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421.
Rodica Olar Gina Vasile Scaeteanu Ioana Dorina Vlaicu Luminita Marutescu Mihaela Badea 《Journal of Thermal Analysis and Calorimetry》2014,118(2):1195-1202
Three new coordinative compounds of the type [Co(en)2CO3]·0.75H2O (1) and [M(en)2(H2O)2]CO3 ((2) M:Ni, (3) M:Cu; en: ethylenediamine) were synthesized and characterized. The IR and UV–Vis spectral data indicate that ethylenediamine acts as chelate, while carbonate ions act as bidentate chelate ligand for (1)/counter ion for (2) and (3) generating complexes with octahedral stereochemistry. The thermal behavior provided confirmation of the complexes composition, as well as the number and the nature of water molecules and the intervals of thermal stability. The biological assays revealed a good activity against Enterococcus faecium for copper complex. 相似文献
422.
Ana-Maria Ungureanu Ovidiu Oprea Bogdan Stefan Vasile Corina Andronescu Georgeta Voicu Ioana Jitaru 《Central European Journal of Chemistry》2014,12(9):909-917
We successfully synthesized tin dioxide nanoparticles with polyhedral morphology via an ethylene glycol assisted sol-gel approach. The structural characteristics of three tin dioxide samples were investigated after being thermally treated at 400°C, 600°C and 800°C. X-ray diffraction (XRD) patterns clearly show the formation of single phase tin dioxide nanoparticles, with crystallite size of 6–20 nm, in good correlation with Fourier transform infrared (FTIR) spectra. Transmission electron microscopy (TEM) analysis confirms the formation of 6nm polyhedral nanoparticles for the 400°C sample. Ultraviolet-visible (UV-Vis) and photoluminescence (PL) spectra suggest a high concentration of oxygen vacancies. The oxygen vacancy concentration increases with temperature, due to the combined action of the formation of VO and the energetic O compensation. X-ray photoelectron spectroscopy (XPS) analysis also confirms the formation of single phase tin dioxide and the presence of oxygen vacancies in good agreement with UV-VIS and PL data. 相似文献
423.
Ovidiu Oprea Oana Ciocirlan Alina Badanoiu Eugeniu Vasile 《Central European Journal of Chemistry》2014,12(7):749-756
ZnO nanoparticles were synthesized in mixtures of ionic liquids based on imidazolium cation with organic solvents (dimethyl sulfoxide and ethylene glycol) by a simple, one-step solution route at low temperature. The effect of these mixtures on the morphology, size and properties of as obtained ZnO nanopowders was investigated. The obtained nanopowders have been characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), UV-Vis absorption spectroscopy (UV-Vis) and photoluminescence (PL). The effect of the ionic liquid mixture on the photocatalytic degradation of methylene blue has been analysed. The XRD studies confirmed the hexagonal wurtzite structure of the obtained ZnO powder. The UV-Vis absorption spectra present the typical shape for ZnO, with a broad band situated in the UV region, with the maximum around 360 nm. The calculated band-gap energy is in interval 3.25–3.28 eV. The synthesized ZnO nanopowders have high photocatalytic activity against methylene blue, the best results being obtained when 1-ethyl-3-methylimidazolium tetrafluoroborate was used as the solvent.
相似文献
424.
Potmischil F Marinescu M Nicolescu A Deleanu C Hillebrand M 《Magnetic resonance in chemistry : MRC》2008,46(12):1141-1147
The (15)N NMR chemical shifts of 1,2,3,4,5,6,7,8-octahydroacridine, 12 of its 9-substituted derivatives, and of the corresponding N-oxides were measured and examined in terms of the 9-substituent effects and the effects of N-oxidation. For the 9-substituent effects, good linear correlations were found with the Taft and Swain-Lupton substituent constants, for both octahydroacridines and their N-oxides. The (15)N chemical shifts of both octahydroacridines and their N-oxides also correlate well, linearly with the (13)C chemical shifts of the para-carbons in analogously substituted benzene derivatives.Within the studied compounds, the magnitudes of the N-oxidation effects range from - 16.4 to - 27.4 ppm (shielding), and also correlate linearly with the Taft and Swain-Lupton substituent constants, as well as with the bond orders of the N(+)-O(-) bonds in the corresponding N-oxides. Furthermore, a very good linear correlation is found between the (15)N chemical shifts of octahydroacridines and those of the corresponding N-oxides. From the (15)N chemical shifts data, the Taft and Swain-Lupton substituent constants for the diacetylamino group (-NAc(2)) were evaluated in the present paper, as follows: sigma(R) = 0.07 and sigma(I) = 0.15; R = 0.08 and F= 0.20. 相似文献
425.
Cojocariu AM Mutin PH Dumitriu E Fajula F Vioux A Hulea V 《Chemical communications (Cambridge, England)》2008,(42):5357-5359
A SiO(2)-TiO(2) mesoporous xerogel prepared in one-step by a non-hydrolytic route shows excellent performance in the mild oxidation of sulfides, sulfoxides and thiophenes with aqueous solutions of H(2)O(2). 相似文献
426.
