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51.
M. del Mar Canedo José Luis González Francisca Cuesta Josef Havel 《Reaction Kinetics and Catalysis Letters》1992,48(1):77-83
A new KINDC kinetic computational method is proposed that offers a greatly improved version of the KILET program. A comparative study is made of its performance and those of the most recent computational methods reported in the literature.
, KINDC, KILET. .相似文献
52.
Francisca Barrios Juan M. Salas M. Purificación Sánchez Miguel Quirós René Faure 《Journal of chemical crystallography》1999,29(9):1009-1013
The complex [Ni(XsH–1)2(H2O)4]·6H2O (XsH–1: xanthosinate) was isolated from the reaction of nickel carbonate with xanthosine in aqueous solution. The octahedral coordination is supported by the reflectance measurements. Single-crystal X-ray diffraction studies show that the crystals belong to the triclinic P1 space group, with a = 7.152(1), b = 8.830(1),c = 13.783(1) Å, = 82.024(1)°, = 86.155(1)°, = 70.900(1)°, and D = 1.643 mg/m3, forZ = 1. Nickel is six coordinate with four water molecules, and two N7 atoms from xanthosinato ligands. A complicated hydrogen-bonding network is present, all possible donors taking part in it. 相似文献
53.
L. J. Francisca Mary P. Kannan 《Journal of polymer science. Part A, Polymer chemistry》1999,37(12):1755-1761
Three series of poly(pyromellitimide‐ester)s were synthesized from various N,N′‐bis(ω‐hydroxyalkyl)pyromellitimides (HAPMIs) by melt condensation with dicarboxylic acids, including terephthalic acid (TPA), 4,4′‐biphenyldicarboxylic acid (BPDA), and 4,4′‐azobenzenedicarboxylic acid (ABDA). Polymers were characterized by elemental analysis, solubility, inherent viscosity, spectra (IR, 1H‐NMR, 13C‐NMR), and X‐ray diffraction (XRD). Thermal stability and phase transition behaviour were evaluated by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and hot‐stage optical polarized microscopy (HOPM). The d‐spacings, calculated from XRD data, showed an odd‐even effect with varying numbers of methylene spacers. Crystallinity of polymers decreased in the following order: azobenzene > biphenyl > phenyl polymers. Similarly, DSC‐obtained melting temperatures (Tm's) showed an odd‐even effect, and glass transition temperatures (Tg's) decreased with increasing numbers of methylene spacers. Thermal stability decreased as methylene chain length increased. Thermal stability of polymers occurred in the following order: phenyl > biphenyl > azobenzene polymers. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 1755–1761, 1999 相似文献
54.
Manuel Bueno Francisca Zamora Inmaculada Molina Hernn A. Orgueira Oscar Varela Juan A. Galbis 《Journal of polymer science. Part A, Polymer chemistry》1997,35(17):3645-3653
The synthesis of three new stereoregular AB-type polyamides based on D -ribono-1,4-lactone, L -arabinose, and D -xylose has been carried out by the active ester polycondensation method. These polyamides were characterized by elemental analysis, IR and NMR spectroscopies, and powder X-ray diffraction. They displayed optical activity and had a pronounced affinity to water, although they were not soluble in this solvent. The polyamide obtained from D -ribono-1,4-lactone was highly crystalline and yielded films with spherulitic texture. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 3645–3653, 1997 相似文献
55.
Inmaculada Molina Pinilla Manuel Bueno Martínez Francisca Zamora Mata Juan A. Galbis 《Journal of polymer science. Part A, Polymer chemistry》1998,36(1):67-77
Two poly(ester amides) containing three methoxy groups stereoregularly attached to the main chain have been prepared by using naturally occurring L -arabinose and D -xylose as the starting materials. The polymers were prepared by the active ester polycondensation method and characterized by elemental analysis, IR, and 1H- and 13C-NMR spectroscopies. Both viscosimetry and GPC were used to estimate the molecular weights. The polymers are hydrophilic, one of them being water soluble, and exhibited moderate optical activity. Thermal and X-ray diffraction studies revealed that they are slightly crystalline and stable up to 250°C under nitrogen. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 67–77, 1998 相似文献
56.
On-line characterisation of apple polyphenols by liquid chromatography coupled with mass spectrometry and ultraviolet absorbance detection 总被引:5,自引:0,他引:5
Alonso-Salces RM Ndjoko K Queiroz EF Ioset JR Hostettmann K Berrueta LA Gallo B Vicente F 《Journal of chromatography. A》2004,1046(1-2):89-100
Apple polyphenols were characterised by means of hyphenated techniques such as HPLC coupled to UV photodiode array detection (LC-DAD) and to mass spectrometry (LC-MS). LC-MS using atmospheric pressure ionisation (APCI) in the positive ion mode provided the molecular weight, the number of hydroxyl groups, the number of sugars and an idea about the substitution pattern of the polyphenols. LC-DAD with postcolumn addition of UV shift reagents afforded precise structural information about the position of the free hydroxyl groups in the polyphenolic nucleus. Five isorhamnetin glycosides, two hydroxyphloretin glycosides and quercetin were reported in apple peel for the first time. Postcolumn addition of UV shift reagents in LC-DAD analysis confirmed the presence of isorhamnetin glycosides and not the isomeric glycosides of rhamnetin. Moreover, isorhamnetin-3-O-rhamnoglucoside was identified unambiguously by comparison with a standard. These results are relevant not only from a chemotaxonomic point of view, but also in the control of authenticity of fruit derived products in order to detect fraudulent admixtures. 相似文献
57.
