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排序方式: 共有6116条查询结果,搜索用时 31 毫秒
31.
Giancarlo Marconi Sandra Monti Francesco Manoli Stefano Ottani 《Journal of inclusion phenomena and macrocyclic chemistry》2007,57(1-4):279-282
The Induced Circular Dichroism of the complex formed by inclusion of Licochalcone-A (a powerful antimalarian of natural origin)
and β-cyclodextrin was measured and calculated. The association constant was determined by titration experiments of ICD and
fluorescence. The lowest energy conformations of the complex were obtained through docking procedures and their Circular Dichroism
was evaluated within the Tinoco framework. The geometry of the complex was found to be consistent with the main experimental
features. 相似文献
32.
33.
Within the 1/N expansion of O(N) nonlinear σ models for d≤4 it is possible to separate consistently the spin-wave and the massive-mode contributions to the scaling part of the free energy near criticality, and to evaluate them to O(1/N). For critical dimensions d=2+2/n the Abe-Hikami anomaly is recovered, while for d=2 the removal of the spin-wave term is justified. 相似文献
34.
Francesco de Giovanni 《Milan Journal of Mathematics》1991,61(1):257-265
35.
Andrea Lodi Monica Caselli Alessandro Casnati Fabio Momicchioli Francesco Sansone Davide Vanossi Glauco Ponterini 《Journal of Molecular Structure》2007,846(1-3):49-54
The sulfonated calixarene I8C12 acts as a host for homologous merocyanines Mc1 and Mc2 in organic solvents, exhibiting neither selectivity towards the guest dyes nor solvent dependence of the complexation equilibria. In water, on the contrary, only the lower homologue, Mc1, is solubilized in the presence of the calixarene. A combination of UV–visible and fluorescence spectroscopic and photophysical analysis and MD structural simulation of the calixarene-dye complexes was employed to account for the observations, and suggests that a radical change in the complexation mode occurs upon moving from an organic to an aqueous environment. 相似文献
36.
Paolo Battocchio Francesco Menoncin Olivier Scaillet 《Annals of Operations Research》2007,152(1):141-165
In a financial market with one riskless asset and n risky assets whose prices are lognormal, we solve in a closed form the problem of a pension fund maximizing the expected
CRRA utility of its surplus till the (stochastic) death time of a representative agent. We consider a unique asset allocation
problem for both accumulation and decumulation phases. The optimal investment in the risky assets must decrease during the
first phase and increase during the second one. We accordingly suggest it is not optimal to manage the two phases separately,
and outsourcing of allocation decisions should be avoided in both phases.
JEL: G23, G11
MSC 2000: 62P05, 91B28, 91B30, 91B70, 93E20 相似文献
37.
J. P. Leroy J. Micheli G. C. Rossi K. Yoshida 《Zeitschrift fur Physik C Particles and Fields》1990,48(4):653-661
In this paper we present a non-trivial check of the consistency of the quantization of a gauge theory with fermions (QCD) in the temporal gauge. We use the approach based on the finite time Feynman propagation kernel, in which the Gauss law is imposed as a constraint on the states by means of a functional integration over all the time independent gauge transformations acting on the boundary values of the fields. We spell out in detail the “Feynman rules” when fermions are present and we compute, as an example, the gauge invariant correlation function $$\begin{gathered} G(t) = \left\langle {\bar \psi (0,t)(\gamma _5 \gamma _0 )\frac{{1 - \gamma _0 }}{2}P} \right. \hfill \\ \left. { \cdot \exp \left( {ig\int\limits_0^t {A_0 (0,t')dt'} } \right)(\gamma _5 \gamma _0 )^ + (0,0)} \right\rangle \hfill \\ \end{gathered} $$ up to orderg 2, obtaining the expected result. 相似文献
38.
39.
Simultaneous separation and identification of hashish constituents by coupled liquid chromatography-mass spectrometry (HPLC-MS) 总被引:1,自引:0,他引:1
C. Rustichelli V. Ferioli F. Vezzalini M. C. Rossi G. Gamberini 《Chromatographia》1996,43(3-4):129-134
Summary This paper reports the use of liquid chromatography for the separation and determination of the major cannabinoids extracted from hashish samples. The direct coupling to the mass spectrometer enables the selective identification both of neutral and acidic cannabinoids. The developed method does not require any preliminary derivatization and should, therefore, be of interest in forensic analysis for simple and unequivocal determination of hashish constituents.Part of this work was presented at the 2nd Italian-Spanish Joint Meeting of Medicinal Chemistry, 30 August–3 September 1995, Ferrara, Italy. 相似文献
40.
Beverina L Abbotto A Landenna M Cerminara M Tubino R Meinardi F Bradamante S Pagani GA 《Organic letters》2005,7(19):4257-4260
[graph: see text] Condensation of squaric acid with a number of differently substituted 2-pyrrolyl derivatives afforded three new classes of squaraines. Their sharp and intense absorption bands in the biological window (700-900 nm), inherent singlet oxygen generation capabilities, together with proper functionalization allowing good water solubility make them suitable candidates as new non-porphyrinic singlet oxygen photosensitizers for photodynamic therapy (PDT). 相似文献