrogenation), leading to two anthracene units flexibly linked by α,ω-alkandiyl groups. 1,2-Ethandiyl- and 1,3-propandiyl-linked derivatives were functionalized with ethynyl groups in positions 1, 8, 1’ and 8’, and these terminally functionalized by Me3Sn groups using Me2NSnMe3. All linked bisanthracenes were subjected to UV light induced cyclomerization and a series of 9,10 : 9’,10’-photo-cyclomers were obtained. Their thermal cycloreversion and (repeated) switchability was demonstrated. 1,3-Bis{1,8-bis[(trimethylstannyl)ethynyl]anthracen-10-yl}propane served as model compound for photo-switchable acceptor molecules and its open and closed forms were characterized by NMR and DOSY experiments. 相似文献
84.
85.
Simonato S Gröger H Möllmer J Staudt R Puls A Dreisbach F Feldmann C 《Chemical communications (Cambridge, England)》2012,48(6):844-846
The CO(2) uptake on nanoscale AlO(OH) hollow spheres (260 mg g(-1)) as a new material is comparable to that on many metal-organic frameworks although their specific surface area is much lower (530 m(2) g(?1)versus 1500-6000 m(2) g(?1)). Suited temperature-pressure cycles allow for reversible storage and separation of CO(2) while the CO(2) uptake is 4.3-times higher as compared to N(2). 相似文献
86.
Lucas Wickemeyer Niklas Aders Andreas Mix Beate Neumann Hans-Georg Stammler Jorge J. Cabrera-Trujillo Israel Fernndez Norbert W. Mitzel 《Chemical science》2022,13(27):8088
The reaction of tBu2P(O)H with Bis2AlH (Bis = CH(SiMe3)2) afforded the adduct tBu2P(H)–O–Al(H)Bis2 (3). It slowly releases H2 to form the first oxygen-bridged geminal Al/P frustrated Lewis pair tBu2P–O–AlBis2. It is capable of reversibly binding molecular hydrogen to afford 3, shown by NMR and H/D scrambling experiments, and forms a 1,2-adduct with CO2. Importantly, the H2 adduct 3 reduces CO2 in a stoichiometric reaction leading to the formic acid adduct tBu2P(H)–O–Al(CO2H)Bis2. The formation of the different species was explored by density functional theory calculations which provide support for the experimental results. All products were characterized by NMR spectroscopy as well as X-ray diffraction experiments and elemental analyses.Addition vs. reduction: the geminal FLP Bis2Al–O–PtBu2 can reversibly bind molecular hydrogen, it reacts with CO2 to give an adduct, and its hydrogen adduct reduces CO2 to an adduct of formic acid. 相似文献
87.
88.
89.
Frank F. Bier Eva Ehrentreich-Förster Christian G. Bauer Frieder W. Scheller 《Analytical and bioanalytical chemistry》1996,354(7-8):861-865
The amplification cycle consisting of NADH independent oligosaccharide dehydrogenase (ODH) and laccase has been recently reported to be highly sensitive to several catecholamines and p-aminophenol. A competitive immunoassay for 2,4-dichlorophenoxyacetic acid has been developed by combining this amplification cycle with β-galactosidase as enzyme label resulting in p-aminophenol as product. The combination of enzymatic amplification cycles with a competitive immunoassay yields a highly sensitive measurement of 2,4-dichlorophenoxyacetic acid. Using a monoclonal antibody the linear range of the assay was between 0.02 and 100 ng/l and the c50 was found at 0.2 ng/l; the detection limit was at 5 pg/l (25 fmol/l) corresponding to 5 amol. 相似文献
90.
Vojinović K Losehand U Mitzel NW 《Dalton transactions (Cambridge, England : 2003)》2004,(16):2578-2581
The crystal structures of (H(3)C)(2)O, H(2)SiCl(2) and an adduct of these were determined by low-temperature X-ray crystallography on crystals grown in situ at low temperatures on a diffractometer. The adduct of (H(3)C)(2)O and H(2)SiCl(2) has the composition [(H(3)C)(2)O.H(2)SiCl(2)](2) and contains a four-membered Si(2)O(2) ring, with the Cl atoms pointing to the outside and the Si-H functions pointing to the inner side of the ring. The Si(2)O(2) ring has two longer and two shorter SiO bonds and thus deviates from a square. Quantum chemical calculations give a geometry for [(H(3)C)(2)O.H(2)SiCl(2)](2) which has D(2h) symmetry and allow to obtain an estimate for the adduct formation energies, which are -13.4 kJ mol(-1) for the formation of the mono adduct [(H(3)C)(2)O + H(2)SiCl(2)-->(H(3)C)(2)O.H(2)SiCl(2)], -14.4 kJ mol(-1) for the dimerization of two mono adducts [(H(3)C)(2)O.H(2)SiCl(2)-->[(H(3)C)(2)O.H(2)SiCl(2)](2)] and -41.2 kJ mol(-1) for the reaction 2 (H(3)C)(2)O + 2 H(2)SiCl(2)-->[(H(3)C)(2)O.H(2)SiCl(2)](2). The results are used to rationalize the strongly reduced reactivity of H(2)SiCl(2) towards nucleophilic substitution reactions in (H(3)C)(2)O at low temperatures. 相似文献