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51.
52.
M. Abdel-Bary K. -Th. Brinkmann H. Clement E. Doroshkevich S. Dshemuchadse A. Erhardt W. Eyrich H. Freiesleben A. Gillitzer R. Jäkel L. Karsch K. Kilian E. Kuhlmann K. Möller H. P. Morsch L. Naumann N. Paul C. Pizzolotto J. Ritman E. Roderburg P. Schönmeier W. Schroeder M. Schulte-Wissermann G. Y. Sun A. Teufel A. Ucar G. J. Wagner M. Wagner P. Wintz P. Wüstner P. Zupranski 《The European Physical Journal A - Hadrons and Nuclei》2006,29(3):353-361
The reaction
has been studied in a kinematically complete experiment at a single beam momentum
GeV/c (T = 759MeV). All four ejectiles have been detected in the large-acceptance time-of-flight spectrometer COSY-TOF. We analyzed
the data along the lines of the spectator model as a means to isolate the quasi-free
reaction. The spectator proton was identified by its momentum and flight direction thus yielding access to the associated
Fermi motion of the bound neutron. A comparison is carried out with Monte Carlo simulations based on two different parameterizations
of the deuteron wave function. Up to a Fermi momentum of roughly 150MeV/c no significant deviations between experimental and simulated data of various observables were found from which we conclude
that the deuteron can indeed be taken as a valid substitute for the neutron. 相似文献
53.
In this article, we describe an algorithm to find the optimal communication network for the new GPS III satellite system. Finding a possible network will be translated to a maximum clique problem and an efficient algorithm for finding all maximum cliques under these special circumstances is described. 相似文献
54.
Mussenbrock T Brinkmann RP Lieberman MA Lichtenberg AJ Kawamura E 《Physical review letters》2008,101(8):085004
In low-pressure capacitive radio frequency discharges, two mechanisms of electron heating are dominant: (i) Ohmic heating due to collisions of electrons with neutrals of the background gas and (ii) stochastic heating due to momentum transfer from the oscillating boundary sheath. In this work we show by means of a nonlinear global model that the self-excitation of the plasma series resonance which arises in asymmetric capacitive discharges due to nonlinear interaction of plasma bulk and sheath significantly affects both Ohmic heating and stochastic heating. We observe that the series resonance effect increases the dissipation by factors of 2-5. We conclude that the nonlinear plasma dynamics should be taken into account in order to describe quantitatively correct electron heating in asymmetric capacitive radio frequency discharges. 相似文献
55.
We report a simple and highly stereocontrolled strategy toward the total synthesis of isoprostanes based on a bicyclic alpha,beta-epoxy ketone intermediate 6. Bicyclo[3.3.0]octene scaffold permitted stereodirection of reagents allowing stereoselective epoxidation, diastereoselective ketone reduction, and regioselective epoxide opening otherwise not accessible with a simple cyclopentene framework. 相似文献
56.
Jelan Kuhn Kenji Yajima Toshihiro Tomita Joachim Gross Freek Kapteijn 《Journal of membrane science》2008
The all silica DDR membrane turns out to be well suited to separate water from organic solvents under pervaporation conditions, despite its hydrophobic character. All-silica zeolites are chemically and hydrothermally more stable than aluminum containing ones and are therefore preferred for membrane applications, including for dehydration, even though these type of membranes are hydrophobic. Permeation of water, ethanol and methanol through an all-silica DDR membrane has been measured at temperatures ranging from 344 to 398 K. The hydrophobic membrane shows high water fluxes (up to 20 kg m−2 h−1). The pure water permeance is insensitive to temperature and is well described assuming weak adsorption. Excellent performance in dewatering ethanol (N=2 kg m−2 h−1and αw=1500 at 373 K and xw=0.18) is observed and the membrane is also able to selectively remove water from methanol (N=5 kg m−2 h−1 and αw=9). Water could also be removed from methanol/ethanol/water (αwater/EtOH=1500, αMeOH/EtOH=70 at 373 K) mixtures, even at water feed concentrations below 1.5 mol%. 相似文献
57.
