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101.
102.
Frauke Schimmele Christiane Kaiser Susanne Pitsch Helmut Sitzmann 《Chemie in Unserer Zeit》2016,50(4):234-243
Reactions of the alkaline earth metals magnesium, calcium, strontium, and barium with water, phenolphthalein solution, diluted extract of red cabbage, diluted hydrochloric acid, or ammonia are well suited for a demonstration of the increase in reactivity within this group of metals with increasing atomic number. If the alkali metals lithium and sodium are included, the reactivity of six s‐block elements can be demonstrated in test tubes with small amounts of chemicals. 相似文献
103.
Susanne Bomke Michael Sperling Uwe Karst 《Analytical and bioanalytical chemistry》2010,397(8):3483-3494
Over the last few decades, the development of several innovative hyphenated analytical techniques and their routine use in
laboratories has led to new possibilities for the quantitative analysis of biomolecules. Today, the identification and quantification
of biomolecules such as peptides and proteins are essential to answer important medical, pharmaceutical, and biological questions.
To allow efficient detection and structure elucidation of biomolecules, several approaches including derivatization strategies
were investigated and applied during recent years. This article summarizes the current approaches for labeling and presents
the different types of organometallic derivatizing agents used as labels. Furthermore, their analytical potential with respect
to quantification and structure elucidation for different applications in the field of bioanalysis is discussed. 相似文献
104.
Christoph Stampfer Stefan Fringes Johannes Gfittinger Francoise Molitor Christian Yolk Bernat Terrds Jan Dauber Stephan Engels Stefan Schnez Arnhild Jacobsen Susanne Droscher Thomas Ihn Klaus Ensslin 《Frontiers of Physics》2011,6(3):271-293
Graphene nanostructures are promising candidates for future nanoelectronics and solid-state quantum information technology. In this review we provide an overview of a number of electron transport experiments on etched graphene nanostructures. We briefly revisit the electronic properties and the transport characteristics of bulk, i.e., two-dimensional graphene. The fabrication techniques for making graphene nanostructures such as nanoribbons, single electron transistors and quantum dots, mainly based on a dry etching ??paper-cutting?? technique are discussed in detail. The limitations of the current fabrication technology are discussed when we outline the quantum transport properties of the nanostructured devices. In particular we focus here on transport through graphene nanoribbons and constrictions, single electron transistors as well as on graphene quantum dots including double quantum dots. These quasi-one-dimensional (nanoribbons) and quasi-zero-dimensional (quantum dots) graphene nanostructures show a clear route of how to overcome the gapless nature of graphene allowing the confinement of individual carriers and their control by lateral graphene gates and charge detectors. In particular, we emphasize that graphene quantum dots and double quantum dots are very promising systems for spin-based solid state quantum computation, since they are believed to have exceptionally long spin coherence times due to weak spin-orbit coupling and weak hyperfine interaction in graphene. 相似文献
105.
Susanne Friedreich D��niel Barna Andreas Dax Ryu Hayano Dezs? Horv��th Masaki Hori Bertalan Juh��sz Oswald Massiczek Anna S��t��r Thomas Pask Eberhard Widmann 《Hyperfine Interactions》2011,199(1-3):337-346
The spin magnetic moment $\mu^{\overline{p}}_{s}$ of the antiproton can be determined by comparing the measured transition frequencies in $\overline{p}^4$ He?+? with three-body QED calculations. A comparison between the proton and antiproton can then be used as a test of CPT invariance. The highest measurement precision of the difference between the proton and the antiproton spin magnetic moments to date is 0.3%. A new experimental value of the spin magnetic moment of the antiproton was obtained as $\mu^{\overline{p}}_{s} = -2.7862(83)\mu_{N}$ , slightly better than the previously best measurement. This agrees with $\mu^{p}_{s}$ within 0.24%. In 2009, a new measurement with antiprotonic 3He has been started. A comparison between the theoretical calculations and experimental results would lead to a stronger test of the theory and address systematic errors therein. A measurement of this state will be the first HF measurement on $\overline{p}^3$ He?+?. We report here on the new experimental setup and the first tests. 相似文献
106.
