57Fe Mössbauer Spectroscopy Study of LaFe1−x Co x O3 (x=0 and 0.5) Formed by Mechanical Milling

Hyperfine Interactions - Perovskite-related phases of the type LaFe1?x Co x O3 (x=0 and 0.5) have been synthesised by milling techniques. The materials are of smaller particle size and more...     

Differentiation of chiral phosphorus enantiomers by P and H NMR spectroscopy using amino acid derivatives as chemical solvating agents

The ability of commercially available amino acid derivatives, especially Fmoc-Trp(Boc)-OH, to differentiate enantiomers of chiral phosphonates, phosphinates, phosphates, phosphine oxides, and phosphonamidates is demonstrated with (31)P, (13)C, and (1)H NMR spectroscopy. The chiral differentiation provided a rapid and convenient method for measuring the enantiomeric purity of these phosphorus compounds.     

Half-explicit Runge-Kutta methods for semi-explicit differential-algebraic equations of index 1

Summary For the numerical solution of non-stiff semi-explicit differentialalgebraic equations (DAEs) of index 1 half-explicit Runge-Kutta methods (HERK) are considered that combine an explicit Runge-Kutta method for the differential part with a simplified Newton method for the (approximate) solution of the algebraic part of the DAE. Two principles for the choice of the initial guesses and the number of Newton steps at each stage are given that allow to construct HERK of the same order as the underlying explicit Runge-Kutta method. Numerical tests illustrate the efficiency of these methods.     

Construction of solutions with exactly k blow-up points for the Schrödinger equation with critical nonlinearity

We consider the nonlinear Schrödinger equation: (1) $${{i\partial u} \mathord{\left/ {\vphantom {{i\partial u} {\partial t}}} \right. \kern-\nulldelimiterspace} {\partial t}} = - \Delta u - \left| u \right|^{{4 \mathord{\left/ {\vphantom {4 N}} \right. \kern-\nulldelimiterspace} N}} uandu\left( {0,.} \right) = \varphi \left( . \right),$$ whereu:[0,T)×? ^N →?. For any given pointsx ₁,x ₂,...,x _k in ? ^N , we construct a solution of Eq. (1),u(t), which blows up in a finite timeT at exactlyx ₁,x ₂,...,x _k . In addition, we describe the precise behavior of the solutionu(t) whent→T, at the blow-up points {x ₁,x ₂,...,x _k } and in ? ^N ?{x ₁,x ₂,...,x _k }.