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931.
J. P. Cosas Fernandes V. H. Mareau 《International Journal of Polymer Analysis and Characterization》2018,23(2):113-119
The optimization of manufacturing processes and the investigation of polymer materials during their life cycle imply an extended knowledge of the physical and chemical properties of the material. To obtain colocalized chemical, morphological, and thermomechanical information on the same sample area, we have developed an innovative colocalized atomic force microscopy (AFM)-Raman setup and a sample preparation strategy using cryoultramicrotomy. The developed technique allows perfect cross-sectioning of thin membranes (10–300?µm) without embedding avoiding chemical contamination. The opened surface is characteristic of the material’s bulk properties and allows spectroscopic and near-field measurements without sample artifacts. Additionally, thin sections can be collected for complementary transmission electron microscopy. 相似文献
932.
Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R Harral B Harris FA 《Physical review letters》1989,63(26):2780-2783
933.
Marcelo R. L. Oliveira Vito M. De Bellis Nelson G. Fernandes 《Structural chemistry》1997,8(3):205-209
The reaction of potassiumN-(methanesulfonyl)-dithiocarbimate, K2[S2C=NSO2CH3], with nickel(II) chloride hexahydrate, NiCl2·6H2O, formed the complex anion bis(N-(methanesulfonyl)-dithiocarbimate)nickelate(II), [Ni(S2C=NSO2CH3)2]2}-, which was isolated as its tetra-n-butylammonium salt. The UV-Vis data obtained were consistent with the formation of a nickelsulfur diamagnetic planar complex. The1H NMR and the13C NMR spectra showed the expected signals for then-Bu4N+ cation and the dithiocarbimate moiety. The single-crystal structure analysis showed that tetra-n-butylammonium bis(N-(methanesulfonyl)-dithiocarbimate)nickelate(II), (Bu4N)2[Ni(S2C=NSO2CH3)2], crystallizes in the monoclinic space groupP2l/c witha=9.3197(5),b=15.0795(8),c=17.5286(9) å,=91.262(3),V=2462.8(3) å3, andZ=2. The nickel atom is coordinated to four sulfur atoms. 相似文献
934.
A. M.?Ramalho M. M.?Conceio V. J.?Fernandes Jr. J. C.?Machado L. E. B.?Soledade A. G.?Souza 《Journal of Thermal Analysis and Calorimetry》2005,79(2):319-322
Summary Solid-state M-4-MeO-Bz compounds, where M stands for bivalent Mn, Co, Ni, Cu and Zn and 4-MeO-Bz is 4-methoxybenzoate, have been synthesized. Simultaneous thermogravimetry-differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC), X-ray powder diffractometry, infrared spectroscopy, elemental analysis and complexometry were used to characterize and to study the thermal behaviour of these compounds. The results led to have information about the composition, dehydration, thermal stability and thermal decomposition of the isolated compounds. 相似文献
935.
Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R Harral B Harris FA 《Physical review letters》1990,64(12):1334-1337
936.
937.
M. A. Bacchi E. A. N. Fernandes 《Journal of Radioanalytical and Nuclear Chemistry》2003,257(3):577-582
This work shortly describes the main steps involved in the design and development of the software package Quantu, created to conduct k
0-standardized NAA. The package comprises a database as well as two individual programs. Quantu-MCA is dedicated to (g-ray spectrum analysis and Quantu-INAA is the interface for the database administration, also dealing with k
0-method calculations. 相似文献
938.
939.
Januário AH Lourenço MV Domézio LA Pietro RC Castilho MS Tomazela DM da Silva MF Vieira PC Fernandes JB França Sde C 《Chemical & pharmaceutical bulletin》2005,53(7):740-742
Crude extracts of callus and roots of Dipteryx odorata were analyzed by HPLC to detect and quantify isoflavone contents. Based on spectroscopic and X-ray crystallography data the structures of two isoflavones were elucidated as 7-hydroxy-4',6-dimethoxyisoflavone and 3',7-dihydroxy-4',6-dimethoxyisoflavone. The production of dry biomass of 7-hydroxy-4',6-dimethoxyisoflavone in cultured callus was 4.12 mg/g, approximately eleven fold higher than the amount accumulated in roots of D. odorata wild-growing plants. The 7-hydroxy-4',6-dimethoxyisoflavone was effective against glyceraldehyde-3-phosphate dehydrogenase from Trypanosoma cruzi. This is the first report on those bioactive isoflavones accumulated in callus of D. odorata. 相似文献
940.
V. V. Kuznetsov A. R. Pal'ma M. Fernandes A. É. Aliev V. K. Shevtsov A. V. Varlamov N. S. Prostakov 《Chemistry of Heterocyclic Compounds》1991,27(10):1080-1083
The bromination of 1,2,3,4-tetrahydro-4-methylspiro[quinoline-2-cyclohexane] has been carried out under various conditions. Dibromo and monobromo derivatives have been obtained; the monobromo derivatives were synthesized by cyclization of 1-allyl-1-bromophenylaminocyclohexanes.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1350–1353, October, 1991. 相似文献