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91.
R.J. Van De Nesse G.Ph. Hoornweg C. Gooijer U.A.Th. Brinkman N.H. Velthorst 《Analytica chimica acta》1989
Laser-induced fluorescence (LIF) detection in conventional-size column liquid chromatography is achieved at 257 nm with a frequency-doubled argon-ion laser. Short-wavelength excitation offers two important advantages: firstly, a wide variety of analytes can be excited, and secondly, the Raman scatter of the eluent does not interfere with the fluorescence of the analytes. A standard mixture of polynuclear aromatic hydrocarbons was studied, both with LIF detection and with a commercially available sensitive conventional fluorescence detector. The improvement in the detection limits ranges from about a factory of 4 to 30; the LIF detection limits are typically at the 50 ng l?1 level, which corresponds to an injected amount of 0.5 pg. 相似文献
92.
Thérèse Dupuis 《Mikrochimica acta》1967,55(3):461-464
Résumé Dans le spectre d'absorption infrarouge de l'iodatochromate de potassium K[(CrO3)(IO3)], on peut identifier la présence de bandes de vibration de valence de ponts Cr-0-I à 508 et680 cm–1.
Summary The infrared absorption spectrum of potassium iodatochromate K(CrO3)(IO3) contains vibration bands of the valence bridges Cr-O-I at 508 and 680 cm–1.
Zusammenfassung Im Infrarot-Absorptionsspektrum des Kaliumjodatochromats lassen sich Banden der Valenzschwingungen der Atomgruppe Or-O-J bei 508 und 680 cm–1 nachweisen.相似文献
93.
M. De Bruin P. Bode H. Th. Wolterbeek 《Journal of Radioanalytical and Nuclear Chemistry》1987,110(2):365-372
Two examples are given to illustrate how modern experimental techniques may extend the scope of possibilities of radiotracer applications. The first example refers to the use of a Ge-detector -ray spectrometer to measure the transport in plants of 15 elements simultaneously. The second example presented is an in-vivo study of the binding of Cd-ions in plants using meansurements of perturbed --directional correlations. 相似文献
94.
Burchard Franck 《Angewandte Chemie (International ed. in English)》1982,21(5):343-353
Uroporphyrinogen III plays a key role in the biosynthesis of heme, the red pigment of blood. In vivo studies with specifically 14C- and 3H-labeled precursors have revealed that the formation uroporphyrinogen III in the organism follows several primary and subsidiary pathways. Model experiments on the pattern of biosynthesis have led to simple and effective methods of synthesizing uroporphyrin analogs and have shown that their production is strongly favored thermodynamically. The biologically porphyrins important thus available permit a mechanistic explanation of the light-induced dermatoses in porphyria diseases and suggest promising medical applications in diagnosis and therapy. 相似文献
95.
The amperometric behaviour of a copper electrode towards amino acids is studied by means of a rotating disc electrode. A theoretical model describing the anodic background current in a buffer solution and the increase of the current caused by amino acids is checked experimentally. The influences of the amino acid concentration, the rotation speed of the electrode and the composition of the buffer solution are studied. It is proved that chemical dissolution of a passivating film on the electrode surface, which is enhanced by the complexation reaction between the amino acid and copper(II) ions, is the principle of the phenomena observed. The applicability to flow systems is demonstrated. 相似文献
96.
Zusammenfassung Durch Messungen der Alterung (Verminderung der prozentualen Farbstoffaufnahme) der zwei aufeinander liegenden Oxyde auf anodisch
oxydiertem Aluminium wurde folgendes festgestellt:
Das genannteγ
2-Al2O3 weist keine wesentliche Alterung in der Luft und unter Wasser auf, da es kompakt und geordnet ist.
Dasγ
1-Al2O3 altert in der Luft und unter Wasser proportional der Zeit. Seine Alterungsgeschwindigkeit ist proportional der Herstellungsstromdichte.
Nach 12 A/dm2 nimmt die Alterung nicht mehr zu, da dieses Oxyd die maximale Fehlordnung besitzt. Die Alterung in der Luft ist kleiner als
unter Wasser, da dieses mit seinem L?sungsverm?gen für die Rekristallisation günstig ist. Mit zunehmender Temperatur nimmt
die Alterungsgeschwindigkeit bis 90°C zu und f?llt darüber hinaus bis zu Null (120°C). Bei h?heren Temperaturen findet eine
Verjüngung des Oxyds statt. Dieses Ph?nomen mit Temperaturmaximum ist zum ersten Mal bei heterogenen Reaktionen unter ?nderung
eines festen Stoffes festgestellt worden und bedeutet eine Rückreaktion entweder unter Bildung von neuen Fehlordnungen (die
Werte der Aktivierungsenergien der Hin- und Rückreaktion sind dafür plausibel) oder eine Freilegung von anwesenden aktiven
Zentren, wegen Desorption von Wasser. 相似文献
97.
