InAs–GaAs self-assembled quantum dot lasers: physical processes and device characteristics

The gain characteristics of InAs–GaAs self-assembled quantum dot lasers are studied using two complementary techniques. The modal gain is derived from a measurement of the normal incidence, inter-band photoconductivity. For a device containing a single layer of dots the maximum modal gain of the ground state transition is found to be insufficient for lasing action. As a consequence lasing occurs for excited state transitions, which have a larger oscillator strength, with the precise transition being dependent upon the device cavity length. The second technique uses the Hakki–Paoli method to determine the spectral and current dependence of the gain. A quasi-periodic modulation of the below threshold gain is observed. This modulation is shown to be responsible for the form of the lasing spectra, which consist of groups of lasing modes separated by non-lasing spectral regions. Possible mechanisms for this behaviour are discussed.     

Two-Dimensional Supramolecular Polymerization of DNA Amphiphiles is Driven by Sequence-Dependent DNA-Chromophore Interactions

Two-dimensional (2D) assemblies of water-soluble block copolymers have been limited by a dearth of systematic studies that relate polymer structure to pathway mechanism and supramolecular morphology. Here, we employ sequence-defined triblock DNA amphiphiles for the supramolecular polymerization of free-standing DNA nanosheets in water. Our systematic modulation of amphiphile sequence shows the alkyl chain core forming a cell membrane-like structure and the distal π-stacking chromophore block folding back to interact with the hydrophilic DNA block on the nanosheet surface. This interaction is crucial to sheet formation, marked by a chiral “signature”, and sensitive to DNA sequence, where nanosheets form with a mixed sequence, but not with a homogeneous poly(thymine) sequence. This work opens the possibility of forming well-ordered, bilayer-like assemblies using a single DNA amphiphile for applications in cell sensing, nucleic acid therapeutic delivery and enzyme arrays.