An amino-modified Zr-terephthalate metal-organic framework as an acid-base catalyst for cross-aldol condensation

After controlled pretreatment, some Zr-terephthalate metal-organic frameworks are highly selective catalysts for the cross-aldol condensation between benzaldehyde and heptanal. The proximity of Lewis acid and base sites in the amino-functionalized UiO-66(NH(2)) material further raises the reaction yields.     

Lewis acid double metal cyanide catalysts for hydroamination of phenylacetylene

Double metal cyanides (DMCs) are highly active recyclable heterogeneous catalysts for hydroamination of phenylacetylene with 4-isopropylaniline. The best hydroamination yields are obtained with Zn-Co DMCs, especially if the particle size is decreased by a reverse emulsion synthesis technique.     

Addendum to “A definable nonstandard enlargement”

?o?'s theorem for bounded D ‐ultrapowers, D being the ultrafilter introduced by Kanovei and Shelah [4], is established. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Diffraction of light by supersonic waves: The solution of the raman-nath equations

The partial differential equation associated with the system of difference-differential equations of Raman-Nath for the amplitudes of the diffracted light-waves is solved exactly by the method of the separation of the variables. The solution is presented as a double infinite series containing the Fourier coefficients of the even periodic Mathieu functions with periodπ and the corresponding eigenvalues. Considering this solution as a Laurent series in one of the variables, the Laurent coefficients immediately give the exact expressions for the amplitudes of the diffracted light-waves, from which the formulae for the intensities are calculated. The connection between the Raman-Nath method and Brillouin’s Mathieu function method has thus been achieved.     

Ionothermal Synthesis of Imide-Linked Covalent Organic Frameworks

Covalent organic frameworks (COFs) are an extensively studied class of porous materials, which distinguish themselves from other porous polymers in their crystallinity and high degree of modularity, enabling a wide range of applications. COFs are most commonly synthesized solvothermally, which is often a time-consuming process and restricted to well-soluble precursor molecules. Synthesis of polyimide-linked COFs (PI-COFs) is further complicated by the poor reversibility of the ring-closing reaction under solvothermal conditions. Herein, we report the ionothermal synthesis of crystalline and porous PI-COFs in zinc chloride and eutectic salt mixtures. This synthesis does not require soluble precursors and the reaction time is significantly reduced as compared to standard solvothermal synthesis methods. In addition to applying the synthesis to previously reported imide COFs, a new perylene-based COF was also synthesized, which could not be obtained by the classical solvothermal route. In situ high-temperature XRPD analysis hints to the formation of precursor–salt adducts as crystalline intermediates, which then react with each other to form the COF.     

Annelated Cyclobutanes by Fe‐Catalyzed Cycloisomerization of Enyne Acetates

Cationic Fe complexes of the general type [(Ph₃P)₂Fe(CO)(NO)]X (X=BF₄, BAr^F₄) catalyze the redox‐neutral cycloisomerization of 1,6‐ and 1,7‐enyneacetates to afford bicyclic cyclobutanes under mild conditions in good yields and diastereoselectivities.