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51.
Krasutsky PA Kolomitsyn IV Kiprof P Carlson RM Fokin AA 《The Journal of organic chemistry》2000,65(13):3926-3933
Selective oxidative cleavage-cyclization of adamantane through the bridge carbon was developed in trifluoroperacetic acid (TFPAA). The methyl group in the bridge position was found to be the substituent that directs consecutive oxygen insertion into the cage structure during the course of a Criegee rearrangement. The formation of stable 5-methyl-4,6-dioxabishomoadamant-5-yl cation at -25 degrees C was observed. Stable carboxonium ion formation allows control of the selectivity of further transformations. Hydrolysis leads to the stereospecific formation of endo,endo-3-hydroxy-7-acetoxybicyclo[3.3. 1]nonane. Its single-crystal X-ray structure was obtained. An increase in temperature results in deprotonation of the 5-methyl-4, 6-dioxabishomoadamant-5-yl cation to endo-3-trifluoroacetoxybicyclo[3.3.1]non-6-ene, which undergoes further epoxidation with TFPAA and acidic transannular cyclization in trifluoroacetic acid (TFAA). The described reactions can be used as a convenient method for the synthesis of bicyclo[3.3.1]nonane and oxaadamantane derivatives. The proposed mechanism for each transformation, as well as supporting ab initio theoretical calculations of the strain energy and the stabilization energy of the relevant oxacage structures, are discussed. 相似文献
52.
A. V. Fokin V. I. Dyachenko V. D. Sviridov A. Yu. Sizov N. D. Chkanikov 《Russian Chemical Bulletin》1996,45(5):1178-1181
C-Hydroxy- andC-aminoalkylation of iminodibenzyl, iminostilbene, phenoxazine, and phenothiazine with hexafluoroacetone, methyl trifluoropyruvate, and their trifluoroacetylimines were investigated. The substitution occurred at one or severalpara- andortho-positions to the N atom of the heterocycles. In the case of methyl trifluoropyruvate and its derivative the substitution in theortho-position was accompanied by the formation of lactams.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1239–1242, May, 1996. 相似文献
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54.
A. E. Zelenin N. D. Chkanikov A. F. Kolomiets A. V. Fokin 《Russian Chemical Bulletin》1988,37(1):110-116
1. | Depending on the ratio of the reactants in the reaction of indoline with hexafluoro-acetone and with methyl trifluoropyruvate, mono- and di-C5,7 alkylation products of indoline, and also tri-C3,5,7-alkylated indoline are formed. |
2. | By dehydrogenation of the products of C-alkylation of indoline with trifluorocarbonyl compounds a number of substituted indoles have been prepared. |
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56.
A. V. Fokin A. F. Kolomiets Yu. N. Studnev A. I. Rapkin V. I. Yakutin 《Russian Chemical Bulletin》1972,21(5):1172-1173
Conclusions The acid chlorides and acid fluorides of halocarboxylic acids under mild conditions enter into exchange reactions with trimethylthiocyanosilane and tetrathiocyanotin to give the isothiocyanates of halocarboxylic acids.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1210–1211, May, 1972. 相似文献
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59.
Burmasov V. S. Dolgov-Savel'ev G. G. Knyazev B. A. Fokin E. P. 《Journal of Applied Spectroscopy》1973,19(3):1230-1232
Journal of Applied Spectroscopy - 相似文献
60.