Neaţu S Pârvulescu VI Epure G Preda E Somoghi V Damin A Bordiga S Zecchina A 《Physical chemistry chemical physics : PCCP》2008,10(43):6562-6570
The photocatalytic decomposition of yperite (bis(2-chloroethyl)sulfide), a chemical warfare agent, was achieved by using titania-silica catalysts doped with several transition metal ions. The preparation of these catalysts was achieved by impregnation of a titania-silica mixed oxide previously synthesized using a sol-gel route with salts of the doping elements (vanadium, iron, manganese). The above catalysts were characterized using several spectroscopic techniques: FTIR, Raman, DR-UV-Vis, and XPS. The band gap energy was measured for each photocatalytic system. The reaction was carried out in two different types of reactors, i.e. naturally aerated and a closed quartz tube aerated under a constant flow, and using two types of irradiation, UV-Vis and Vis. The investigated systems proved to be extremely active, leading to an almost complete degradation of yperite in 2 h of irradiation. An excellent correlation between the photocatalytic performances and the band gap has been found. Based on the characterization data and on the temporal evolution of the reaction products, a reaction mechanism has been suggested. This mechanism considers two distinct pathways for the decomposition of yperite, namely the C-S bond cleavage and the S oxidation. 相似文献
427.
Emil Ioan Muresan Spiridon Oprea Vasile Hulea Theodor Malutan Mihai Vata 《Central European Journal of Chemistry》2008,6(3):419-428
The kinetics of the esterification reaction between acetic acid and epichlorohydrin catalysed by Purolite A-520E strong basic
anion exchange resin was studied. The effects of certain parameters such as stirring speed, particle diameter, temperature,
catalyst amount and molar ratio between reactants were experimentally determined. It was found that the overall reaction rate
is intrinsically kinetically controlled. The partial orders of reaction with respect to catalyst, acetic acid and epichlorohydrin
were determined. A reaction mechanism is proposed. Based on chromatographic data and taking into account the partial orders
of reaction, a more detailed kinetic model is suggested.
相似文献
428.
Czechoslovak Mathematical Journal - We prove that for normal operators N1, $${N_2} \in {\cal L}({\cal H})$$ , the generalized commutator [N1, N2; X] approaches zero when [N1, N2; [N1, N2; X]] tends... 相似文献
429.
Potenza D Belvisi L Vasile F Moroni E Cossu F Seneci P 《Organic & biomolecular chemistry》2012,10(16):3278-3287
In this paper we report an extensive NMR analysis of small ligands (Smac mimics) complexed with different constructs of XIAP. The mimics-binding site of XIAP is known as the BIR3 domain - primary, and the linker BIR2 region - secondary site. Interactions between the BIR3 domain and Smac mimics have been extensively studied by X-ray but, as of today, there are scarce data about the interaction between BIR2, or the whole linker-BIR2-BIR3 construct, and Smac mimics. In order to characterize our Smac mimics, we performed a STD NMR study between our 4-substituted, 1-aza-2-oxobicyclo[5.3.0]decane scaffold-based molecules and three different XIAP fragments: single BIR2 and BIR3 domains, and bifunctional linker-BIR2-BIR3. The results were integrated with docking calculations and molecular dynamics simulations. NMR data, which are consistent with biological tests, indicated that the two BIR subunits interact differently with our Smac mimics and suggest that the ligands enter into more intimate contact with the linker-BIR2-BIR3. In conclusion, we observe that the SMAC mimics showed with the construct linker-BIR2-BIR3 a series of NOE contacts that were not observed in the mono-domain ligand:BIR2 or :BIR3 complexes. So, in agreement with the computational models we believe that the linker moieties of the binding site play a key role in the stability of the protein complex. 相似文献
430.
Mihaela-Ramona Buga Adnana Alina Spinu-Zaulet Cosmin Giorgian Ungureanu Raul-Augustin Mitran Eugeniu Vasile Mihaela Florea Florentina Neatu 《Molecules (Basel, Switzerland)》2021,26(15)
Porous silica-based materials are a promising alternative to graphite anodes for Li-ion batteries due to their high theoretical capacity, low discharge potential similar to pure silicon, superior cycling stability compared to silicon, abundance, and environmental friendliness. However, several challenges prevent the practical application of silica anodes, such as low coulombic efficiency and irreversible capacity losses during cycling. The main strategy to tackle the challenges of silica as an anode material has been developed to prepare carbon-coated SiO2 composites by carbonization in argon atmosphere. A facile and eco-friendly method of preparing carbon-coated SiO2 composites using sucrose is reported herein. The carbon-coated SiO2 composites were characterized using X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetry, transmission and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, cyclic voltammetry, and charge–discharge cycling. A C/SiO2-0.085 M calendered electrode displays the best cycling stability, capacity of 714.3 mAh·g−1, and coulombic efficiency as well as the lowest charge transfer resistance over 200 cycles without electrode degradation. The electrochemical performance improvement could be attributed to the positive effect of the carbon thin layer that can effectively diminish interfacial impedance. 相似文献