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The cationic ruthenium complexes [(η5-C5H5)Ru(Ph2PCH2CH2PPh2)L]PF6 (L=olefin, CO, pyridine or acetonitrile) have been prepared by treatment of (η5-C5H5)Ru(Ph2PCH2CH2PPh2)Cl with L and NH4PF6 in methanol of 20°C. 相似文献
23.
Wilson MH Ledwaba LP Field JS McMillin DR 《Dalton transactions (Cambridge, England : 2003)》2005,(16):2754-2759
As part of an effort to develop new lumaphors involving late transition metal ions, this report describes the synthesis and characterization of the first platinum(II) derivatives containing 2,2':6',2'-terpyridine (trpy) and cyanide as co-ligands. According to existing models, including cyanide in the coordination sphere should raise the energies and minimize the influence of short-lived d-d excited states that otherwise compromise the excited-state lifetime. Both [Pt(trpy)(CN)]+ and the 4'-cyano-2,2':6',2'-terpyridine analogue [Pt(CN-T)(CN)]+ are emissive in dichloromethane solution, but the signals are weak. Part of the problem is that the d-pi* charge-transfer excited states also rise in energy, so that the emission actually originates from a (3)pi-pi* state with a relatively low radiative rate constant. However, another member of the series, the 4'-dimethylamino-2,2':6',2'-terpyridine (dma-T) derivative [Pt(dma-T)(CN)]+, proves to be a very promising platform with an emission quantum yield of phi= 0.26 and an excited-state lifetime of tau = 22 micros in room-temperature, deoxygenated dichloromethane solution. In the dma-T complex the electron-rich dimethylamino substituent provides the basis for an emissive, but largely ligand-based, charge-transfer excited state. The orbital parentage is such that the photoluminescence persists in donating solvents like dimethylformamide, which ordinarily quenches d-pi* excited states in complexes of this type. 相似文献
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Cron GO Wallace JC Stevens WD Fortin T Pappas BA Wilkins RC Kelcz F Santyr GE 《Magnetic resonance imaging》2005,23(5):619-627
The arterial input function (AIF) is important for quantitative MR imaging perfusion experiments employing Gd contrast agents. This study compared the accuracy of T(2)*-weighted magnitude and phase imaging for noninvasive measurement of the AIF in the rat aorta. Twenty-eight in vivo experiments were performed involving simultaneous arterial blood sampling and MR imaging following Gd injection. In vitro experiments were also performed to confirm the in vivo results. At 1.89 T and TE=3 ms, the relationship between changes in 1/T(2)* in blood (estimated from MR signal magnitude) and Gd concentration ([Gd]) was measured to be approximately 19 s(-1) mM(-1), while that between phase and [Gd] was approximately 0.19 rad mM(-1). Both of these values are consistent with previously published results. The in vivo phase data had approximately half as much scatter with respect to [Gd] than the in vivo magnitude data (r(2)=.34 vs. r(2)=.17, respectively). This is likely due to the fact that the estimated change in 1/T(2)* is more sensitive than the phase to a variety of factors such as partial volume effects and T(1) weighting. Therefore, this study indicates that phase imaging may be a preferred method for measuring the AIF in the rat aorta compared to T(2)*-weighted magnitude imaging. 相似文献
26.
Aaron McCulloch Lindsey Bennie Jonathan A. Coulter Helen O. McCarthy Brendan Dromey David R. Grimes Paul Quinn Balder Villagomez‐Bernabe Frederick Currell 《Particle & Particle Systems Characterization》2019,36(9)
Studies into the cell nucleus' incorporation of gold nanoparticles (AuNPs) are often limited by ambiguities arising from conventional imaging techniques. Indeed, it is suggested that to date there is no unambiguous imaging evidence for such uptake in whole cells, particularly at the single nanoparticle level. This shortcoming in understanding exists despite the nucleus being the most important subcellular compartment in eukaryotes and gold being the most commonly used metal nanoparticle in medical applications. Here, dual‐angle X‐ray flouresence is used to show individually resolved nanoparticles within the cell nucleus, finding them to be well separated and 79% of the intranuclear population to be monodispersed. These findings have important implications for nanomedicine, illustrated here through a specific exemplar of the predicted enhancement of radiation effects arising from the observed AuNPs, finding intranuclear dose enhancements spanning nearly five orders of magnitude. 相似文献
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Richard A. Gottscho J. Brooke Koffend Robert W. Field 《Journal of Molecular Spectroscopy》1980,82(2):310-338
Optical-optical double-resonance (OODR) induced photoluminescence into the lowest excited electronic states of BaO—a3Σ+, A1Σ+, b3Π, and —from C1Σ+ is described. These low-lying states are deperturbed to obtain spectroscopic constants and potential energy curves:
16 596(3) | 16 807.345(10) | 17 502.6(10) | 17 619.7(2) | |
469.0(7) | 499.620(19) | 447.62(8) | 447.95(22) | |
1.48(4) | 1.716(8) | 2.287(12) | 2.139(8) | |
2.14(9) | 1.02(3) | |||
0.2594(5) | 0.2583908(26) | 0.22426(16) | 0.22385(16) | |
1.44(5) | 1.111(3) | 1.18(4) | 1.15(4) | |
7.0(7) | ?4.0(21) | |||
2.1294(20) | 2.133512(11) | 2.2901(8) | 2.2922(8) |