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61.
Lukas M. Müller-Wirtz Daniel Kiefer Joschua Knauf Maximilian A. Floss Jonas Doneit Beate Wolf Felix Maurer Daniel I. Sessler Thomas Volk Sascha Kreuer Tobias Fink 《Molecules (Basel, Switzerland)》2021,26(9)
High inspired oxygen during mechanical ventilation may influence the exhalation of the previously proposed breath biomarkers pentanal and hexanal, and additionally induce systemic inflammation. We therefore investigated the effect of various concentrations of inspired oxygen on pentanal and hexanal exhalation and serum interleukin concentrations in 30 Sprague Dawley rats mechanically ventilated with 30, 60, or 93% inspired oxygen for 12 h. Pentanal exhalation did not differ as a function of inspired oxygen but increased by an average of 0.4 (95%CI: 0.3; 0.5) ppb per hour, with concentrations doubling from 3.8 (IQR: 2.8; 5.1) ppb at baseline to 7.3 (IQR: 5.0; 10.8) ppb after 12 h. Hexanal exhalation was slightly higher at 93% of inspired oxygen with an average difference of 0.09 (95%CI: 0.002; 0.172) ppb compared to 30%. Serum IL-6 did not differ by inspired oxygen, whereas IL-10 at 60% and 93% of inspired oxygen was greater than with 30%. Both interleukins increased over 12 h of mechanical ventilation at all oxygen concentrations. Mechanical ventilation at high inspired oxygen promotes pulmonary lipid peroxidation and systemic inflammation. However, the response of pentanal and hexanal exhalation varies, with pentanal increasing by mechanical ventilation, whereas hexanal increases by high inspired oxygen concentrations. 相似文献
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The cycloalkanones (1a-lf) have been converted into their corresponding cycloalkane carboxylates (2a-2f) by a lead (IV) acetate promoted rearrangement in presence of perchloric acid in triethyl orthoformate. 相似文献
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Felix Katzsch Tobias Gruber Edwin Weber 《Acta Crystallographica. Section C, Structural Chemistry》2016,72(9):679-684
The syntheses of three bis(benzo[b]thiophen‐2‐yl)methane derivatives, namely bis(benzo[b]thiophen‐2‐yl)methanone, C17H10OS2, (I), 1,1‐bis(benzo[b]thiophen‐2‐yl)‐3‐(trimethylsilyl)prop‐2‐yn‐1‐ol, C22H20OS2Si, (II), and 1,1‐bis(benzo[b]thiophen‐2‐yl)prop‐2‐yn‐1‐ol, C19H12OS2, (III), are described and their crystal structures discussed comparatively. The conformation of ketone (I) and the respective analogues are rather similar for most of the compounds compared. This is true for the interplanar angles, the Caryl—Cbridge—Caryl angles and the dihedral angles. The best resemblance is found for a bioisotere of (I), viz. 2,2′‐dinaphthyl ketone, (VII). By way of interest, the crystal packings also reveal similarities between (I) and (VII). In (I), the edge‐to‐face interactions seen between two napthyl residues in (VII) are substituted by S…π contacts between the benzo[b]thiophen‐2‐yl units in (I). In the structures of the bis(benzo[b]thiophen‐2‐yl)methanols, i.e. (II) and (III), the interplanar angles are also quite similar compared with analogues and related active pharmaceutical ingredients (APIs) containing the dithiophen‐2‐ylmethane scaffold, though the dihedral angles show a larger variability and produce unsymmetrical molecules. 相似文献
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This paper discusses stationary rotordynamics of synchronous electric machinery, considering different load cases. The model comprises the electrical operation in a rigid network and in an isolated condition. The mechanical part is modelled as a Laval Rotor (Jeffcott Rotor) with a noncircular shaft, accounting for both static- and dynamic rotor eccentricities. The results show, that the machine's electrical operation may influence the occurence of mechanical vibrations significantly and therefore demonstrate the importance of analysing the electromechanical interaction. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献