褶合光谱法考察羟自由基清除剂对紫外照射致DNA变异的作用

采用褶合光谱法考察了紫外线UV A ,UV B ,UV C导致的DNA变异 ,并以褶合光谱差谱值的形式量化表达DNA细微突变的程度。DNA受UV A ,UV B ,UV C作用后 ,差谱值依次增大 ,表明变异程度增大 ;添加二甲亚砜、甘露醇等羟自由基清除剂以后 ,在UV A ,UV B ,UV C作用下 ,差谱值有不同程度的降低 ,呈现一定的抑制变异作用。尽管DNA的变异程度有所区别 ,但它们的差谱点分布区域相似 ,提示UV A ,UV B ,UV C导致的DNA变异类型可能相似 ,两种羟自由基清除剂抑制DNA变异的作用机制也可能相似     

五种氨基酸钆络合物的ESR波谱

迄今未见任何稀土氨基酸络合物的ESR波谱报道,本文在合成Gd³⁺分别与甘氨酸、β-丙氨酸、谷氨酸、天冬氨酸和天冬酰胺五种氨基酸络合物的基础上,测定了不同温度下,水溶液、粉末及分子筛吸附样品的ESR谱,讨论了络合物中晶体场强,对称性及成键特性。     

NIR光谱的LLE-PLS非线性建模方法及应用

传统的偏最小二乘(PLS)建模方法不能有效反映近红外(NIR)光谱与分析样本的物理化学性质之间存在的非线性关系。局部线性嵌入(LLE)是一种新的非线性降维方法,属于流形学习方法,它能有效地发现高维数据中的本真低维结构。结合LLE和PLS,提出一种近红外光谱非线性建模的新方法,并用于建立丹参多酚酸盐柱层析过程中丹酚酸B含量的回归校正模型。该方法首先用LLE对NIR光谱数据降维,再用PLS建立校正模型。结果表明,与多元散射校正、一阶导等预处理方法结合PLS建模比较,参数优化后的LLE-PLS方法能更准确地预测丹酚酸B的含量,其交叉验证均方根误差为0.128 mg·mL-1、决定系数为0.998 8。基于NIR光谱及LLE-PLS建模,可实现丹参多酚酸盐柱层析过程的在线检测。     

单偏振控制器环形腔光纤激光器实验研究

理论分析了非线性偏振旋转环形腔作为类饱和可吸收体获得脉冲的物理机理。在光纤环形腔结构中,采用单个偏振控制器实现了非线性偏振旋转锁模,直接获得了脉冲宽度为131 fs的超短脉冲输出。实验中,采用性能稳定的976 nm半导体二极管激光器作为抽运源,使用高掺杂浓度的Er3 光纤为增益介质,通过调节偏振控制器,获得了光谱谱宽(3 dB带宽处)为23.5 nm的稳定锁模脉冲输出。脉冲中心波长为1535.9 nm,平均功率为5.91 mW,脉冲重复率为11.20 MHz。     

Boundary reflection from curved liquid surfaces and its application

A boundary light reflection from curved liquid surfaces was discovered. Due to the wetting effect, the liquid surface near the plate which was inserted into the liquid was deformed. When a collimated light beam vertically illumined the curved liquid surface, special reflective patterns of a strip-shape dark region in the center and the visibility interference fringes on both sides was observed for the up-curved liquid surface. The width of the dark region increases with the decreasing width of the incident beam. The relation of the dark region width and the incident beam width was derived theoretically. The slope and the height of curved liquid surface were obtained directly from measuring the dark central region width of the reflection pattern and the incident beam width. Furthermore, the analytic expression of the profile of the curved liquid surface was derived. As a result, it shows that an effective and practical technique for measuring the characterization of curved liquid surface was found.     

Design of Enhanced Catalysts by Coupling of Noble Metals (Au,Ag) with Semiconductor SnO2 for Catalytic Reduction of 4‐Nitrophenol

The reduction of 4‐nitrophenol (Nip) into 4‐aminophenol (Amp) by NaBH₄, which is catalyzed by both binary and ternary yolk–shell noble‐metal/SnO₂ heterostructures, is reported. The binary heterostructures contain individual Au or Ag nanoparticles (NPs) and the ternary heterostructures contain both Au and Ag NPs. The Au@SnO₂ yolk–shell NPs are synthesized via a silica seeds‐mediated hydrothermal method. Subsequently, the Au@SnO₂@Ag and Au@SnO₂@Au yolk–shell–shell (YSS) NPs are synthesized, whereby SnO₂ is located between the Au and Ag NPs. The morphology, composition, and optical properties of the as‐prepared samples are analyzed. For the binary heterostructures, the rate of the reduction reaction increases with decreasing particle size. The catalytic results demonstrate the synergistic effect of Au and Ag in the ternary metal–semiconductor heterostructures, which is beneficial to the catalytic reduction of Nip into Amp. Both the binary and ternary heterostructures exhibit significantly better catalytic performances than the corresponding bare Au and Ag NPs. It is envisaged that the current synthesized strategy will promote further interest in the field of bimetal NP‐based catalysis.     

“现代谱分析图形软件系统”的一些应用

“现代谱分析图形软件系统”是一个以谱分析为主体的大型软件，它包括了３２种当前典型的现代谱分析方法、经典谱分析方法和其它常用信号分析方法，并具有丰富的图形处理功能。本文介绍了该软件系统的基本功能和主要特点，研究了它在现代谱分析、水声、医疗、语音分析等领域的应用，并分析了有关结果。     

Spin-polarized current through a lateral double quantum dot with spin–orbit interaction

We study the spin-polarized current through a vertical double quantum dot scheme. Both the Rashba spin–orbit (RSO) interaction inside one of the quantum dots and the strong intradot Coulomb interactions on the two dots are taken into account by using the second-quantized form of the Hamiltonian. Due to the existence of the RSO interaction, spin-up and spin-down electrons couple to the external leads with different strengths, and then a spin polarized current can be driven out of the middle lead by controlling a set of structure parameters and the external bias voltage. Moreover, by properly adjusting the dot levels and the external bias voltages, a pure spin current with no accompanying charge current can be generated in the weak coupling regime. We show that the difference between the intradot Coulomb interactions strongly influences the spin-polarized currents flowing through the middle lead and is undesirable in the generation of the net spin current. Based on the RSO interaction, the structure we propose can efficiently polarize the electron spin without the usage of any magnetic field or ferromagnetic material. This device can be used as a spin-battery and is realizable using the present available technologies.     

Study on improving output capability of high-power lasers providing short pulses by using different laser glasses together in the amplifier chain

We have discussed the optical and laser properties of different laser glass types. According to the properties of the gain and the B integral in the high-power laser amplifier chain, an optimal configuration is pointed out to improve the output capability at short pulses based on reducing nonlinear refractive index n₂. In this way, high gain glasses and low n₂ glasses are used in different amplifier stages simultaneously. The simulated results show that on the condition that the maximal output energies of both the configurations are same at 3 and 5 ns, the maximal output capability growth ratio of 30.48% () and 42.24% () for the optimal configuration can be obtained at 1 ns, respectively.