Influence of the formulation of catalysts deposited on cordierite monoliths for acetic acid oxidation

Monolithic catalysts are prepared by washcoating cordierite monoliths with different sols (Pt/Al₂O₃, Pt/CeO₂, Pt/ZrO₂, Pt/Al₂O₃CeO₂, Pt/Al₂O₃ZrO₂, and Pt/CeO₂ZrO₂). These sols are prepared by a sol–gel process and characterized by specific surface area (S_BET), inductively coupled plasma, hydrogen chemisorption, high-resolution transmission electron microscopy, field emission scanning electron microscopy, oxygen storage capacity, X-ray diffraction, temperature-programmed reduction, CO₂ chemisorption, and the model reaction of 3,3-dimethylbutene isomerization. The catalytic performances of the monolithic catalysts are then evaluated for the acetic acid oxidation. The nature of catalyst coating has been found to influence the adherence with the cordierite monolith and the presence of cerium in the catalyst appears to increase the adherence of the latter. Pt/CeO₂, Pt/Al₂O₃CeO₂, and Pt/CeO₂ZrO₂ are found to be the most reducible catalysts (oxygen storage capacity and temperature-programmed reduction) and to have the lowest acidities (3,3-dimethylbutene isomerization). CO₂ chemisorption shows that these catalysts possess a good basicity. From the relation established between the catalytic activity and the redox and acid–base properties it has been concluded that the reducibility is the key factor for a good catalytic activity although the basicity has a significant influence on the catalytic performance.     

Measurement of the spin correlationA ookk innp elastic scattering between 0.63 and 1.08 GeV

We present the measurements of the spin correlation parameterA _ookk (np). A longitudinally polarized beam of free neutrons obtained from the break-up of polarized deuterons was scattered on the longitudinally polarized Saclay frozen-spin proton target. Measurements were carried out at SATURNE II, at neutron beam kinetic energies of 0.63, 0.88, 0.98 and 1.08 GeV. The data points cover the angular region from about 40° to 110° CM. The observed angular dependence ofA _ookk (np) at 0.63 GeV agree with the phase shift analysis predictions except at small angles.     

Visualization of the hinge flow in a 5:1 scaled model of the medtronic parallel bileaflet heart valve prosthesis

 In this work, a flow visualization experiment was performed to elucidate features of the retrograde hinge flow through a 5 : 1 scaled model of the Medtronic Parallel bileaflet heart valve. It was hypothesized that this model would provide detailed flow information facilitating identification of flow structures associated with thrombus formation in this valve. The experimental protocol was designed to ensure fluid dynamic similarity between the model and prototype heart valves. Flow was visualized using dye injection. The detailed flow structures observed showed the hinge’s inflow channel was the most suspect region for thrombus formation. Here a complex helical structure was observed. Received: 27 October 1997/Accepted: 1 May 1998     

Neutron matter densities in the even Ni isotopes

Elastic scattering of 1.047 GeV protons is studied on the isotopically enriched ^58,60,62,64Ni isotopes. A spin independent Glauber theory analysis allowed the extraction of nuclear matter densities for these targets.     

Measurement of ΔσL in pp scattering between 200 and 583 MeV

The main structure around m = 2.15 GeV first observed by the Argonne group in the spin-dependent total cross section Δσ_L is confirmed in the energy range available at SIN. A simultaneous study of the scattered particles at small angles has been carried out with success and gave the spin-correlation parameter A_00kk for the pp elastic scattering and for the reaction pp → π⁺d. The contribution of the 3-body reactions to this spin-dependent total cross section has been deduced and found to be lower than the contribution of the π⁺d reaction even at 583 MeV.     

On the geometrical aspects of electromagnetism,I

The trajectory of a charged test particle under a Lorentz force is obtained as the geodesic of a riemannian four dimensional manifold. Originally, the geodesic equation is nonlinear in some vector field A′_μ. The nonlinearity is traded in for the correct characteristic $\text{e}\text{m}$ of the test particle through a gauge condition, imposed upon A′_μ, which turns the geodesic into the fully covariant linear and gauge invariant Lorentz equation. Fitting the $\text{e}\text{m}$ ratio inside the gauge leaves F′_μν independent of $\text{e}\text{m}$ and allows its identification with the E.-M. tensor F_μν. This four dimensional approach allows the identification of the fifth coordinate used in Kaluza's geometrization |1,2|. The gauge function appears as the sum of Hamilton-Jacobi function plus an additional term, related to the “length” of the trajectory. It is this latter term which guarantees the correct “normalisation” of the $\text{e}\text{m}$ ratio.     

Observation of leading particles in pp interactions with large transverse momentum secondaries at the CERN-ISR

Events with a positive particle of large transverse momentum emitted at medium angles have been studied using the split field magnet spectrometer at the CERN-ISR at a c.m. energy of √s = 52.5 GeV. Positive particles with large longitudinal momentum, |x| > 0.5, i.e., leading particles, associated to large p_T events, are analysed.