Codimension two Kähler submanifolds of space forms

In this article we study isometric immersions from Kähler manifolds whose (1, 1) part of the second fundamental form is parallel, theppmc isometric immersions. When the domain is a Riemann surface these immersions are precisely those with parallel mean curvature. P. J. Ryan has classified the Kähler manifolds that admit isometric immersions, as real hypersurfaces, in space forms. We classify the codimension twoppmc isometric immersions into space forms.     

A Travelling Salesman Model for the Sequencing of Duties in Bus Crew Rotas

The paper addresses one aspect of the rostering problem posed to the public transport company operating in Porto, Portugal. The specific problem dealt with in this paper is that of sequencing the duties within each rota (rotating schedule) so as to minimize the variance of the rest periods between successive duties while satisfying constraints on their minimum value. This problem is formulated as a travelling salesman problem. Solutions derived from two heuristics are compared with the optimal ones.     

Luminescence quantum yield determination for molecules adsorbed onto solid powdered particles.

A new methodology for the determination of the fluorescence quantum yield of dyes adsorbed onto microcrystalline cellulose is presented and applied to rhodamine 101, cresyl violet and auramine O. It is based on a previously reported method by Ruetten and Thomas (J. Phys. Chem., 1998, 102, 598-606), which is not applicable to the dyes used in the present study. It uses ground-state diffuse reflectance spectra obtained with and without filters, which prevents the luminescence of the dye from reaching the integrating sphere and the photodetector. New equations are presented here, correcting for the fluorescence emission of the dye, which depends on the detector sensitivity. Cut-on filters, which have a transmittance close to unity in the absorption region, and close to zero in the emission region, of the dye are used to obtain corrected reflectance spectra. The influence of the substrate was also taken into account. This methodology may be applied to other probes and surfaces or emissions of a different nature (i.e., phosphorescence or delayed fluorescence), and constitutes a very simple and general procedure to solve the important problem of luminescence quantum yield determination of probes adsorbed onto solid powdered surfaces.     

Tunable L-band erbium-doped fibre ring laser by means of induced cavity loss using a fibre taper

In this paper, we present a continuous-wave tunable fibre ring laser operating in the L-band. A bi-directional pumped L-band erbium-doped fibre amplifier provides gain to the loop. Tunability is achieved by bending a single-mode fibre taper using a micrometer drive, controlling in this way the spectral cavity losses. Laser emission is achieved between 1587 and 1606 nm, and low variation of the output laser power is observed over all the tuning range. PACS 42.55.Wd; 42.60.Da     

Static features in real-time recognition of isolated vowels at high pitch

This paper addresses the problem of automatic identification of vowels uttered in isolation by female and child speakers. In this case, the magnitude spectrum of voiced vowels is sparsely sampled since only frequencies at integer multiples of F0 are significant. This impacts negatively on the performance of vowel identification techniques that either ignore pitch or rely on global shape models. A new pitch-dependent approach to vowel identification is proposed that emerges from the concept of timbre and that defines perceptual spectral clusters (PSC) of harmonic partials. A representative set of static PSC-related features are estimated and their performance is evaluated in automatic classification tests using the Mahalanobis distance. Linear prediction features and Mel-frequency cepstral coefficients (MFCC) coefficients are used as a reference and a database of five (Portuguese) natural vowel sounds uttered by 44 speakers (including 27 child speakers) is used for training and testing the Gaussian models. Results indicate that perceptual spectral cluster (PSC) features perform better than plain linear prediction features, but perform slightly worse than MFCC features. However, PSC features have the potential to take full advantage of the pitch structure of voiced vowels, namely in the analysis of concurrent voices, or by using pitch as a normalization parameter.     

Spatial information transmission using axial temporal coherence coding

We present an approach that can be used for transmission of information through space-limited systems or for superresolution. The spatial information is coded with different axial temporal coherence by interfering every spatial region in the input with the same region, but with a certain known delay in the longitudinal axis. Every spatial region has different delay. After mixing all of the spatial information, it is transmitted through the space-limited system. At the detection the information is passed through a similar interference setup containing certain axial delay. By temporally scanning along the longitudinal axis, each time a different spatial region that was coded with the corresponding axial delay is reconstructed. To allow coding of different spatial regions with different and small axial delays, we use a thermal light source that has very short coherence length. We include experimental validation of the presented approach.     

Confidence intervals and ellipsoids for estimable functions and estimable vectors in models with orthogonal block structure

Sub-models of mixed linear models are considered. The independence of these sub-models leads to sufficient statistics for the parameters relevant for their densities. Using pivot variables, confidence regions are obtained as well hypothesis testing for variance components, estimable functions, and estimable vectors. In addition, to compare the estimators and the models, we present the histograms with the empirical joint densities for positive and negative parts of the estimators. The figures, for the two-dimensional charts, contain the corresponding UMVUE and are all unimodal with the UMVUE near the mode. The nearness of the estimators and the modes validates the presented methodology and allows the safe use of induced densities. A numerical example applied to real data is presented.     

Amperometric Folic Acid Quantification Using a Supramolecular Tetraruthenated Nickel Porphyrin µ‐Peroxo‐Bridged Matrix Modified Electrode Associated to Batch Injection Analysis

A supramolecular Nickel (II) porphyrin complex containing four pyridyl‐bis(2,2′‐bipyridyl)chloro ruthenium meso substituents was submitted to successive voltammetric cycles in high alkaline media to produce a supramolecular matrix with Nickel centers linked by µ‐peroxo bridges, producing a highly stable thin film able to act as redox mediator for electrocatalytic oxidation of folic acid. The characterization of electrode surface material was performed by Scanning Electron Microscopy and Electrochemical Impedance Spectroscopy. The modified electrode was inserted into a batch injection electrochemical cell used for the rapid and precise quantification of folic acid in pharmaceutical products. The favorable hydrodynamic conditions provided by amperometry‐BIA association allowed a very high throughput with good linear range (1 to 200 µmol L^?1) and low detection limit (7.37×10^?7 mol L^?1). The electrochemical method was applied to the quantification of folic acid in different tablet samples. The results were comparable with values indicated by the manufacturer and those found using high HPLC according to the Brazilian Pharmacopoeia; commercial samples were submitted to a procedure in order to remove lactose of tablets, since carbohydrates act as interfering species. This procedure together with the electrochemical method showed to be simple, rapid, efficient and an appropriate alternative for quantifying this compound in real samples.