Imines in the Titanium Coordination Sphere – Transformation of Imidoyl Chlorides to Nitrilium Ions

In the reaction of TiCl₄ in benzene as solvent with the imidoyl chloride p‐Tolyl(Cl)C=NPh ( 1 ) the abstraction of the chloride substituent is observed, leading to the nitrilium salt [p‐Tolyl–C≡N–Ph]⁺[Ti₂Cl₉]^– ( 2 ) in quantitative yield. The highly electrophilic salt 2 is characterized by IR‐ and NMR spectroscopy. The observed band for the C≡N stretching mode of 2 clearly indicates the formation of a nitrilium ion. Especially a characteristic line broadening of the ¹³C{¹H}‐NMR signals related to carbon atoms next to the nitrogen is observed. By ¹⁵N,¹H‐HMBC NMR experiments it is shown that the nitrogen signal of 2 is significantly shifted to high‐field in relation to nitriles and imines. The molecular structure of 2 was confirmed by single‐crystal X‐ray diffraction. The C≡N bond length and the linearity of the C–C≡N–C unit in 2 confirm the triple bond character of this bond.     

Self–gravitating fluid flows with Gowdy symmetry near cosmological singularities

We consider self-gravitating fluids in cosmological spacetimes with Gowdy symmetry on the torus T³ and, in this class, we solve the singular initial value problem for the Einstein–Euler system of general relativity, when an initial data set is prescribed on the hypersurface of singularity. We specify initial conditions for the geometric and matter variables and identify the asymptotic behavior of these variables near the cosmological singularity. Our analysis of this class of nonlinear and singular partial differential equations exhibits a condition on the sound speed, which leads us to the notion of sub-critical, critical, and super-critical regimes. Solutions to the Einstein–Euler systems when the fluid is governed by a linear equation of state are constructed in the first two regimes, while additional difficulties arise in the latter one. All previous studies on inhomogeneous spacetimes concerned vacuum cosmological spacetimes only.     

Determination of a Constitutive Friction Law Using an Elastic-Plastic Half-Space Model

Friction influences metal forming processes both in economic and technical terms. A precise understanding of friction is inevitable as friction restricts the potential of the product design. Friction depends on the occurring contact loads which is especially true for sheet-bulk metal forming (SBMF) as the incorporated contact loads appear in a very broad range. Numerical simulations, which are verified experimentally, are carried out to analyse contact interactions which typically appear in SBMF. On the one hand the multi-scale character of rough surfaces requires a very fine resolution of the contact area, on the other hand a large contact area is necessary to be representative. A half-space model is chosen for the contact analysis, because it only depends on the two-dimensional surface boundary which consumes less computing capacity than the finite element method (FEM) with its three-dimensional volume approach for the same surface resolution and area. The outcome is a constitutive friction law (CFL) consisting of two equations. The law is implemented into the framework of FEM to see the impact in a typical SBMF-process which aims to form metal sheet into cups with integrated gearing teeth. (© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Characterisation of filled rubber with a pronounced non-linear viscoelasticity

This contribution presents the characterisation of an incompressible carbon black-filled elastomer as one characteristical example for highly filled rubber. It shows a strongly pronounced non-linear viscoelastic behaviour and the most important characteristic is the extremely long relaxation time which has to be taken into account. The material model is developed with respect to uniaxial tension data. The basis in the development of a phenomenological model is given by the basic elasticity. For this evaluation the long term relaxation behaviour results in a complex experimental procedure. Therefore, special attention has to be paid according to an optimised experimental process in order to get the necessary reference data in an adequate and reproduceable way [1]. With this model basis further investigations are taken into account concerning the time-dependent viscoelasticity. Therefore, cyclic deformations from zero up to a maximum of deformation are considered for different strain rates. Furthermore, the relaxation behaviour is investigated for multiple strain levels. The phenomena which are observed in the experimental results yield in a purely viscoelastic model, based on a rheological analogous model consisting of an equilibrium spring and several Maxwell-elements which contain nonlinear relations for the relaxation times of the dashpot elements [1,2]. The material model's numerical realisation is accomplished in two ways. Because of its numerical simplicity especially according to the parameter identification the model is restricted only to the simple case of uniaxial tension. A second, alternative implementation is executed providing the benefit that more complex deformation conditions can also be taken into account. Therefore, the general, three-dimensional finite model is implemented in an open-source Finite Element library [3]. (© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

On a metric for the class of compact convex sets

A distance function, defined in [12], for the class of compact convex sets inn-space is introduced in a new way, and some of its properties are developed. This concept is compared with some traditional distance functions for convex sets.     

Toric partial density functions and stability of toric varieties

Let $(L, h)\rightarrow (X, \omega )$ denote a polarized toric Kähler manifold. Fix a toric submanifold $Y$ and denote by $\hat{\rho }_{tk}:X\rightarrow \mathbb {R}$ the partial density function corresponding to the partial Bergman kernel projecting smooth sections of $L^k$ onto holomorphic sections of $L^k$ that vanish to order at least $tk$ along $Y$ , for fixed $t>0$ such that $tk\in \mathbb {N}$ . We prove the existence of a distributional expansion of $\hat{\rho }_{tk}$ as $k\rightarrow \infty $ , including the identification of the coefficient of $k^{n-1}$ as a distribution on $X$ . This expansion is used to give a direct proof that if $\omega $ has constant scalar curvature, then $(X, L)$ must be slope semi-stable with respect to $Y$ (cf. Ross and Thomas in J Differ Geom 72(3): 429–466, 2006). Similar results are also obtained for more general partial density functions. These results have analogous applications to the study of toric K-stability of toric varieties.     

A generalization of regula falsi

Summary The method of nondiscrete mathematical induction is applied to a multistep variant of the secant method. Optimal conditions for convergence as well as error estimates, sharp in every step, are obtained.     

Up to isometries,a deformation is a continuous function of its metric tensorAux isométries près,une déformation est une fonction continue de son tenseur métrique

If the Riemann–Christoffel tensor associated with a field of class $\text{C}{}^2$ of positive definite symmetric matrices of order three vanishes in a connected and simply connected open subset $\text{Ω?}\text{R}{}^3$, then this field is the metric tensor field associated with a deformation of class $\text{C}{}^3$ of the set $\text{Ω}$, uniquely determined up to isometries of $\text{R}{}^3$. We establish here that the mapping defined in this fashion is continuous, for ad hoc metrizable topologies. To cite this article: P.G. Ciarlet, F. Laurent, C. R. Acad. Sci. Paris, Ser. I 335 (2002) 489–493.     

Strong immersion is a well-quasi-ordering for semicomplete digraphs

We prove that the strong immersion order is a well-quasi-ordering on the class of semicomplete digraphs, thereby strengthening a result of Chudnovsky and Seymour (2011, J. Comb. Theory, Series B, 101, 47–53) that this holds for the class of tournaments.