107.
Prof. Dr. Lena Keller Dr. Emilia Oueis Dr. Amninder Kaur Dr. Nasim Safaei Dr. Susanne H. Kirsch Dr. Antonia P. Gunesch Dr. Sibylle Haid Dr. Ulfert Rand Prof. Dr. Luka Čičin-Šain Dr. Chengzhang Fu PD Dr. Joachim Wink Prof. Dr. Thomas Pietschmann Prof. Dr. Rolf Müller 《Angewandte Chemie (International ed. in English)》2023,62(6):e202214595
A new family of highly unusual sesquarterpenoids (persicamidines A–E) exhibiting significant antiviral activity was isolated from a newly discovered actinobacterial strain, Kibdelosporangium persicum sp. nov., collected from a hot desert in Iran. Extensive NMR analysis unraveled a hexacyclic terpenoid molecule with a modified sugar moiety on one side and a highly unusual isourea moiety fused to the terpenoid structure. The structures of the five analogues differed only in the aminoalkyl side chain attached to the isourea moiety. Persicamidines A–E showed potent activity against hCoV-229E and SARS-CoV-2 viruses in the nanomolar range together with very good selectivity indices, making persicamidines promising as starting points for drug development. 相似文献
108.
Fabian Hoffmann Dr. Anna-Lena Leistner Dr. Susanne Kirchner Prof. Dr. Burkhard Luy Dr. Claudia Muhle-Goll Dr. Zbigniew Pianowski 《European journal of organic chemistry》2023,26(20):e202300227
Photochromic supramolecular hydrogels are prospective materials for light-triggered drug release and bionanotechnology. Here we present a structural analysis of peptide-derived photochromic supramolecular hydrogels, which were physically loaded with a selection of biologically related compounds, using advanced techniques of nuclear magnetic resonance. The results enable detailed and correct understanding of the loading process and will allow for correct design of pharmacologically relevant systems for phototriggered drug delivery. 相似文献
109.
This note aims to subsume several apparently unrelated models under a common framework. Several examples of well-known quantum field theories are listed which are connected via stochastic quantization. We highlight the fact that the quantization method used to obtain the quantum crystal is a discrete analog of stochastic quantization. This model is of interest for string theory, since the (classical) melting crystal corner is related to the topological A-model. We outline several ideas for interpreting the quantum crystal on the string theory side of the correspondence, exploring interpretations in the Wheeler–De Witt framework and in terms of a non-Lorentz invariant limit of topological M-theory. 相似文献
110.
David Moe Almenningen Brita Susanne Haga Henrik Erring Hansen Dr. Audun Formo Buene Prof. Dr. Bård Helge Hoff Prof. Dr. Odd Reidar Gautun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(51):e202201726
Designing and evaluating novel dye concepts is crucial for the development of the field of dye-sensitized solar cells (DSSCs). In our recent report, the novel concept of tethering the anti-aggregation additive chenodeoxycholic acid (CDCA) to dyes for DSSC was introduced. Based on the performance improvements seen for this modification, the aim of this study is to see if a simplified anti-aggregation unit could achieve similar results. The following study reports the synthesis and photovoltaic characterization of two novel dyes decorated with the steric ethyladamantyl moiety on the π-spacer, and on the triarylamine donor. This modification is demonstrated to be successful in increasing the photovoltages in devices employing copper-based electrolytes compared to the non-modified reference dye. The best photovoltaic performance is achieved by a device prepared with the adamantyl decorated donor dye and CDCA, this device achieves a power conversion efficiency of 6.1 % (Short-circuit current=8.3 mA cm−2, Open-circuit voltage=1054 mV, Fill factor=0.69). The improved photovoltaic performance seen for the adamantyl decorated donor demonstrate the potential of ethyladamantyl side chains as a tool to ensure surface protection of TiO2. 相似文献