Interfacial Activity of Amine‐Functionalized Polyhedral Oligomeric Silsesquioxanes (POSS): A Simple Strategy To Structure Liquids

Amine‐functionalized polyhedral oligomeric silsesquioxane (POSS), the smallest, monodisperse cage‐shaped silica cubic nanoparticle, is exceptionally interfacially active and can form assemblies that jam the toluene/water interface, locking in non‐equilibrium shapes of one liquid phase in another. The packing density of the amine‐functionalized POSS assembly at the water/toluene interface can be tuned by varying the concentration, the pH value, and the degree of POSS functionalization. Functionalized POSS gives a higher interface coverage, and hence a lower interfacial tension, than nanoparticle surfactants formed by interactions between functionalized nanoparticles and polymeric ligands. Hydrogen‐bonded POSS surfactants are more stable at the interface, offering some unique advantages for generating Pickering emulsions over typical micron‐sized colloidal particles and ligand‐stabilized nanoparticle surfactants.     

Slow epimerization of stereochemically rigid diastereomers of the equatorially substituted cluster [Os3H2(mu 3-S)(CO)8((S)-PhCHMeNH2)

Turnstile rotation is suppressed in the equatorially substituted cluster [Os3(mu-H)2(mu 3-S)(CO)8((S)-PhCHMeNH2)] which was separated by HPLC into two diastereomers which do not interconvert at room temperature and epimerize only slowly at 90 degrees C.     

REBUILDING THE EASTERN BALTIC COD STOCK UNDER ENVIRONMENTAL CHANGE–A PRELIMINARY APPROACH USING STOCK,ENVIRONMENTAL, AND MANAGEMENT CONSTRAINTS

ABSTRACT. . The population dynamics of the Eastern Baltic cod (Gadus morhua callarias L.), unlike many other stocks, shows a strong dependency on environmental conditions. To test the implications of different management policies on the stock and the fishery in a system of global environmental change, we apply a spatially disaggregated, discrete time, age‐structured model of the Eastern Baltic cod stock in 50 year simulation analyses. The simulation provides an analysis of stock, yield, and revenue development under various management policies and environmental scenarios. The policy analysis, focusing on different regulations of fishing mortality, is embedded into three environmental scenarios, assuming low, medium, or high climate and environmental change. The environmental assumptions are based on simulation results from a coupled atmosphere‐ocean regional climate model, which project salinity in the Baltic Sea to decrease by 7–47% in the period 2071–2100 relative to the reference period 1961 1990. Our simulation results show that a significant reduction in fishing mortality is necessary for achieving high long‐term economic yields. Moreover, under the environmental scenarios presented, a stock collapse cannot be prevented. It can, however, be postponed by the establishment of a marine reserve in ICES subdivision 25.     

Quality control of automotive engine oils with mass-sensitive chemical sensors – QCMs and molecularly imprinted polymers

Molecularly imprinted polyurethanes were used as sensor materials for monitoring the degradation of automotive engine oils. Imprinting with characteristic oils permits the analysis of these complex mixtures without accurately knowing their composition. Mass-sensitive quartz crystal microbalances (QCMs) coated with such layers exhibit mass effects in addition to frequency shifts caused by viscosity, which can be compensated by an uncoated quartz or a non-imprint layer. Incorporation of degradation products into the imprinted coatings is a bulk phenomenon, which is proven by variation of the sensor layer height. Therefore, the resulting sensor effects are determined by the degradation products in the oil. Received: 5 August 1999 / Revised: 26 October 1999 / Accepted: 1 November 1999     

Some topological dynamics properties of discrete-time control systems

This paper is concerned with the study of certain stabilityproperties of discrete-time systems by means of topologicalmethods. It turns out that suitably defined sets guarantee thestability of the reachable sets in the vicinity of compact sets.Furthermore, special properties about affine control systemsare given.     

REBUILDING THE EASTERN BALTIC COD STOCK UNDER ENVIRONMENTAL CHANGE (PART II): TAKING INTO ACCOUNT THE COSTS OF A MARINE PROTECTED AREA

Abstract This study adds a cost analysis of the Eastern Baltic cod fishery to the existing model presented in Röckmann et al. [2007a] . As cost data on this international fishery do not exist, data from Denmark are extrapolated to the whole international fishery. Additionally, unit and total variable costs are simulated, and the sensitivity to a set of different cost–stock and cost–output elasticities is tested. The study supports preliminary conclusions that a temporary marine reserve policy, which focuses on protecting the Eastern Baltic cod spawning stock in the International Council for the Exploration of the Sea (ICES) subdivision 25, is a valuable fisheries management tool to (i) rebuild the overexploited Eastern Baltic cod stock and (ii) increase operating profits. The negative effects of climate change can be postponed for at least 20 years—depending on the assumed rate of future climate change. Including costs in the economic analysis does not change the ranking of management policies as proposed in the previous study where costs were neglected.     

Nanoporous metal organic framework materials for hydrogen storage

Hydrogen is expected to play an important role in future transportation as a promising alternative clean energy source to carbon-based fuels.One of the key challenges to commercialize hydrogen energy is to develop appropriate onboard hydrogen storage systems,capable of charging and discharging large quantities of hydrogen with fast enough kinetics to meet commercial requirements.Metal organic framework (MOF) is a new type of inorganic and organic hybrid nanoporous particulate materials.Its diverse networks can enhance hydrogen storage through tuning the structure and property of MOFs.The MOF materials so far developed adsorb hydrogen through weak disperston interactions,which allow significant quantity of hydrogen to be stored at cryogenic temperatures with fast kinetics.Novel MOFs are being developed to strengthen the interactions between hydrogen and MOFs in order to store hydrogen under ambient conditions.This review surveys the development of such candidate materials,their performance and future research needs.