Iron(III) amine-bis(phenolate) complexes as catalysts for the coupling of alkyl halides with aryl Grignard reagents

Catalytic cross-coupling of aryl Grignard reagents with primary and secondary alkyl halides bearing beta-hydrogens is achieved using Fe(III) amine-bis(phenolate) halide complexes.     

A new method for computing surface tension using a drop of liquid

In the simulation of a liquid drop it is expensive to calculate the excess pressure and obtain the surface tension by the Laplace formula. We use the Kelvin formula which only requires the vapour density, or at most the virial pressure. Some results are given for a Lennard-Jones 12-6 fluid.     

高山-峡谷复合地形对入射平面P-SV波的散射

高山峡谷地形作为一种常见的复合场地,其对地震波散射相干效应十分复杂,然而,目前相关的研究成果还十分有限.为此,提出了一种用于求解平面内多域弹性波散射的多域间接边界元法,研究了高山峡谷地形对平面P-SV波的散射问题.该方法充分利用全空间Green函数与半空间Green函数在构造独立闭合域和半空间开口域中散射波场方面的优势,结合辅助函数法给出了高山峡谷场地的地震波场解答,在保证计算精度的同时显著提高了求解效率.该文通过与已有结果的比较验证了方法的正确性,并以半空间中Gauss型高山峡谷为例,分别在频域和时域内进行了数值计算分析.研究表明:高山峡谷地形附近地表位移幅值的分布非常复杂,山体与峡谷之间存在显著的动力相互作用,频域响应依赖于入射波的频率和角度;地震波垂直入射时,山体的存在对峡谷地震动有一定的抑制作用,显著改变了峡谷内部的加速度峰值及反应谱特性;高山峡谷地形两侧山体高宽比的改变将引起地震效应的改变,基岩的存在也将显著放大地形的地震效应.     

Crossdocking— Just in Time scheduling: an alternative solution approach

In this paper, a scheduling problem which allows a warehouse to function as a crossdock where transit storage time for cargo is minimized according to Just in Time scheduling is studied. A model that uses the machine scheduling notation to describe the problem is written. As the problem is NP-hard, a solution approach based on a combination of two metaheuristics, Reactive GRASP and Tabu Search (RGTS), is provided. Experiments are carried out to determine the usefulness of this approach. The results obtained from the exact method that uses the ILOG CPLEX 9.1 solver for 16 problem instances and the results obtained from the RGTS metaheuristic scheduling algorithm and two other algorithms proposed by other authors for the same problem instances are discussed. Analysis and comparisons are made.     

Counterexamples to a proposed algorithm for Fries structures of benzenoids

The Fries number of a benzenoid is the maximum number of benzenoid hexagons over all of its Kekulé structures (perfect matchings), and a Fries canonical structure is a perfect matching that realises this maximum. A recently published algorithm claims to determine Fries canonical structures of benzenoids via iterated Hadamard products based on the adjacency matrix (Ciesielski et?al. in Symmetry 2:1390–1400, 2010). This algorithm is re-examined here. Convergence is typically rapid and often yields a single candidate perfect matching, but the algorithm can give an exponential number of choices, of which only a small number are canonical. More worryingly, the algorithm is found to give incorrect results for the Fries number for some benzenoids with as few as seven hexagonal faces. We give a combinatorial reformulation of the algorithm in terms of linear combinations of perfect matchings (with weights at each stage proportional to the products of weights of the edges included in a matching). In all the cases we have examined, the algorithm converges to a maximum-weight matching (or combination of maximum-weight matchings), and where the algorithm fails, either no best Fries matching is of maximum weight, or a best Fries matching is of maximum weight but a sub-optimal matching of the same weight is chosen.     

交通产业链上企业工程项目成本控制的影响因素研究

一些企业以轨道交通产业为纽带形成了交通产业链,轨道交通产业链上的企业要注重对相关工程项目实施全过程中的成本控制.从产业链的视角出发,围绕财务指标、内部业务流程指标、客户指标、学习与成长能力指标这4个方面,构建了评价指标体系和成本控制指标体系.运用层次分析法和模糊综合评价法进行评价和分析,找出了影响轨道交通产业链上企业工程项目成本控制的主要因素.研究表明,有55%的人认为财务指标、内部业务流程指标、客户指标、学习与成长能力指标这4个因素对轨道交通工程项目成本控制的影响较大.     

强脉冲电磁场对金属凝固组织影响的研究

提出了用强脉冲磁场和电流细化金属凝固组织的新工艺.与未经磁场或电流处理的凝固样品相比,强脉冲电磁场能够显著地改善LY12铝合金的凝固组织,使晶粒明显细化、球化;电磁场的强度愈强,这种改善效果愈明显.对该新工艺的细化机理进行了理论分析,同时,指出了实验中的新现象和新问题.关键词：