全文获取类型
收费全文 | 3519篇 |
免费 | 121篇 |
国内免费 | 3篇 |
专业分类
化学 | 1902篇 |
晶体学 | 76篇 |
力学 | 112篇 |
数学 | 858篇 |
物理学 | 695篇 |
出版年
2023年 | 24篇 |
2022年 | 43篇 |
2021年 | 69篇 |
2020年 | 113篇 |
2019年 | 106篇 |
2018年 | 188篇 |
2017年 | 162篇 |
2016年 | 211篇 |
2015年 | 134篇 |
2014年 | 198篇 |
2013年 | 463篇 |
2012年 | 227篇 |
2011年 | 239篇 |
2010年 | 214篇 |
2009年 | 161篇 |
2008年 | 219篇 |
2007年 | 196篇 |
2006年 | 102篇 |
2005年 | 60篇 |
2004年 | 52篇 |
2003年 | 53篇 |
2002年 | 49篇 |
2001年 | 46篇 |
2000年 | 30篇 |
1999年 | 20篇 |
1998年 | 28篇 |
1997年 | 24篇 |
1996年 | 15篇 |
1995年 | 6篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1991年 | 6篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1986年 | 6篇 |
1985年 | 14篇 |
1984年 | 20篇 |
1983年 | 9篇 |
1982年 | 6篇 |
1981年 | 8篇 |
1980年 | 6篇 |
1978年 | 8篇 |
1977年 | 4篇 |
1976年 | 6篇 |
1975年 | 7篇 |
1974年 | 6篇 |
1970年 | 4篇 |
1969年 | 5篇 |
1968年 | 4篇 |
1967年 | 5篇 |
排序方式: 共有3643条查询结果,搜索用时 15 毫秒
101.
Trinitrotoluene, known as TNT, is a widely used powerful explosive. It is a poisonous material, which injures almost all cells, especially those of liver, bone marrow, and kidney. Estrone is a sex hormone having an electron rich aromatic (phenolic) ring that is capable of forming a π complex with molecules containing an electron deficient π system. This study has focused on investigating the tendency of the complex formation of TNT with estrone. It has been thought that the formation of estrone‐TNT π complex might take place in a human body exposed to acute or prolong period of this hazardous chemical and consequently estrone activities might be impaired. The complex formation reaction was investigated mainly using DFT method with B3LYP/6‐31G(d, p) basis set in gas phase. The existence of π interaction between estrone and TNT was demonstrated by computational spectroscopic analyses (UV/Vis, IR, and 1H NMR techniques). The frontier molecular orbital (HOMO and LUMO) analyses have shown that the considered π complex is very resistant to oxidation with respect to its components, estrone and TNT. 相似文献
102.
A series of piperidoimidazolinium salts which differ in the chain lengths (butyl, octyl, dodecyl, octadecyl) and their Pd–N‐heterocyclic carbene complexes with pyridine were synthesized and characterized using elemental analysis and spectroscopic methods. The effects of these ligands on catalyst activation and the performance of the complexes were studied in Suzuki–Miyaura reactions of arylboronic acid with aryl chlorides. The complex with the ligand having the longest chain length was found to be most active. The results demonstrated that the length of the alkyl chain of the piperidoimidazolin‐2‐ylidene controlled the dispersion and composition of the nanoparticles and it affected the catalytic activity. The impact of alkyl chain length of piperidoimidazolin‐2‐ylidene on the Suzuki–Miyaura reactions of arylboronic acid with aryl halides was systematically investigated. 相似文献
103.
We analyze the structural behavior of a single polymer chain inside an attractive sphere. Our model is composed of a coarse-grained polymer governed by Lennard-Jones interactions of the monomers and an attractive sphere potential which follows by integrating the monomer-monomer interaction over the (inner) surface of the sphere. By means of extensive multicanonical Monte Carlo simulations it is shown that the system exhibits a rich phase diagram in the adsorption strength-temperature (ε ? T) plane ranging from highly ordered and compact to extended and random coil structures and from desorbed to partially or even completely adsorbed conformations. These findings are identified with different energetic and structural observables. The resulting phase diagram in the ε ? T plane is compared with that for a polymer adsorbing to a plane, attractive substrate obtained previously by Möddel, Bachmann, and one of the authors. 相似文献
104.
105.
106.
107.
108.
109.
110.