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排序方式: 共有347条查询结果,搜索用时 171 毫秒
31.
32.
Herbert L. Holland Peter R. Andreana Reza Salehzadeh-Asl Aaron van Vliet Nancy J. Ihasz Frances M. Brown 《Monatshefte für Chemie / Chemical Monthly》2000,40(5):667-672
Biotransformation of a series of racemic N-benzoyl α-amino acids by the fungus Beauveria bassiana ATCC 7159 results in isolation of the corresponding D-amino acid benzamides in high enantiomeric purity and yield. 相似文献
33.
Frances Y. Kuo Grzegorz W. Wasilkowski Henryk Wo
niakowski 《Journal of Approximation Theory》2008,152(2):135-160
We study the worst case setting for approximation of d variate functions from a general reproducing kernel Hilbert space with the error measured in the L∞ norm. We mainly consider algorithms that use n arbitrary continuous linear functionals. We look for algorithms with the minimal worst case errors and for their rates of convergence as n goes to infinity. Algorithms using n function values will be analyzed in a forthcoming paper.We show that the L∞ approximation problem in the worst case setting is related to the weighted L2 approximation problem in the average case setting with respect to a zero-mean Gaussian stochastic process whose covariance function is the same as the reproducing kernel of the Hilbert space. This relation enables us to find optimal algorithms and their rates of convergence for the weighted Korobov space with an arbitrary smoothness parameter α>1, and for the weighted Sobolev space whose reproducing kernel corresponds to the Wiener sheet measure. The optimal convergence rates are n-(α-1)/2 and n-1/2, respectively.We also study tractability of L∞ approximation for the absolute and normalized error criteria, i.e., how the minimal worst case errors depend on the number of variables, d, especially when d is arbitrarily large. We provide necessary and sufficient conditions on tractability of L∞ approximation in terms of tractability conditions of the weighted L2 approximation in the average case setting. In particular, tractability holds in weighted Korobov and Sobolev spaces only for weights tending sufficiently fast to zero and does not hold for the classical unweighted spaces. 相似文献
34.
Dan Luo Yong Xiao Liam Hardwick Robert Snell Matthew Way Xavier Sanuy Morell Frances Livera Nicholas Ludford Chinnapat Panwisawas Hongbiao Dong Russell Goodall 《Entropy (Basel, Switzerland)》2021,23(1)
In the search for applications for alloys developed under the philosophy of the High Entropy Alloy (HEA)-type materials, the focus may be placed on applications where current alloys also use multiple components, albeit at lower levels than those found in HEAs. One such area, where alloys with complex compositions are already found, is in filler metals used for joining. In soldering (<450 °C) and brazing (>450 °C), filler metal alloys are taken above their liquidus temperature and used to form a metallic bond between two components, which remain both unmelted and largely unchanged throughout the process. These joining methods are widely used in applications from electronics to aerospace and energy, and filler metals are highly diverse, to allow compatibility with a broad range of base materials (including the capability to join ceramics to metals) and a large range of processing temperatures. Here, we review recent developments in filler metals relevant to High Entropy materials, and argue that such alloys merit further exploration to help overcome a number of current challenges that need to be solved for filler metal-based joining methods. 相似文献
35.
Donato Ercole Conte Abdelmaula Aboulaich Josette Olivier-Fourcade Christian Jordy 《Journal of solid state chemistry》2010,183(1):65-6650
A comparative study of two Sn-based composite materials as negative electrode for Li-ion accumulators is presented. The former SnB0.6P0.4O2.9 obtained by in-situ dispersion of SnO in an oxide matrix is shown to be an amorphous tin composite oxide (ATCO). The latter Sn0.72[BPO4]0.28 obtained by ex-situ dispersion of Sn in a borophosphate matrix consists of Sn particles embedded in a crystalline BPO4 matrix. The electrochemical responses of ATCO and Sn0.72[BPO4]0.28 composite in galvanostatic mode show reversible capacities of about 450 and 530 mAh g−1, respectively, with different irreversible capacities (60% and 29%). Analysis of these composite materials by 119Sn Mössbauer spectroscopy in transmission (TMS) and emission (CEMS) modes confirms that ATCO is an amorphous SnII composite oxide and shows that in the case of Sn0.72[BPO4]0.28, the surface of the tin clusters is mainly formed by SnII in an amorphous interface whereas the bulk of the clusters is mainly formed by Sn0. The determination of the recoilless free fractions f (Lamb-Mössbauer factors) leads to the effective fraction of both Sn0 and SnII species in such composites. The influence of chemical composition and especially of the surface-to-bulk tin species ratio on the electrochemical behaviour has been analysed for several Snx[BPO4]1−x composite materials (0.17<x<0.91). The cell using the compound Sn0.72[BPO4]0.28 as active material exhibits interesting electrochemical performances (reversible capacity of 500 mAh g−1 at C/5 rate). 相似文献
36.
