Structural characterisation of GaAlN/GaN HEMT heterostructures

(GaN/GaAlN/GaN)//Al₂O₃(00.1) HEMT heterostructures have been studied by X-ray scattering techniques, transmission electron microscopy and atomic force microscopy. X-ray reflectometry has been used to determine with a high accuracy both the individual layer thicknesses and the interfacial roughness, in spite of the weak electronic density contrast between layers. From the Fourier inversion method and using a simulation software, the roughness of the interface corresponding to the two-dimensional electron gas location has been determined equal to 0.5 nm. Both high resolution X-ray diffraction and transmission electron microscopy experiments have shown the excellent crystallinity of the heterostructures. Finally, the surface morphology has been inferred using atomic force microscopy experiments.     

Socketing of polyester fibre ropes with epoxy resins for deep-water mooring applications

The use of polyester (PET) fibre ropes in mooring applications for deep water oil platforms implies the use of terminations, e.g. the spliced eye, which demands specialized manual labour and is time consuming. This research evaluates the technical viability of substituting these terminations with a resin socketing procedure, which consists of introducing a simple-end rope in a hollow metallic device having a conical shape (i.e. a socket) and pouring into it a thermoset resin that, once cured, fastens the rope extremity. PET ropes (10 or 48 mm diameter) were socketed and evaluated under tensile testing. The curing and viscoelastic behaviour of various epoxy resin systems were monitored with DSC and DMA. The performance of socketed PET ropes was suitable for the intended application, showing failure loads similar to those of unsocketed ropes, being particularly dependant on resin type, socket conicity and resin/fibre volumetric ratio in it.     

Simple,fast, and low-contamination microwave-assisted digestion procedures for the determination of chemical elements in biological and environmental matrices by sector field ICP-MS

A simple and convenient method for the digestion of animal tissues, lichens, and plants for 33 metals measured by sector field inductively coupled plasma mass spectrometry (SF-ICP-MS) was described. Microwave-assisted acid digestions were performed at atmospheric pressure by means of a multi-samples rotor designed for processing a large number of samples at once in screw-capped disposable polystyrene liners. The digested samples were filled up to final volume directly in the polystyrene liners ready for elemental quantification. Seven certified reference materials, namely BCR 184 (bovine muscle), BCR 186 (pig kidney), DORM-2 (dogfish muscle), BCR 422 (cod muscle), BCR 62 (olive leaves), BCR 100 (beech leaves), and BCR 482 (lichen) were analysed to verify the accuracy of the method. The linearity range, limit of quantification, precision, and recovery by addition of non-certified elements were also assessed. All elements, with the exception of Hg in BCR 184 and As in BCR 186, were above the quantification limit and blank concentrations, and good agreement existed between found and target values in bovine muscle, pig kidney, and cod muscle. Significant deviations were observed for Al, Co, Cr, Mn, and Ni in dogfish muscle and for Ca, Cr, Fe, and Hg in lichens and plants. The proposed digestion procedure offers a low contamination risk, simplicity, speed, low cost, and applicability in routine analysis, and the SF-ICP-MS method allowed metals from a fraction of ng?g^?1 to hundreds of µg?g^?1 to be quantified in one analytical run.     

Capillary electrophoresis speciation analysis of various arsenical compounds

Separation of seven organic and inorganic arsenical species, i.e., inorganic arsenite (As III) and arsenate (As V), monomethylarsonic acid (MMA), dimethylarsinic acid (DMA), arsenobetaine (AsBet), arsenocholine (AsCh) and p-arsanilic acid (pAs) was carried out by capillary electrophoresis (CE) equipped with one of two different optical path cells, i.e., either the standard detection interface (SDI) or the high sensitive detection cell (HSDC). Separation, identification and quantification of the As species were performed by means of a capillary silica column with an alkaline borate buffer at pH 9.3 and direct UV detection at 192 nm. This methodological approach was tested with the abovementioned types of cells, and the results of the two modes were compared. In both cases, good separation was obtained, and also, repeatability in terms of migration times and peak areas was rather satisfactory. With regard to sensitivity, the HSDC allowed peak areas to be obtained, which were ca. 50 times greater than those afforded by the former cell. This also led to a substantial improvement in the limits of detection (LoDs); by a factor of 9 in the case of AsCh.     

