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排序方式: 共有275条查询结果,搜索用时 15 毫秒
61.
Zhang Y Aslan K Previte MJ Malyn SN Geddes CD 《The journal of physical chemistry. B》2006,110(49):25108-25114
We report our detailed metal-enhanced phosphorescence (MEP) findings using Rose Bengal at low temperature. Silver Island Films (SiFs) in close proximity to Rose Bengal significantly enhance the phosphorescence emission intensity. In this regard, a 5-fold brighter phosphorescence intensity of Rose Bengal was observed from SiFs as compared to a glass control sample at 77 K. In addition, several factors affecting MEP, such as distance dependence and silver film morphology, were also investigated. Our findings suggest that both singlet and triplet states can couple to surface plasmons and enhance both fluorescence and phosphorescence yields. This finding suggests that MEP can be used to promote triplet-based assays, such as those used in photodynamic therapy. 相似文献
62.
?smail Aslan 《Applied mathematics and computation》2010,217(2):937-4217
We report an observation on two recent analytic methods; the (G′/G)-expansion method and the simplest equation method. 相似文献
63.
In this paper, we study the approximation properties of nonlinear integral operators of convolution-type by using summability process. In the approximation, we investigate the convergence with respect to both the variation semi-norm and the classical supremum norm. We also compute the rate of approximation on some appropriate function classes. At the end of the paper, we construct a specific sequence of nonlinear operators, which verifies the summability process. Some graphical illustrations and numerical computations are also provided. 相似文献
64.
The thermal behaviour of copolymers of thiophene with decanedioic acid bis-(2-thiophen-3-yl-ethyl)ester (DATE) and terephthalic acid bis-(2-thiophen-3-yl-ethyl)ester (TATE) prepared by potentiostatic polymerization was studied via pyrolysis mass spectrometry. It was determined that the electrolytic films correspond to the related homopolymers. The increase in thermal stability of ester linkages, and evolution of characteristic degradation products of TATE and DATE together with thiophene based products above 400 °C confirmed copolymer formation. 相似文献
65.
Omer Sahin Fevzi Aslan Mustafa Ozdemir Mustafa Durgun 《Journal of Crystal Growth》2004,270(3-4):604-614
Growth rate of polycrystalline disc of borax compressed at different pressure and rotated at various speed has been measured in a rotating disc crystallizer under well-defined conditions of supersaturation. It was found that the mass transfer coefficient, K, increased while overall growth rate constant, Kg, and surface reaction constant, kr, decreased with increasing smoothness of the disc. It was also determined that kinetic parameters (kr,r,K,g) of crystal growth rate of borax decreased with increasing rotating speed of the polycrystalline disc. The effectiveness factor was calculated from the growth rate data to evaluate the relative magnitude of the steps in series bulk diffusion through the mass transfer boundary layer and the surface integration. At low rotating speed of disc, the crystal growth rate of borax is mainly controlled by integration. However, both diffusion and integration steps affect the growth rate of borax at higher rotating speed of polycrystalline disc. 相似文献
66.
A second-order-accurate (in both time and space) formulation is developed and implemented for solution of the three-dimensional incompressible Navier–Stokes equations involving high-Reynolds-number flows past complex configurations. For stabilization, only a fourth-order-accurate artificial dissipation term in the momentum equations is used. The finite element method (FEM) with an explicit time-marching scheme based on two-fractional-step integration is used for solution of the momentum equations. The element-by-element (EBE) technique is employed for solution of the auxiliary potential function equation in order to ease the memory requirements for matrix. The cubic cavity problem, the laminar flow past a sphere at various Reynolds numbers and the flow around the fuselage of a helicopter are successfully solved. Comparison of the results with the low-order solutions indicates that the flow details are depicted clearly even with coarse grids. © 1997 John Wiley & Sons, Ltd. 相似文献
67.
An improved microwave Clevenger apparatus for distillation of essential oils from orange peel 总被引:5,自引:0,他引:5
Microwave Clevenger or microwave accelerated distillation (MAD) is a combination of microwave heating and distillation, performed at atmospheric pressure without added any solvent or water. Isolation and concentration of volatile compounds are performed by a single stage. MAD extraction of orange essential oil was studied using fresh orange peel from Valencia late cultivar oranges as the raw material. MAD has been compared with a conventional technique, which used a Clevenger apparatus with hydro-distillation (HD). MAD and HD were compared in term of extraction time, yields, chemical composition and quality of the essential oil, efficiency and costs of the process. Extraction of essential oils from orange peels with MAD was better in terms of energy saving, extraction time (30 min versus 3 h), oxygenated fraction (11.7% versus 7.9%), product yield (0.42% versus 0.39%) and product quality. Orange peels treated by MAD and HD were observed by scanning electronic microscopy (SEM). Micrographs provide evidence of more rapid opening of essential oil glands treated by MAD, in contrast to conventional hydro-distillation. 相似文献
68.
69.
We review new methodologies for glucose sensing from our laboratories based on the specific biological interactions between Con A, dextran-coated gold nanoparticles and glucose, and the interactions between dextran, glucose, and boronic-acid capped silver nanoparticles in solution. Our new approaches promise new tunable glucose sensing platforms. Dextran-coated gold nanoparticles were aggregated with the addition of Con A resulting in increase an in absorbance of nanoparticles at 650 nm, where the post-addition of glucose caused the dissociation of the aggregates and thus a decrease in the absorbance at 650 nm. The interaction of glucose and dextran with boronic acid-capped silver nanoparticles in solution resulted in enhanced luminescence intensity cumulatively due to surface-enhanced fluorescence and the decrease in absorbance at 400 nm, with an increase in absorbance at 640 nm. Lifetime measurements were used to distinguish the contribution from the surface-enhanced fluorescence. TEM was employed to assess the aggregation of nanoparticles. 相似文献
70.