De Souza EJ Brinkmann M Mohrdieck C Arzt E 《Langmuir : the ACS journal of surfaces and colloids》2008,24(16):8813-8820
Capillary forces can significantly contribute to the adhesion of biological and artificial micro- and nanoscale objects. In this paper, we study numerically the effect of meniscus size on the force between two homogeneous flat plates for different contact angles. The force distance curves show excellent quantitative agreement with previous investigations. The results for n menisci of equal total liquid volume reveal interesting scaling properties and an unexpected maximum force for moderately hydrophilic surfaces (i.e., contact angles around 70 degrees ). Further, we calculate the minimum solid-liquid area for multiple bridges, the cohesive stress (i.e., force per area) between the plates, and the work required to separate them. The results are presented in two-dimensional maps, which may be useful in the understanding of biological attachment structures and in the design of artificial contact systems. 相似文献
58.
Hoeben FJ Heller I Albracht SP Dekker C Lemay SG Heering HA 《Langmuir : the ACS journal of surfaces and colloids》2008,24(11):5925-5931
We report on the use of polymyxin (PM), a cyclic cationic lipodecapeptide, as an electrode modifier for studying protein film voltammetry (PFV) on Au and single-walled carbon nanotube (SWNT) electrodes. Pretreating the electrodes with PM allows for the subsequent immobilization of an active submonolayer of [NiFe]-hydrogenase from Allochromatium vinosum ( Av H2ase). Probed by cyclic voltammetry (CV), the adsorbed enzyme exhibits characteristic electrocatalytic behavior that is stable for several hours under continuous potential cycling. An unexpected feature of the immobilization procedure is that the presence of chloride ions is a prerequisite for obtaining electrocatalytic activity. Atomic force microscopy (AFM) relates the observed catalytic activity to enzymatic adsorption at the PM/Au(111) surface, and a combination of concentration-dependent CV and AFM is used to investigate the interaction between the enzyme and the PM layer. 相似文献
59.
Hoeben FJ Zhang J Lee CC Pouderoijen MJ Wolffs M Würthner F Schenning AP Meijer EW De Feyter S 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(28):8579-8589
A melamine derivative has been covalently equipped with two oligo(para-phenylenevinylene) (OPV) chromophores. This procedure yields a bifunctional molecule with two hydrogen-bonding arrays available for complementary binding to perylene bisimide derivatives. Depending on the solvent, hydrogen-bonded trimers, tetramers, and dimers on a graphite surface are observed for pure OPV-melamine by using scanning tunneling microscopy (STM). Upon the addition of perylene bisimide, linear tapes of perylene bisimide, 12-membered rosettes that consist of alternating hydrogen-bonded OPV-melamine and perylene bisimide moieties are visualized. These results provide direct evidence for the possible modes of hydrogen bonding within a supramolecular co-assembly in solution. Subsequently, the optical properties of pure OPV-melamine and co-assemblies with a perylene bisimide derivative were characterized in solution. In an apolar solvent, OPV-melamine self-assembles into chiral superstructures. Disassembly into molecularly dissolved species is reversibly controlled by concentration and temperature. Complementary hydrogen bonding to a perylene bisimide derivative in an apolar solvent yields multicomponent, pi-stacked dye assemblies of enhanced stability that are characterized by fluorescence quenching of the constituent chromophores. Titration experiments reveal that a mixture of hydrogen-bonded oligomers is present in solution, rather than a single discrete assembly. The solution experiments are consistent with the STM results, which revealed various supramolecular assemblies. Our system is likely not to be optimally programmed to obtain a discrete co-assembled structure in quantitative yield. 相似文献
60.
The asymmetric rhodium-catalysed 1,4-addition of alkenylzirconium reagents to 2-cyclohexenone can be useful in the synthesis of 3-alkenyl-2-methylcyclohexanones, provided that formaldehyde is used in trapping the intermediate zirconium enolates. In this manner a four-step sequence leading to the two epimeric 3-hexenyl-2-methylcyclohexanones in enantiomeric form was developed. 相似文献