Belén Begines Francisca Zamora Elena Benito Mª de Gracia García‐Martín Juan A. Galbis 《Journal of polymer science. Part A, Polymer chemistry》2012,50(22):4638-4646
Linear polyurethanes based on sugar monomers having D ‐gluco, galacto, and D ‐manno configurations and their secondary hydroxyl groups protected as bicyclic acetals, have been prepared by polyaddition reaction of these diol monomers to hexamethylene diisocyanate ( HMDI ) and 4,4′‐methylene‐bis(phenyl isocyanate) ( MDI ). The new polyurethanes seem to be amorphous materials, except that obtained from 2,3:4,5‐di‐O‐methylene‐galactitol and HMDI. Weight‐average molecular weights, determined by GPC, were in the range 16,000–115,200. TGA analyses indicated that the thermal stability of these bicyclic polyurethanes is comparable to those based on the isosorbide; both the onset and the maximum rate decomposition temperatures increased significantly with respect to the polyurethanes based on acyclic sugar monomers. The presence of the acetalized alditol units in the polyurethanes also increased the Tgs as compared with their acyclic analogs. Deacetalization of the polyurethanes containing di‐O‐isopropylidene‐D ‐mannitol units yielded the polyhydroxylated polymers in good yields, without apparent degradation of the polymer chain. These hydroxylated polymers showed an enhanced hydrophilicity and degradability and lower Tgs and thermal stability than their parent acetalized polyurethanes. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
58.
Belén Begines Francisca Zamora Isaac Roffé Manuel Mancera Juan A. Galbis 《Journal of polymer science. Part A, Polymer chemistry》2011,49(9):1953-1961
Novel linear homogeneous polyurethanes and polyureas with enhanced hydrophilic character have been successfully prepared from sugar‐based monomers having their hydroxyl groups free or partially protected. By the reaction of primary hydroxyl groups of xylitol with dimethyl hexamethylene dicarbamate (HMDC) or di‐tert‐butyl‐4,4′‐diphenyl methyl dicarbamate (MDC), two new linear semicrystalline polyurethanes [PU(X‐HMDC) and PU(X‐MDC)] have been prepared. Likewise, by the reaction of xylitol with the analogous diisocyanates hexamethylene diisocyanate (HMDI) or 4,4′‐methylenebis(phenyl isocyanate) (MDI), similar polyurethanes [PU(X‐HMDI) and PU(X‐MDI)] were obtained. However, these latter polyurethanes present some degree of crosslinking because of the higher reactivity of the diisocyanate comonomers. Linear hydrophilic polyureas having free hydroxyl groups joined to the main chain have also been prepared by the reaction of the same diisocyanates (HMDI and MDI) with 1,6‐diamino‐1,6‐dideoxy‐D ‐mannitol and 1,6‐diamino‐1,6‐dideoxy‐3:4‐O‐isopropylidene‐D ‐mannitol. As far as we are aware, this kind of polyhydroxylated polyurea has not been previously described in the literature. The new polymers were characterized by standard methods (elemental analyses, gel permeation chromatography, IR, and NMR). The polyurethanes were hydrolytically degradable under physiological conditions, in contrast with less‐hydrophilic linear polyurethanes previously described. The thermal properties of the novel polymers were investigated by thermogravimetric analysis and differential scanning calorimetry. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
59.
Michael Hrušák Diego Rojas‐Rebolledo Jindřich Zapletal 《Mathematical Logic Quarterly》2014,60(1-2):31-39
We study the possible values of the cofinality invariant for various Borel ideals on the natural numbers. We introduce the notions of a fragmented and gradually fragmented ideal and prove a dichotomy for fragmented ideals. We show that every gradually fragmented ideal has cofinality consistently strictly smaller than the cardinal invariant and produce a model where there are uncountably many pairwise distinct cofinalities of gradually fragmented ideals. 相似文献
60.
Víctor Tena Pérez Ángel L. Fuentes de Arriba Laura M. Monleón Luis Simón Omayra H. Rubio Francisca Sanz Joaquín R. Morán 《Tetrahedron》2014
Borohydride reduction of salicylaldehyde imines yields surprisingly a cyclic boramide. This is a fairly stable compound, and X-ray analysis shows it has a tetrahedral boron atom. Mechanistic studies show a reaction pathway through an oxazaborinane intermediate. The reaction also works with halogen substituted salicylaldehydes and for the preparation of non-symmetrical boramides. 相似文献