全文获取类型
收费全文 | 2732篇 |
免费 | 116篇 |
国内免费 | 7篇 |
专业分类
化学 | 1961篇 |
晶体学 | 5篇 |
力学 | 56篇 |
数学 | 428篇 |
物理学 | 405篇 |
出版年
2023年 | 54篇 |
2022年 | 42篇 |
2021年 | 67篇 |
2020年 | 111篇 |
2019年 | 86篇 |
2018年 | 28篇 |
2017年 | 55篇 |
2016年 | 106篇 |
2015年 | 85篇 |
2014年 | 86篇 |
2013年 | 98篇 |
2012年 | 135篇 |
2011年 | 153篇 |
2010年 | 78篇 |
2009年 | 58篇 |
2008年 | 127篇 |
2007年 | 97篇 |
2006年 | 97篇 |
2005年 | 79篇 |
2004年 | 62篇 |
2003年 | 53篇 |
2002年 | 55篇 |
2001年 | 28篇 |
2000年 | 35篇 |
1999年 | 31篇 |
1998年 | 23篇 |
1997年 | 15篇 |
1996年 | 16篇 |
1995年 | 19篇 |
1994年 | 27篇 |
1993年 | 25篇 |
1992年 | 20篇 |
1991年 | 13篇 |
1989年 | 20篇 |
1988年 | 20篇 |
1987年 | 22篇 |
1986年 | 20篇 |
1985年 | 35篇 |
1984年 | 34篇 |
1982年 | 19篇 |
1981年 | 25篇 |
1980年 | 15篇 |
1979年 | 22篇 |
1978年 | 13篇 |
1977年 | 18篇 |
1976年 | 16篇 |
1975年 | 17篇 |
1964年 | 64篇 |
1963年 | 54篇 |
1962年 | 16篇 |
排序方式: 共有2855条查询结果,搜索用时 15 毫秒
51.
Cover Picture: Absolute Configuration from Different Multifragmentation Pathways in Light‐Induced Coulomb Explosion Imaging (ChemPhysChem 16/2016) 下载免费PDF全文
Dr. Martin Pitzer Gregor Kastirke Dr. Maksim Kunitski Dr. Till Jahnke Dr. Tobias Bauer Christoph Goihl Florian Trinter Carl Schober Kevin Henrichs Jasper Becht Stefan Zeller Helena Gassert Markus Waitz Andreas Kuhlins Hendrik Sann Felix Sturm Florian Wiegandt Dr. Robert Wallauer Dr. Lothar Ph. H. Schmidt Allan S. Johnson Manuel Mazenauer Benjamin Spenger Sabrina Marquardt Sebastian Marquardt Prof. Dr. Horst Schmidt‐Böcking Prof. Dr. Jürgen Stohner Prof. Dr. Reinhard Dörner Dr. Markus Schöffler Prof. Dr. Robert Berger 《Chemphyschem》2016,17(16):2448-2448
52.
53.
Dipl.‐Chem. Felix Koch Dr. Andreas Berkefeld Dr. Hartmut Schubert Claudius Grauer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(41):14640-14647
This work reports on the redox and acid–base properties of binuclear complexes of nickel from 1,4‐terphenyldithiophenol ligands. The results provide insight into the cooperative electronic interaction between a dinickel core and its ligand. Donor/acceptor contributions flexibly adjust to stabilize different redox states at the metals, which is relevant for redox reactions like proton reduction. Proton transfer to the [S2Ni2] core and Ni?H bond formation are kinetically favored over the thermodynamically favored yet unproductive proton transfer to ligand. 相似文献
54.
David Bialas Christoph Brüning Dr. Felix Schlosser Dr. Benjamin Fimmel Johannes Thein Prof. Dr. Volker Engel Prof. Dr. Frank Würthner 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(42):15011-15018
The optical properties of a series of three cyclophanes comprising either identical or different perylene bisimide (PBI) chromophores were studied by UV/Vis absorption spectroscopy and their distinctive spectral features were analyzed. All the investigated cyclophanes show significantly different absorption features with respect to the corresponding constituent PBI monomers indicating strong coupling interactions between the PBI units within the cyclophanes. DFT calculations suggest a π‐stacked arrangement of the PBI units at close van der Waals distance in the cyclophanes with rotational displacement. Simulations of the absorption spectra based on time‐dependent quantum mechanics properly reproduced the experimental spectra, revealing exciton‐vibrational coupling between the chromophores both in homo‐ and heterodimer stacks. The PBI cyclophane comprising two different PBI chromophores represents the first example of a PBI heterodimer stack for which the exciton coupling has been investigated. The quantum dynamics analysis reveals that exciton coupling in heteroaggregates is indeed of similar strength as for homoaggregates. 相似文献
55.
56.
57.
Piero Pino Felix Oldani Giambattista Consiglio 《Journal of organometallic chemistry》1983,250(1):491-497
In the hydroformylation of ethylene with approximately equimolar H2/D2 mixtures and Rh4(CO)12 or Co2(CO)8 as the catalyst precursor about 50% of propionaldehyde-d1 was formed. The propionaldehyde-d0/d2 ratio was ~ 3 for rhodium and ~ 2.6 for the cobalt catalyst. On the basis of the results and assuming that there is no rapid M(H)2/M(D)2 scrambling, activation of hydrogen through M(H)2 or M(H)2(olefin) complexes can be excluded. 相似文献
58.
