Chemical ionization and electron impact mass spectra of thiosulfinates,thiosulfonates and sulfinyl sulfones

The chemical ionization and electron impact mass spectra of some thiosulfinates, thiosulfonates and sulfinyl sulfones have been studied. The electron impact mass spectra of four of the six thiosulfonates show molecular ions of less than 1%. Inconclusive evidence was obtained for sulfenyl sulfinate type intermediates in the electron impact spectra of thiosulfonates. The electron impact spectra of thiosulfonates were similar to those of thiosulfonates. The chemical ionization (isobutane) mass spectra of thiosulfinates and thiosulfonates generally show protonated molecular ions [MH]⁺ as base peaks and [MH+1]⁺ and [MH+2]⁺ peaks.     

A weak Grothendieck compactness principle

The Grothendieck compactness principle states that every norm compact subset of a Banach space is contained in the closed convex hull of a norm null sequence. In this article, an analogue of the Grothendieck compactness principle is considered when the norm topology of a Banach space is replaced by its weak topology. It is shown that every weakly compact subset of a Banach space is contained in the closed convex hull of a weakly null sequence if and only if the Banach space has the Schur property.     

Intersections of t-reguli,rational curves,and orthogonal Latin squares

The celebrated net-embedding theorem of R.H. Bruck asserts that a net with a large number of parallel classes, i.e., a net with small deficiency, can be embedded in an affine plane. The only known class of examples of unembeddable nets of small deficiency has been constructed by geometry, using partial spreads of PG(3, q). In this note we attempt to generalize that discussion to PG(n, q), with particular emphasis on the case n=5.     

One Cubic Diophantine Inequality

Suppose that G(x) is a form, or homogeneous polynomial, of odddegree d in s variables, with real coefficients. Schmidt [15]has shown that there exists a positive integer s₀(d), whichdepends only on the degree d, so that if s s₀(d), then thereis an x Z^s\{0} satisfying the inequality |G(x)|<1. (1) In other words, if there are enough variables, in terms of thedegree only, then there is a nontrivial solution to (1). Lets₀(d) be the minimum integer with the above property. In thecourse of proving this important result, Schmidt did not explicitlygive upper bounds for s₀(d). His methods do indicate how todo so, although not very efficiently. However, in fact muchearlier, Pitman [13] provided explicit bounds in the case whenG is a cubic. We consider a general cubic form F(x) with realcoefficients, in s variables, and look at the inequality |F(x)|<1. (2) Specifically, Pitman showed that if s(1314)²⁵⁶–1, (3) then inequality (2) is non-trivially soluble in integers. Wepresent the following improvement of this bound.     

Enhancing the Success of African-American Students in the Sciences: Freshman Year Outcomes

The Meyerhoff Program is an intensive, multicomponent program focused on enhancing the success of talented African-American students in science and engineering at a predominantly white, medium-sized university. The program components, taken together, address the four primary factors emphasized in the research literature as limiting minority student performance and persistence in science: knowledge and skills, motivation and support, monitoring and advising, and academic and social integration. Outcome analyses indicated that the first three cohorts of Meyerhoff students (total N=69) achieved an overall GPA (mean=3.5) significantly greater than that of an African-American historical comparison sample (mean=2.8) of comparably talented science students at the university. This difference was even greater for first year science GPA (means of 3.4 and 2.4, respectively), and in specific science and mathematics courses. Observational and questionnaire data indicated that the Meyerhoff program study groups, peerbased community, financial scholarships, summer bridge program and staff appear to be especially important contributors to student success. Implications of the findings for enhancing the success of African-American and other underrepresented populations in science are discussed.     

Correlations between eigenvalues of a random matrix

Exact analytical expressions are found for the joint probability distribution functions ofn eigenvalues belonging to a random Hermitian matrix of orderN, wheren is any integer andN. The distribution functions, like those obtained earlier forn=2, involve only trigonometrical functions of the eigenvalue differences.