Synthese de bases de mannich acetyleniques cycliques

Terminal acetylenes can be converted in excellent yields into Mannich bases by reacting them with gem-aminoethers instead of formaldehyde and a secondary amine. This provides a possibility of preparing cyclic aminoacetylenes from w-acetylenic secondary amines, via the derived gem-aminoethers, using high dilution technique.     

Angular momentum transfer and spin dealignment mechanisms in damped nuclear reactions Ar+Bi and Ni+Pb

The angular momentum transferred to fragment spins has been studied in the damped nuclear reactions Ar+Bi at 255 MeV and 295 MeV and Ni+Pb at 435 MeV from measurement of the angular distribution of the fission fragments of the heavy-recoil nucleus in coincidence with the projectile-like fragment. The heavy-fragment spin is strongly aligned along the normal to the reaction plane and the rigid-rotation limit of the dinuclear system is attained. The dealignment mechanisms produce spin components mainly located in a plane approximately perpendicular to the heavy-recoil lab direction. They are well described by a dynamical model based on the nucleon exchange between the two ions during the collision. The spin-component fluctuations reach high values. In the heavy-recoil direction, these fluctuations are increasing with the total kinetic energy loss and the charge transfer from the projectile to the target. The spin values extracted from both the angular distributions and the fission probabilities are seen to be compatible.     

Une nouvelle voie d’acces aux indoles par condensation ylure-amide

Abstract-o-Acylaminobenzylidenephosphoranes lead to indoles in good yield by an intramolecular Wittig reaction with the amide carbonyl group. Mechanistic aspects are discussed. A general method is described for the synthesis of indoles from o-nitrobenzyl bromides and o-aminobenzyl alcohols.     

关于Thue方程的解数

设ｍ是正整数，ｆ（Ｘ，Ｙ）＝ａ０Ｘｎ＋ａ１Ｘ（ｎ－１）Ｙ＋．．．＋ａｎＹｎ∈Ｚ［Ｘ，Ｙ］是Ｑ上不可约化的叫ｎ（ｎ≥３）次齐次多项式。本文证明了：当ｇｃｄ（ｍ，ａ０）＝１，ｎ≥４００且ｍ≥１０（３５）时，方程｜ｆ（ｘ，ｙ）｜＝ｍ，ｘ，ｙ∈ｚ，ｇｃｄ（ｘ，ｙ）＝１，至多有６ｎｖ（ｍ）组解（ｘ，ｙ），其中ｖ（ｍ）是同余式Ｆ（ｚ）＝ｆ（ｚ，１）≡０（ｍｏｄｍ）的解数。特别是当ｇｃｄ（ｍ，ＤＦ）＝１时，该方程至多有６ｎ（ω（ｍ）＋１）组解（ｘ，ｙ），其中ＤＦ是多项式Ｆ的判别式，ω（ｍ）是ｍ的不同素因数的个数．     

High-Resolution Infrared Spectroscopy of Methyl Isocyanide: The ν3, ν6, and ν7 + ν8 Bands

The vibration-rotation spectrum of methyl isocyanide (CH₃NC) has been recorded with the aid of a high-resolution Fourier transform spectrometer in the region 1370 to 1560 cm⁻¹ containing the perpendicular band of the fundamental vibration ν₆ (species E), the weaker parallel band of the ν₃ (A₁) fundamental, and the perpendicular combination band ν₇ + ν₈ (E) enhanced by Fermi resonance with ν₆. Sixteen hundred seventy well-resolved lines were assigned to 15 subbands of ν₆, 6 subbands of ν₃, and 3 subbands of ν⁻₇ + ν⁻₈. A strong x, y-Coriolis resonance between ν₃ and ν₆ and Fermi resonance between ν^±₆ and the E component ν₇ + ν₈, as well as between ν₃ and the A_1,2 components ν^±₇ + ν₈, greatly affects the spectrum. Additional weaker anharmonic interaction of ν₆ with the ν₄ + 2ν²₈ combination and higher-order rotational interactions connecting the various states were also detected in the spectrum. All of these interactions have been incorporated into a 9 × 9 Hamiltonian matrix used for modeling the upper states of the observed transitions. A set of spectroscopic constants is reported for the upper states of the bands ν₃, ν₆, and ν₇ + ν₈ and for ν₄ + 2ν²₈ which reproduces the observed lines with an overall standard deviation of 0.0012 cm⁻¹.     

Etude des aldimines lithiees: II. Preparation d'aldehydes a groupement halogenovinylique. Application a la synthese d'oxo-3 cyclopentenes et d'aldehydes γ acetyleniques

The condensation of metallated aldimines, prepared from activated lithium dialkylamides, with different dihalogenoalkenes gives aldehydes with a halogenovinylic group. Acidic hydrolysis of these aldehydes leads directly to cyclopentenones. When treated with an excess of activated amide, halogenovinylic aldimines give γ-acetylenic aldehydes.     

Electronic structure of Chevrel Phases: Emphasis on the part played by the cluster twisting angle through a LCAO-EHT tight binding study

The electronic structure of PbMo₆S₈ has been investigated using the so-called EHT-tight-binding method. An idealized cubic and an experimental distorted geometry are used, with standard atomic orbital parameters and diagonal H-matrix elements. A full band structure is presented in the idealized case. In both cases, the density of state curves computed using an integration over the Brillouin zone are also presented. The results show the importance of the twisting angle on the electronic structure near the Fermi level.