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961.
María A. Aramendía Alberto Marinas José M Marinas Elena Sánchez Francisco J. Urbano Claude Guillou José M. Moreno Rojas Mustafa Moalem Luis Rallo 《Rapid communications in mass spectrometry : RCM》2010,24(10):1457-1466
We have determined δ13C, δ2H and δ18O isotopic abundances in Andalusian olive oils. In addition, the fatty acid composition and the distribution of isomers at positions 1,3 and 2 of glycerol were determined by 1H and 13C nuclear magnetic resonance (NMR) spectroscopy, respectively. Isotopic results obtained for four series of oil samples extracted from olives harvested in the 2004/05 and 2005/06 seasons are discussed in terms of olive variety, ripeness, geographical origin, fatty acid composition and growing altitude. A distinction was also established between olives grown in irrigated and in dry land by studying selected samples of the previous series and others from the 2005/06, 2006/07, 2007/08 and 2008/09 seasons. The results showed that olive ripeness does not influence the abundance of any of the three isotopes studied. On the other hand, the olive variety influences the abundance of the oxygen and hydrogen isotopes, and also, less markedly, that of carbon. No clear‐cut effect of height or latitude on isotope values is observed, probably because the olive variety also changes with height and latitude, thus masking such influences. The oil samples from dryland‐grown olives had increased δ13C values relative to irrigation‐grown olives. In addition, no definite relationship appears to exist between isotope distribution and fatty acid composition. Finally, oil samples from olives harvested in the 2005/06 season in Italy could be distinguished from those from Spain in terms of their isotopic values (δ2H mainly). Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
962.
963.
Aline de Souza Ramos Joyce Benzaquem Ribeiro Leonardo Vazquez Selma Gomes Ferreira Leite Francisco Radler de Aquino Neto 《Tetrahedron letters》2009,50(52):7362-6129
The enantioselective reduction of ethyl benzoylacetate (EBA) into ethyl (S)-3-hydroxy-3-phenylpropanoate (S-HPPE) by nine yeast strains and three filamentous fungi strains is described. The conversion obtained was in the range 0-89% and the enantiomeric excess was 100% in many cases. Conversion levels were higher when the reduction was performed with microorganisms immobilized in calcium alginate and enantioselectivity remained excellent. Some reaction’s conditions of bioreduction by immobilized cells of Rhodotorula rubra were studied using a 25-2 fractional factorial design. 相似文献
964.
Francisco Alonso 《Tetrahedron letters》2009,50(25):3070-6179
A novel synthesis of resveratrol, DMU-212 and analogues is presented using benzyl alcohols as phosphorus ylide partners in a one-pot Wittig-type olefination reaction promoted by nickel nanoparticles. 相似文献
965.
Francisco Jara 《Tetrahedron》2006,62(33):7817-7823
The interactions of six solvatochromic pyridiniophenolate dyes with α- and β-cyclodextrins were investigated with the aid of UV-vis and 1H NMR spectroscopies, and molecular dynamics simulations. The deduced mode of encapsulation of these dyes within the hydrophobic host cavity was employed as a measure of the relative contributions of the donor and acceptor moieties to their solvatochromic properties. 相似文献
966.
Pyridoxamine has been found to inhibit protein glycation and to avoid the formation of advanced glycation end‐products (AGEs). One of the mechanisms by which pyridoxamine can inhibit glycation involves the scavenger of carbonyl groups with glycation capacity. In this work, we conducted a kinetic study of the reactions of pyridoxamine with various carbohydrates under physiological pH and temperature. The reactions involving hexoses were found to give a tricyclic compound ( 5 ) in addition to pyridoxal and pyridoxine. Such a tricyclic compound inhibits the Amadori rearrangement and the formation of other carbonyl compounds with glycating properties. The reactions involving pentoses gave compound 7 and pyridoxal—by transamination of the Schiff base. The transamination reaction enhances the inhibitory action of pyridoxamine. The formation rate constants for the Schiff base, k3, were found to be similar to those for the reactions of D ‐glucose with amino acids, which suggests competition between pyridoxamine and terminal amino residues in proteins for glycating sites in sugars. These constants are dependent on the electrophilic character of the carbonyl carbon in the carbohydrate. © 2007 Wiley Periodicals, Inc. 39: 154–167, 2007 相似文献
967.
We apply the method of Dalgarno and Lewis to scattering states and discuss the choice of the unperturbed model in order to have a convergent perturbation series for the phase shift. We show that a recently proposed approach is a particular case of the method of Dalgarno and Lewis. 相似文献
968.
Jocelino Sato Vicente Francisco De Souza Neto 《Annals of Global Analysis and Geometry》2006,29(3):221-240
We classify the zero scalar curvature O(p+1)×O(q+1)-invariant hypersurfaces in the euclidean space ℝ
p+q+2, p,q > 1, analyzing whether they are embedded and stable. The Morse index of the complete hypersurfaces show the existence of embedded, complete and globally stable zero scalar curvature O(p+1)×O(q+1)-invariant hypersurfaces in ℝ
p+q+2, p+q≥ 7, which are not homeomorphic to ℝ
p+q+1. Such stable examples provide counter-examples to a Bernstein-type conjecture in the stable class, for immersions with zero scalar curvature.
Mathematics Subject Classifications (2000): 53A10, 53C42,49005. 相似文献
969.
Combretastatins A-4 and AVE-8062A have been synthesized by coupling 3,4,5-trimethoxyphenylacetylene with the corresponding iodomethoxyphenol and bromomethoxyaniline, followed by hydrolysis of the thermally-stable Ti(II)-alkyne complexes. 相似文献
970.
Marta Teijeira Yagamare Fall Francisco Santamarta Emilia Tojo 《Tetrahedron letters》2007,48(45):7926-7929
A new efficient and rapid experimental method and product isolation procedure as well as easy recyclable reaction media is expected to contribute to the development of a green strategy for the synthesis of furan diol from d-glucal. We determine the best conditions of reaction, minimizing the toxicity and finding an environmentally more acceptable process, using [Bmim][MSO4]/InCl3·3H2O as a new solvent system under extremely mild conditions, providing high yields with a dramatic enhancement of reaction rate. 相似文献