全文获取类型
收费全文 | 48082篇 |
免费 | 8316篇 |
国内免费 | 5933篇 |
专业分类
化学 | 33011篇 |
晶体学 | 547篇 |
力学 | 3203篇 |
综合类 | 517篇 |
数学 | 5928篇 |
物理学 | 19125篇 |
出版年
2024年 | 158篇 |
2023年 | 943篇 |
2022年 | 1748篇 |
2021年 | 1785篇 |
2020年 | 1951篇 |
2019年 | 1874篇 |
2018年 | 1675篇 |
2017年 | 1620篇 |
2016年 | 2285篇 |
2015年 | 2313篇 |
2014年 | 2760篇 |
2013年 | 3568篇 |
2012年 | 4229篇 |
2011年 | 4380篇 |
2010年 | 3033篇 |
2009年 | 3007篇 |
2008年 | 3266篇 |
2007年 | 2824篇 |
2006年 | 2624篇 |
2005年 | 2202篇 |
2004年 | 1728篇 |
2003年 | 1350篇 |
2002年 | 1289篇 |
2001年 | 1104篇 |
2000年 | 974篇 |
1999年 | 1018篇 |
1998年 | 842篇 |
1997年 | 837篇 |
1996年 | 758篇 |
1995年 | 689篇 |
1994年 | 599篇 |
1993年 | 499篇 |
1992年 | 393篇 |
1991年 | 378篇 |
1990年 | 341篇 |
1989年 | 254篇 |
1988年 | 217篇 |
1987年 | 186篇 |
1986年 | 138篇 |
1985年 | 127篇 |
1984年 | 90篇 |
1983年 | 77篇 |
1982年 | 76篇 |
1981年 | 39篇 |
1980年 | 28篇 |
1979年 | 9篇 |
1976年 | 7篇 |
1975年 | 8篇 |
1959年 | 6篇 |
1957年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Based on the complexation between proteins and Cu(II) coupled with the time-resolved chemiluminescence (CL) technique, a highly sensitive and quantitative assay for measuring proteins in solution is described. The complexes of proteins with Cu(II) have a strongly catalytic effect on the luminol-H2O2 CL reaction. Because the CL emission produced by the complexes is much more long-lived than that by Cu(II), the CL signals originating from proteins can be easily identified and measured with a time-resolved technique. On this basis, bovine albumin fraction V (BAF V) can be quantitatively determined in the range of 0.01 - 5.0 microg/ml with a detection limit of 5.8 ng/ml. The results show that the proposed assay exhibits a small variation in the response values for the same amount of different proteins, as compared to the Lowry as well as Bradford assays. The CL assay has also been studied for the detection of immobilized proteins. 相似文献
22.
Behavior of cellulose in NaOH/Urea aqueous solution characterized by light scattering and viscometry
Cellulose was dissolved in 6 wt % NaOH/4 wt % urea aqueous solution, which was proven by a 13C NMR spectrum to be a direct solvent of cellulose rather than a derivative aqueous solution system. Dilute solution behavior of cellulose in a NaOH/urea aqueous solution system was examined by laser light scattering and viscometry. The Mark–Houwink equation for cellulose in 6 wt % NaOH/4 wt % urea aqueous solution at 25 °C was [η] = 2.45 × 10?2 weight‐average molecular weight (Mw)0.815 (mL g?1) in the Mw region from 3.2 × 104 to 12.9 × 104. The persistence length (q), molar mass per unit contour length (ML), and characteristic ratio (C∞) of cellulose in the dilute solution were 6.0 nm, 350 nm?1, and 20.9, respectively, which agreed with the Yamakawa–Fujii theory of the wormlike chain. The results indicated that the cellulose molecules exist as semiflexible chains in the aqueous solution and were more extended than in cadoxen. This work provided a novel, simple, and nonpollution solvent system that can be used to investigate the dilute solution properties and molecular weight of cellulose. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 347–353, 2004 相似文献
23.
24.
XiangGuoSHI DaFangZHONG YuMingSUN YuFengZHANG 《中国化学快报》2004,15(4):431-434
A sensitive analytical method to identify active metabolites of bitespiramycin in rat urine and bile was developed by liquid chromatography-electrospray ionization tandem mass spectrometry(LC/ESI-MS^n).Bitespiramycin and its major active metabolites in rat urine and bile were isolated and identified as M1 serial(spiramycin Ⅰ,Ⅱ,Ⅲ),M2 serial(platenomycin A1,josamycin and leucomycin A1) and M3 serial(deisovalerylplatenomycin A1,deisovaleryljosamycin,deisovalerylleucomycin A1). 相似文献
25.
LiAlO2 single crvstals doped with Ti at concentration 0.2at.% are grown by the Czochralskl technique with dimensions φ42×55mm. Ti ions in the crystal are quadrivalence proven by comparing the absorption and fluorescence spectra of pure LiAlO2 and Ti: LiAlO2. After air and Li-rich atmosphere annealing, the absorption peaks in the range of 600-800nm disappear. We conclude that 682 and 756nm absorption peaks are attributed to the VLi and Vo absorptions, respectively: The peaks at 716nm and 798nm may stem from the VLi^+ and absorptions. The colour-centre model can be applied to explain the experimental phenomena. Ti^4+-doping produces more lithium vacancies in the LiAlO2 crystal. The intensities of [LiO4] and the associated bonds remain unchanged, which improves the anti-hydrolyzation and thermal stability of LiAlO2 crystals. 相似文献
26.
本文首先提出逆(反)对策这一新问题,给出了数学模型;探讨了“奇门遁甲”预测理论(术)中的数学问题;通过系统分析“专门遁甲”预测过程,可知它的预测过程隐含着一个特殊的逆(反)对策问题;最后指出逆(反)对策问题的广泛存在并给出案例分析. 相似文献
27.
周焕松 《数学物理学报(B辑英文版)》1998,(2)
1IntroductionIntillspaper,weare(follccrlledwitlltileexistellccofPositly(tsollltiollsoftilefollowillgnonhonlogelleousellipticProblclll:whereg(x)EL'(R'),g(:v)Z0alldg(x)t0,f(x,t)=h(x,t).hi=withb>0,h(x,t)EC(R=xR,R)alldtilefollowing(CI)-(C3)11old:(CI)sliphillM0.linljfl- x,h(T,t)(t--if-=011llif'orllllyforxeR2.hill}t:l-:,t)(axle(~ltJ')= lx,11lliforllllyl'Ora:6RZ.ltl~la(C3)ThereexistM>0,aE(0,1]sucllthatFOllowing[1,5],wesaythatf(x,t)=h(x,f… 相似文献
28.
29.
L.-Q. Han S.-Y. Zhao Y.-D. Zhou P.-L. Zhang 《Applied physics. B, Lasers and optics》1997,65(3):399-402
Received: 18 June 1996/Revised version: 3 January 1997 相似文献
30.
We study a generalization of the notion of the chromatic number of a graph in which the colors assigned to adjacent vertices are required to be, in a certain sense, far apart. © 1993 John Wiley & Sons, Inc. 相似文献