About Cosmic Ray Sources in Galaxy

Physics of Atomic Nuclei - In the last two decades the new experimental data on cosmic rays concerning energy spectra in a wide energy range up to 10 $${}^{14}$$ eV, isotropy, ratio of positron...     

Numerical modeling of thermocapillary convection in a fluid layer with local heating of the free surface

Thermocapillary convection in a plane horizontal fluid layer with concentrated heating of the free surface is modeled numerically using the Navier-Stokes equations and the heat transport equation. This makes it possible to examine the structure of the convection throughout the fluid volume, in particular in the region where the motion is weak. The deformation of the free surface is assumed to be negligibly small. In the case of a ponderable fluid this assumption is justified given certain upper and lower constraints on the temperature difference and the thickness of the layer, respectively, [9, 10]. Under conditions of weightlessness a fluid layer of constant thickness in a rectangular channel can be realized at a contact angle of 90° [7].Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 108–113, July–August, 1987.     

Molecular and hydrodynamic characteristics of star-shaped polystyrenes with one or two fullerene (C<Subscript>60</Subscript>) molecules as a branching center

The molecular properties of regular star-shaped polystyrenes with different numbers of arms (6, 12, and 22) and different structures of the branching center (one or two covalently bonded fullerene C60 molecules) are studied by static light scattering; translational diffusion; and viscometry in toluene, THF, and chloroform. The lengths of the arms for the studied polymer stars are found to be the same. (The molecular mass of the arm is 8.1 × 10³.) The molecular mass and hydrodynamic sizes of macromolecules are estimated. It is shown that the conformational and hydrodynamic characteristics of polymer stars remain practically unchanged on passage from THF to chloroform. Compared to the linear analog, star-shaped fullerene-containing PSs are characterized by a higher density of the molecular coil. The shape of their macromolecules differs insignificantly from spherical, in consistence with theoretical predictions for polymer stars with relatively short arms.     

Hydrodynamic,optical, and electrooptical properties of macromolecules of third-generation cylindrical dendrimers in chloroform and dichloroacetic acid

Acrylic polymers containing side dendrons of the third generation based on L-aspartic acid have been studied via the methods of molecular hydrodynamics, dynamic and static light-scattering, optics, and electrooptics. There are marked differences in hydrodynamic and optical properties of the macromolecules under study and previously examined polymers with side dendrons of first and second generations. In the range of degrees of polymerization from 10 to 40, these macromolecules possess an extremely low shape asymmetry. Experiments demonstrate the predominant orientation of end side dendrons along the main molecular chain. In chloroform solutions, the orientation of macromolecules in hydrodynamic and electric fields occurs according to the large-scale mechanism. In dichloroacetic acid, the hydrodynamic dimensions of macromolecules decrease, an effect that is accompanied by an increase in the kinetic flexibility of polymer chains.     

Molecular properties of conjugates formed by synthetic hydrophilic polymers and sterically hindered phenols

Water-soluble conjugates are prepared via the chemical modification of poly(vinyl alcohol) and poly(ethylene glycol) by antioxidants taken from the family of sterically hindered phenols. The effects of the degree of substitution of conjugates on the dimensions of molecules and their aggregates are studied by viscometry and light scattering in dilute solutions. It is shown that an increase in the amount of antioxidant groups incorporated into the poly(vinyl alcohol) chain leads to a decrease in the dimensions of single conjugate molecules owing to attraction of hydrophobic groups. Poly(ethylene glycol) molecules carrying end groups of sterically hindered phenols form micellar aggregates that are absent in the solution of the initial polymer. The mean number of molecules involved in such an aggregate is 83. It is found that the presence of hydrophobic end groups in poly(ethylene glycol) molecules causes a sharp reduction in the lower critical solution temperature of a solution relative to that of the initial polymer.     

Nonregular phenomena in systems of quantum wells in the presence of tunneling processes

The effect of tunneling on inelastic processes in atomic collision physics has been studied using two examples: head-on collision between hydrogen atoms and protons and hydrogen-atom reflection from an impenetrable wall. These phenomena are analyzed using the numerical solution of the nonstationary Schr?dinger equation.