For large-particulated fluids encountered in natural debris flow, building materials, and sewage treatment, only a few rheometers
exist that allow the determination of yield stress and viscosity. In the present investigation, we focus on the rheometrical
analysis of the ball measuring system as a suitable tool to measure the rheology of particulated fluids up to grain sizes
of 10 mm. The ball measuring system consists of a sphere that is dragged through a sample volume of approximately 0.5 l. Implemented
in a standard rheometer, torques exerted on the sphere and the corresponding rotational speeds are recorded within a wide
measuring range. In the second part of this investigation, six rheometric devices to determine flow curve and yield stress
of fluids containing large particles with maximum grain sizes of 1 to 25 mm are compared, considering both rheological data
and application in practical use. The large-scale rheometer of Coussot and Piau, the building material learning viscometer
of Wallevik and Gjorv, and the ball measuring system were used for the flow curve determination and a capillary rheometer,
the inclined plane test, and the slump test were used for the yield stress determination. For different coarse and concentrated
sediment–water mixtures, the flow curves and the yield stresses agree well, except for the capillary rheometer, which exhibits
much larger yield stress values. Differences are also noted in the measuring range of the different devices, as well as for
the required sample volume that is crucial for application. 相似文献
Summary: We describe the development of different drop‐on‐demand systems particularly for applications for the liquid handling of biopolymers. Different designs of drop‐on‐demand systems developed by the authors are described. Experiments with these systems show the applicability for pipetting different liquids with different properties. Commercially available systems are also tested. A comparison of the different approaches leads to a discussion of the best fields of application of the different approaches or, alternatively, to the potential further development of the drop‐on‐demand technologies.
More Precise knowledge of the growth mechanism of garnets in form of epitaxial layers or single crystals in high temperature solutions on the base of trivalent oxides Me2O3 in PbO B2O3 solvent is desirable. Data of physicochemical properties of the melts especially density, shear viscosity, and electrical conductivity and their dependence on the temperature are useful in endeavour to recognize the structural principles of oxidie melts. Therefore as a first step the binary system PbO Ga2O3 was investigated to understand the influence of the Ga component on a complete mixed garnet solution, for instance (Y, Sm)3 (Fe, Ga)5O12 in PbO B2O3 solvent. 相似文献
A DTA-apparatus is described which is suitable for solubility measurements of garnets in flux melts. It is important that the temperature will be measured as near as possible to the crystallization region. Solubility temperatures are measured with an uncertainty ≦ 10 deg. A mixture of PbO, PbF2 and B2O3 was used as solvent. The following garnet systems were investigated: Y3Fe5−xMxO12 (M = Ga, Al, In, Cr; x = 0 …︁ 5) and Gd3Ga5O12. If results of other authors are available they are in good agreement with our data. Habit and chemical analysis of crystallites give informations about the grown phases and their composition. In connexion with the solubility thus it is possible to select appropriate solvents. 相似文献
Published crystal structures of the AEL-type aluminophosphate AlPO-11 in its calcined form (space group ) show some peculiar features, such as unusually short Al−O and P−O bonds and near-linear Al−O−P angles. Although experimental evidence for the presence of dynamic disorder was presented, the nature of the associated distortions remained unresolved. In this study, ab initio molecular dynamics (AIMD) calculations in the framework of density functional theory (DFT) were employed to study the dynamic behaviour of this zeotype. At 100 K, static local distortions that break the symmetry are present in the time-averaged structures computed from the AIMD trajectories. At 300 and 500 K, the time-averaged structures approach symmetry. Although shortened Al−O and P−O bonds and near-linear Al−O−P angles were found in the average structures, an analysis of radial and angular distribution functions confirmed their absence in the instantaneous structures. This deviation is due to a precession-like motion of some oxygen atoms around the Al−P connection line, which moves their time-averaged positions closer to this line. In hydrated AlPO-11, some of the water molecules are coordinated to framework Al atoms, leading to an octahedral coordination of 1/5 of the Al sites. DFT optimisations and AIMD simulations on partially hydrated models delivered evidence for a preferential adsorption at the Al1 site. No dynamic disorder was observed for the hydrated form. 相似文献
Computational Optimization and Applications - It is well-recognized that in the presence of singular (and in particular nonisolated) solutions of unconstrained or constrained smooth nonlinear... 相似文献