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91.
M.T. Sandor X.K. XiJ.Q. Wang H.Y. BaiW.H. Wang Y. Wu 《Journal of magnetism and magnetic materials》2012,324(2):173-177
We report magnetization properties of (CuZr)93−xAl7Gdx bulk metallic glasses from temperature dependent 27Al nuclear magnetic resonance spectroscopy and magnetic susceptibility measurements. Significant non-linear line broadening of 27Al spectra commencing at high temperatures is attributed to the development of a local magnetic susceptibility distribution that prevails over a finite temperature range. Magnetization measurements confirm the linewidth enhancement due to strong frustrated magnetic short-range order. This study provides insight into the nature of magnetic development and frustration in paramagnetic systems. 相似文献
92.
Gerbig S Golf O Balog J Denes J Baranyai Z Zarand A Raso E Timar J Takats Z 《Analytical and bioanalytical chemistry》2012,403(8):2315-2325
Negative ion desorption electrospray ionization (DESI) was used for the analysis of an ex vivo tissue sample set comprising primary colorectal adenocarcinoma samples and colorectal adenocarcinoma liver metastasis samples. Frozen sections (12 μm thick) were analyzed by means of DESI imaging mass spectrometry (IMS) with spatial resolution of 100 μm using a computer-controlled DESI imaging stage mounted on a high resolution Orbitrap mass spectrometer. DESI-IMS data were found to predominantly feature complex lipids, including phosphatidyl-inositols, phophatidyl-ethanolamines, phosphatidyl-serines, phosphatidyl-ethanolamine plasmalogens, phosphatidic acids, phosphatidyl-glycerols, ceramides, sphingolipids, and sulfatides among others. Molecular constituents were identified based on their exact mass and MS/MS fragmentation spectra. An identified set of molecules was found to be in good agreement with previously reported DESI imaging data. Different histological tissue types were found to yield characteristic mass spectrometric data in each individual section. Histological features were identified by comparison to hematoxylin-eosin stained neighboring sections. Ions specific to certain histological tissue types (connective tissue, smooth muscle, healthy mucosa, healthy liver parenchyma, and adenocarcinoma) were identified by semi-automated screening of data. While each section featured a number of tissue-specific species, no potential global biomarker was found in the full sample set for any of the tissue types. As an alternative approach, data were analyzed by principal component analysis (PCA) and linear discriminant analysis (LDA) which resulted in efficient separation of data points based on their histological types. A pixel-by-pixel tissue identification method was developed, featuring the PCA/LDA analysis of authentic data set, and localization of unknowns in the resulting 60D, histologically assigned LDA space. Novel approach was found to yield results which are in 95% agreement with the results of classical histology. KRAS mutation status was determined for each sample by standard molecular biology methods and a similar PCA/LDA approach was developed to assess the feasibility of the determination of this important parameter using solely DESI imaging data. Results showed that the mutant and wild-type samples fully separated. DESI-MS and molecular biology results were in agreement in 90% of the cases. 相似文献
93.
Johnson SL de Souza RA Staub U Beaud P Möhr-Vorobeva E Ingold G Caviezel A Scagnoli V Schlotter WF Turner JJ Krupin O Lee WS Chuang YD Patthey L Moore RG Lu D Yi M Kirchmann PS Trigo M Denes P Doering D Hussain Z Shen ZX Prabhakaran D Boothroyd AT 《Physical review letters》2012,108(3):037203
We report on the ultrafast dynamics of magnetic order in a single crystal of CuO at a temperature of 207 K in response to strong optical excitation using femtosecond resonant x-ray diffraction. In the experiment, a femtosecond laser pulse induces a sudden, nonequilibrium increase in magnetic disorder. After a short delay ranging from 400 fs to 2 ps, we observe changes in the relative intensity of the magnetic ordering diffraction peaks that indicate a shift from a collinear commensurate phase to a spiral incommensurate phase. These results indicate that the ultimate speed for this antiferromagnetic reorientation transition in CuO is limited by the long-wavelength magnetic excitation connecting the two phases. 相似文献
94.
95.