The three molybdenum-N2 complexes [Mo(N2)(dpepp)(depe)] (1), [Mo(N2)(dpepp)(dppe)] (2), and [Mo(N2)(dpepp)(1,2-dppp)] (3), all of which contain a combination of a bi- and a tridentate phosphine ligand, were prepared and investigated by vibrational and (31)P NMR spectroscopy. As a tridentate ligand bis(2-diphenylphosphinoethyl)phenylphosphine (dpepp) has been employed. The three different bidentate ligands are 1,2-bis(diethylphosphino)ethane (depe), 1,2-bis(diphenylphosphino)ethane (dppe), and R-(+)-1,2-bis(diphenylphosphino)propane (1,2-dppp). N-N as well as metal-N vibrations of 1-3 are identified and interpreted in terms of the geometric and electronic structures of the complexes. (31)P NMR spectra are recorded and fully analyzed. Moreover, correlation spectroscopy (COSY)-45 measurements are performed to determine the relative signs of coupling constants. Special attention is directed to a detection of different isomers and their (31)P NMR, as well as vibrational spectroscopic properties. The implications of the results for the area of synthetic nitrogen fixation with phosphine complexes are discussed. 相似文献
59.
Upconverted yellow singlet fluorescence from rubrene (5,6,11,12-tetraphenylnapthacene) was generated from selective excitation (lambdaex = 725 nm) of the red light absorbing triplet sensitizer palladium(II) octabutoxyphthalocyanine, PdPc(OBu)8, in vacuum degassed toluene solutions using a Nd:YAG/OPO laser system in concert with gated iCCD detection. The data are consistent with upconversion proceeding from triplet-triplet annihilation (TTA) of rubrene acceptor molecules. The TTA process was confirmed by the quadratic dependence of the upconverted delayed fluorescence intensity with respect to incident light, measured by integrating the corresponding kinetic traces as a function of the incident excitation power. In vacuum degassed toluene solutions, the red-to-yellow upconversion process is stable under continuous long wavelength irradiation and is readily visualized by the naked eye even at modest laser fluence (0.6 mJ/pulse). In aerated solutions, however, selective excitation of the phthalocyanine sensitizer leads to rapid decomposition of rubrene into its corresponding endoperoxide as evidenced by UV-vis (in toluene), 1H NMR (in d6-benzene), and MALDI-TOF mass spectrometry, consistent with the established reactivity of rubrene with singlet dioxygen. The upconversion process in this triplet sensitizer/acceptor-annihilator combination was preliminarily investigated in solid polymer films composed of a 50:50 mixture of an ethyleneoxide/epichlorohydrin copolymer, P(EO/EP). Films that were prepared under an argon atmosphere and maintained under this inert environment successfully achieve the anticipated quadratic incident power dependence, whereas air exposure causes the film to deviate somewhat from this dependence. To the best of our knowledge, the current study represents the first example of photon upconversion using a phthalocyanine triplet sensitizer, furthering the notion that anti-Stokes light-producing sensitized TTA appears to be a general phenomenon as long as proper energy criteria are met. 相似文献
60.
Marianne Stranger Agnieszka Krata Velichka Kontozova-Deutsch Felix Deutsch Anna Worobiec Edward Roekens 《Microchemical Journal》2008,90(2):93-98
Nitrogen dioxide (NO2) concentrations were used to evaluate the air quality before and after the infrastructural change of an important traffic artery in Mortsel, Antwerp (Belgium). During the reconstruction works two pairs of traffic lanes were reduced to one in each direction. Two sampling campaigns were conducted: the first one before the works in 2003 and the second one in 2005, after the road works were finished. Sampling was performed on a weekly base with the use of passive diffusion tubes on the streets, and also indoors in nearby houses. The samples were analyzed by ion chromatography, from which data the NO2 concentrations in air could be calculated. These results were compared with NO2 values from the air monitoring station 42R801 of the Flemish Environment Agency in Borgerhout, Antwerp. On the base of different NO2 concentrations, correlated well with the traffic density, sampling locations were classified into three groups as follows: 1) ‘heavily polluted’ (heavy traffic); 2) ‘moderately polluted’ (medium traffic); or 3) ‘less polluted’ (low traffic density). Sampling sites located further from the road works, enclosed to the group ‘less polluted’, showed the lowest NO2 concentrations. The highest NO2 level was found for the locations close to reconstruction works, which belonged to the group ‘heavily polluted’. The contribution of NO2 was at the same level before and after the road works. During the first campaign it ranged from 30 ± 7 µg/m3 to 71 ± 11 µg/m3 and during the second sampling it was between 36 ± 17 µg/m3 and 73 ± 17 µg/m3. These modernization works had no impact on preventing the traffic-related pollutant as NO2 and as a consequence no significant effect on the air quality in the studied region. It has been proven that the impact of traffic on the air quality is unmistakably high and simply reduction of the number of the traffic lanes, intended to discourage the traffic flow, had apparently no environmentally advantageous effect. 相似文献