Grey Ercole 《Archiv der Mathematik》2014,103(2):189-194
We consider the following q-eigenvalue problem for the p-Laplacian $$\left\{\begin{array}{ll}-{\rm div}\big( |\nabla u|^{p-2}\nabla u\big) = \lambda \|u\|_{L^{q}(\Omega)}^{p-q}|u|^{q-2}u \quad \quad\, {\rm in} \,\,\,\, \Omega\\ \quad\quad\quad \quad \quad \quad u = 0 \quad\qquad\qquad \quad\quad \,\,{\rm on } \,\,\,\, \partial\Omega,\end{array}\right.$$ where \({\lambda\in\mathbb{R},}\) p > 1, Ω is a bounded and smooth domain of \({\mathbb{R}^{N},}\) N > 1, \({1\leq q < p^{\star}}\) , \({p^{\star}=\frac{Np}{N-p}}\) if p < N and \({p^{\star}=\infty}\) if \({p\geq N.}\) Let λ q denote the first q-eigenvalue. We prove that in the super-linear case, \({p < q < p^{\star},}\) there exists \({\epsilon_{q}>0}\) such that if \({\lambda\in(\lambda_{q},\lambda _{q}+\epsilon_{q})}\) is a q-eigenvalue, then any corresponding q-eigenfunction does not change sign in Ω. As a consequence of this result we obtain, in the super-linear case, the isolatedness of λ q for those Ω such that the Lane–Emden problem $$\left\{\begin{array}{ll}-{\rm div}\big(|\nabla u|^{p-2}\nabla u\big) = |u|^{q-2}u \qquad\quad\quad\quad \,\,{\rm in}\,\,\,\Omega\\ \quad\quad\quad \quad \quad \quad u = 0 \quad\qquad\qquad \quad\quad \,{\rm on } \,\,\, \partial\Omega,\end{array}\right.$$ has exactly one positive solution. 相似文献
37.
We describe real time observations of the behaviour of the silicon-oxide interface during oxidation in situ in an ultrahigh vacuum transmission electron microscope. We have formed clean, flat Si(111) surfaces by heating under UHV and allowed oxidation or oxygen etching to proceed in the microscope. We have examined the kinetics of both the oxidation and etching reactions using an imaging technique based on the use of forbidden reflections in silicon. We find that oxidation to form SiO2 occurs by the reaction of discrete monolayers with no flow of surface steps. This is in dramatic contrast to oxygen etching, during which the volatile oxide SiO evaporates preferentially from step edges. 相似文献
38.
39.
Ji Min Kim Loc Nguyen Mary Frances Barr Michael Morabito Damien Stringer J. Helen Fitton Kelly A. Mowery 《Analytica chimica acta》2015
The use of polyanion and polycation-sensitive membrane electrodes to detect five different preparations of fucoidan is described. Unlike linear polyanionic molecules previously measured with polymer membrane-based electrochemical sensors, fucoidans from marine brown algae are all highly branched, sulfated polysaccharides with varying charge densities and structures, depending on the species of seaweed, method of extraction used and extent of purification. When tridodecylmethylammonium (TDMA) was used as the ion-exchanger, a large, non-equilibrium EMF response was observed over a concentration range of 0.5–50 μg mL−1 fucoidan. Fucoidan was also measured by titration with polycationic protamine, using a dinonylnaphthalene sulfonate (DNNS)-doped membrane electrode as the potentiometric endpoint detector. Potentiometric titration was used to determine the binding ratio between protamine and fucoidan at the neutralization endpoint for each fucoidan preparation. This binding ratio was then used to successfully determine the fucoidan content of commercially available nutritional supplements. Fucoidan was also measured in undiluted blood serum, demonstrating that this method may be applicable for measuring fucoidan for clinical applications. 相似文献
40.
Neville F Broderick MJ Gibson T Millner PA 《Langmuir : the ACS journal of surfaces and colloids》2011,27(1):279-285
In nature, some peptides induce precipitation of silicic acid into silica nanoparticles such as is found in marine algae called diatoms. However, polybasic polymers can act as peptide mimics; one such polymer, polyethyleneimine (PEI), has the advantage that it is stable at room temperature and is inexpensive, in comparison with synthetic peptides. We describe the fabrication and characterization of biosilicate nanoparticles formed by mimicking the peptides using PEI. Brownian motion nanoparticle tracking analysis and field emission gun scanning electron microscopy have been used for the first time to characterize nanoparticles made with tetramethyl orthosilicate (TMOS) and PEI to investigate the fundamental factors that affect particle properties. These factors include the effect of phosphate concentration, PEI molecular weight, TMOS concentration, and species of alkoxy-silane used. The properties of the particles are compared with other particles made with polymers that induce silication. Our results show that using PEI gives differences in particle size compared with previous work using other polymers that induce silication. The entrapment of enzymes during the silication process, rationale for using nonphosphate and phosphate buffers during enzyme entrapment, and the analysis of enzyme activity are also presented. Because enzymes can be entrapped during fabrication, it means that there are many future possibilities for the use of silicate nanoparticles containing enzymes, such as biosensors and biocatalytic reactors. 相似文献