Peter Kozma Andras Hamori Kaspar Cottier Sandor Kurunczi Robert Horvath 《Applied physics. B, Lasers and optics》2009,97(1):5-8
An interferometric sensor based on gratings on a planar waveguide is introduced. The device combines the advantages of known
interference-based waveguide sensors with the simplicity of grating couplers. In the presented configuration, two parallel
and coherent light beams, laterally separated in the direction of mode propagation, are coupled into a planar waveguide through
a grating. One of the coupled beams is phase modulated using a periodically relaxing liquid crystal modulator, resulting in
a time varying intensity signal at the end face of the waveguide. Refractive index changes within the waveguide section between
the two coupling regions are monitored by observing characteristic changes in the intensity signal. 相似文献
96.
Sebastian Burck Dietrich Gudat Prof. Dr. Martin Nieger Zoltan Benkö Lászlo Nyulászi Denes Szieberth 《无机化学与普通化学杂志》2009,635(2):245-252
P‐bromo‐ and P‐Iodo‐substituted N‐heterocyclic phosphanes (NHP) were synthesized by halogen exchange starting from the P‐chloro compound and characterized by spectroscopic data and X‐ray diffraction studies. Whereas the Br‐NHP still forms a molecular crystal, the solid‐state structure of the I‐derivative consists of ion‐pairs which assemble via secondary P···I interactions to form one‐dimensional coordination polymers. Computational studies indicate that the bond dissociation is due to a combination of intramolecular stabilisation (aromatisation of the phosphenium cation formed) and intermolecular Lewis‐acid/base interactions. Reaction of the I‐NHP with I2 proceeded under complete P–I bond cleavage to give an ionic phosphenium triiodide whose single‐crystal X‐ray diffraction study revealed a unique supramolecular structure. 相似文献
97.
Sandor Balog Dominic A. Urban Ana M. Milosevic Federica Crippa Barbara Rothen-Rutishauser Alke Petri-Fink 《Journal of nanoparticle research》2017,19(8):287
The ability to detect and accurately characterize particles is required by many fields of nanotechnology, including materials science, nanotoxicology, and nanomedicine. Among the most relevant physicochemical properties of nanoparticles, size and the related surface-to-volume ratio are fundamental ones. Taylor dispersion combines three independent phenomena to determine particle size: optical extinction, translational diffusion, and sheer-enhanced dispersion of nanoparticles subjected to a steady laminar flow. The interplay of these defines the apparent size. Considering that particles in fact are never truly uniform nor monodisperse, we rigorously address particle polydispersity and calculate the apparent particle size measured by Taylor dispersion analysis. We conducted case studies addressing aqueous suspensions of model particles and large-scale-produced “industrial” particles of both academic and commercial interest of various core materials and sizes, ranging from 15 to 100 nm. A comparison with particle sizes determined by transmission electron microscopy confirms that our approach is model-independent, non-parametric, and of general validity that provides an accurate account of size polydispersity—independently on the shape of the size distribution and without any assumption required a priori. 相似文献
98.
Goga NO Demco DE Kolz J Ferencz R Haber A Casanova F Blümich B 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2008,192(1):1-7
Depth profiles taken from the surface of UV irradiated natural rubber sheets have been measured with microscopic resolution using a Profile NMR-MOUSE. An NMR observable related to the sum of the spin echoes in the Carr-Purcell-Meiboom-Gill pulse sequence was used to characterize the cross-link density changes produced by the action of UV radiation in each sheet. The aging process was investigated as function of irradiation time and penetration depth. An exponential attenuation law with a space dependent absorption coefficient describes the change in the NMR observable with penetration depth. An Avrami model is used to describe the dependence of the absorption coefficient on the aging time. The method can be applied to investigate the effect of various aging agents on the surfaces of elastomers. 相似文献
99.
100.
Abstract Photorepair of UV-B lesions occurred in embryonic northern anchovy larvae. The photoreactive fluence rate required to fully activate photorepair mechanisms was less than 10% of that available from the sun on a clear day in March (33N). Even with UV–B enhancement from ozone depletion, sufficient photoreactive fluence exists in the sea to ensure maximal photorepair of UV damage in anchovy larvae. 相似文献