von Euler H Olsson JM Hultenby K Thörne A Lagerstedt AS 《Bioelectrochemistry (Amsterdam, Netherlands)》2003,59(1-2):89-98
INTRODUCTION: Electrochemical treatment (EChT) has been taken under serious consideration as being one of several techniques for local treatment of malignancies. The advantage of EChT is the minimal invasive approach and the absence of serious side effects. Macroscopic, histopathological and ultra-structural findings in liver following a four-electrode configuration (dog) and a two-electrode EChT design (dog and rat) were studied. MATERIALS AND METHODS: 30 female Sprague-Dawley rats and four female beagle dogs were studied with EChT using Platinum:Iridium electrodes and the delivered dose was 5, 10 or 90 C (As). After EChT, the animals were euthanized. RESULTS: The distribution of the lesions was predictable, irrespective of dose and electrode configuration. Destruction volumes were found to fit into a logarithmic curve (dose-response). Histopathological examination confirmed a spherical (rat) and cylindrical/ellipsoidal (dog) lesion. The type of necrosis differed due to electrode polarity. Ultra-structural analysis showed distinct features of cell damage depending on the distance from the electrode. Histopathological and ultra-structural examination demonstrated that the liver tissue close to the border of the lesion displayed a normal morphology. CONCLUSIONS: The in vivo dose-planning model is reliable, even in species with larger tissue mass such as dogs. A multi-electrode EChT-design could obtain predictable lesions. The cellular toxicity following EChT is clearly identified and varies with the distance from the electrode and polarity. The distinct border between the lesion and normal tissue suggests that EChT in a clinical setting for the treatment of liver tumours can give a reliable destruction margin. 相似文献
98.
Oudhoff KA Macka M Haddad PR Schoenmakers PJ Kok WT 《Journal of chromatography. A》2005,1068(1):183-187
A capacitively coupled contactless conductivity detection (CCD) system has been applied for the detection of neutral synthetic polymers in capillary size-exclusion electrokinetic chromatography (SEEC). Polystyrene standards, that were used as a model compounds, were separated on a capillary column packed with porous 10 microm silica particles with an electrokinetically driven mobile phase, and detected by CCD and UV detection simultaneously. Mass-calibration curves for polystyrene were constructed. Satisfactory results were obtained for the linearity, the run-to-run repeatability (<0.2% for the relative retention and <4% for the peak area) and the robustness of the detector. One of the major issues in this preliminary study was to investigate the origin of the peaks observed for the polystyrene standards. The effect of the molar mass of the polystyrenes on the sensitivity was small. Therefore, the signals obtained could not be explained as the result of an increased viscosity and a decreased solution conductivity of the solute zone. An alternative hypothesis is suggested, and recommendations for further research are given. 相似文献
99.
Glycerol of different quality classifications served as a model for a neutral excess component in the isotachophoretic determination of low-molecular-mass anionic trace impurities. Potential anionic contaminants such as nitrate, sulphate, chlorate, nitrite, oxalate, fluoride formate and phosphate were analysed up to an analyte-to-excess ratio of 1:4·107, thus providing the possibility of checking the sample for the mentioned analytes in the order of 2.5·10−6–9.5·10−6%. Because we used a column-coupling isotachophoretic instrument the electrolyte system consisted of two different leading electrolytes, one for the pre-separation (10 mmol/l HCl, β-alanine, pH 3.2) in the first capillary and one for the final separation (5 mmol/l HCl, 1,3-bis[tris(hydroxymethyl)methylamino]propane, β-alanine, pH 3.6) in the second capillary. The terminating electrolyte was citric acid. Due to an increased injection volume of 300 μl, limits of detection (LODs) in the nanomolar range were realised by conductivity detection. The developed method allows simultaneous analysis without sample preparation and/or preconcentration within 25 min and is for that reason suitable for in-place process control. 相似文献
100.
Summary The use of non-segmented flow, post-column reaction detection is evaluated for use with miniaturized HPLC. Non-segmented open-tubular reactors with internal diameters 0.1 mm to 0.25 mm and packed-bed reactors with internal diameters of 1 mm, filled with 5 and 10 m particles are evaluated theoretically and experimentally with respect to band broadening and pressure drop characteristics. An integrated system consisting of miniaturized HPLC (1 mm i. d.) columns and compatible hardware is described. An example of the separation of catecholamines is given. 相似文献