Optimum reinforcement of a circular hole under an arbitrary stress system at infinity

Summary A circular hole is made in an infinite plane elastic sheet under a stress system which is constant at infinity. An optimum reinforcement is shown to exist and it is such that its weight is approximately equal to the weight of the material removed. For such reinforcement, when the principal stresses at infinity vary, the maximum value of the stress concentration factor at the boundary of the hole and its total variation are minimal.

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Sommario In uno strata elastico piano infinito, soggetto ad uno stato di tensione fondamentale costante, è praticato un foro circolare. Si dimostra che esiste un irrigidimento ottimale in corrispondenza del quale il peso del rinforzo è approssimativamente eguale a quello del materiale asportato nel praticare il foro. Per tale rinforzo sono minimi, al variare dello stato di tensione fondamentale, sia il massimo valore che può assumere il fattore di concentrazione degli sforzi lungo il bordo del foro, sia la variazione complessiva dello stesso.

     

Solid state NMR study of sodium thiocyanate/poly(ethylene oxide) electrolytes

¹H-, ¹³C-, ²³Na-solid state NMR measurements have been used to characterise the morphology and the dynamics of several NaSCN-PEO mixtures. Selective ¹³C-MAS experiments allowed to determine the composition of the (PEO)_nNaSCN samples in terms of the different phases present, as well as the real stoichiometry of the crystalline complex. ¹H- and ¹³C-spin-lattice relaxation times provided estimates of the dimensions of the different domains and gave information on the dynamics of the polymer chains. ²³Na-MAS spectra and 2D nutation experiments allowed to individuate the presence of different environments for the sodium cations on the basis of their quadrupolar interactions.     

Anion recognition in water with use of a neutral uranyl-salophen receptor

A new water-soluble uranyl-salophen complex incorporating two glucose units has been synthesized. This neutral derivative shows noteworthy binding affinity for fluoride in water thanks to the Lewis acid-base interaction occurring between the metal and the anion. Such interaction is strong enough to overcome the high hydration enthalpy of fluoride. Moreover this complex effectively binds hydrogen phosphate and exhibits remarkably strong association for nucleotide polyanions ADP(3-) and ATP(4-).     

A unified approach to invariants of plane elasticity tensors

The action of the orthogonal group \(O(2)\) on the space of plane elasticity tensors has been the subject of some recent investigations. It is shown here that the approach based on the “harmonic decomposition” technique, which is also used in a three-dimensional setting, gives a unified perspective on this issue. We construct explicit relationships between invariants and quantities derived from such an approach and what was found earlier by Tsai and Pagano and, more recently, through the “polar method” and the use of complex variables.     

Chromium isotopes tracking the resurgence of hexavalent chromium contamination in a past-contaminated area in the Friuli Venezia Giulia Region,northern Italy

The origin of a resurgent hexavalent chromium contamination in groundwater from a phreatic aquifer in the Friuli Venezia Giulia Region plain was investigated by chromium isotopic systematics. The area underwent a severe Cr(VI) contamination by industrial effluents in 1997, when Cr(VI) concentration in groundwater reached 4500?µg/L. In subsequent years the contamination naturally attenuated, totally disappearing in 2003. A renewal of water contamination was observed in 2008, Cr(VI) reaching 1560?µg/L. The δ⁵³Cr value in groundwater and extracts from sediments was measured in 2009–2011, and it ranges between ?3.21 and +0.21‰ and between ?4.71 and +1.26‰, respectively. Due to the lack of geogenic Cr-sources, these data are interpreted as evidence of the subsequent oxidation through Mn-oxides of the Cr(III) hosted in the aquifer and originated by the reduction of the original industrial chromates. Cr(III) is characterized by negative δ⁵³Cr, starting from the δ⁵³Cr value around zero of Cr(VI) in industrial effluents. Oxidation liberates soluble Cr(VI) which is transported by groundwater and permeated soils. The complex Cr-isotopic vs. concentration distribution reflects both the new Cr(VI) reduction and dilution processes in the aquifer system. From an environmental point of view, the data raise concerns regarding the potential impact of past Cr(VI)-contamination.