Coupled high Q-factor surface nanoscale axial photonics (SNAP) microresonators

We experimentally demonstrate series of identical two, three, and five coupled high Q-factor surface nanoscale axial photonics (SNAP) microresonators formed by periodic nanoscale variation of the optical fiber radius. These microresonators are fabricated with a 100 μm period along an 18 μm radius optical fiber. The axial FWHM of these microresonators is 80 μm and their Q-factor exceeds 10(7). In addition, we demonstrate a SNAP microresonator with the axial FWHM as small as 30 μm and the axial FWHM of the fundamental mode as small as 10 μm. These results may potentially enable the dense integration of record low loss coupled photonic microdevices on the optical fiber platform.     

Enthalpies of the dissolution and dilution of aqueous solutions of rubidium and cesium diclofenac at 293.15–318.15 K

Enthalpies of the dissolution and dilution of aqueous solutions of rubidium and cesium diclofenac (RbDC and CsDC) are measured at 293.15, 298.15, 308.15, and 318.15 K at concentrations of water of less than 0.1 mol/kg. The heat capacity of RbDC and CsDC crystal salts is determined. Changes in the thermodynamic properties of both a solution and its components vs. concentration and temperature is considered. An increase in the endothermicity of the dissolution of RbDC and CsDC with a rise in temperature is noted. It is shown that the dissolution of both RbDC and CsDC electrolytes in water is determined by the contribution from entropy. It is shown that in aqueous solutions of RbDC and CsDC, the degree of binding of water molecules is higher than in pure water at temperatures below 303.15 K.     

Vibrational study on the cobalt binding mode of Carnosine

The Co(II)-l-Carnosine (Carnos) system was investigated at different pH and metal/ligand molar ratios by Raman and IR spectroscopy. Raman spectra present some marker bands yielding information on the ability of the Co(II)/Carnos system to bind molecular oxygen and to identify the metal co-ordination site of the imidazole ring (N_π or N_τ atom) of Carnos.The existence of different oxygenated species is greatly affected by pH and the structure of the predominant complexes depends on the available nitrogen atoms. Under basic conditions, binuclear complexes binding molecular oxygen are the predominant species and two forms (monobridged and dibridged) were identified by the Raman νO-O band (750-850 cm⁻¹).Decreasing pH to 7, the species present in the system are less able to bind oxygen. Hydrogen peroxide and a Co(III) chelate not binding O₂, were formed with a significant conversion of peroxo into superoxo complexes. A slight excess of Carnos does not enhance metal chelation.In slightly acidic conditions, the formation of H₂O₂ and superoxo species is more enhanced than at pH 7 and another Co(III) chelate is probably formed.     

A pseudospectral method for nonlinear Duffing equation involving both integral and non‐integral forcing terms

The Legendre pseudospectral method is developed for the numerical solution of nonlinear Duffing equation involving both integral and non‐integral forcing terms. By using differentiation matrix, the problem is reduced to the solution of a system of algebraic equations. The method is general, easy to implement, and yields very accurate results. Numerical experiments are presented to demonstrate the accuracy and the efficiency of the proposed computational procedure. Copyright © 2014 John Wiley & Sons, Ltd.