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71.
72.
García F Less RJ McPartlin M Michalski A Mulvey RE Naseri V Stead ML Morán de Vega A Wright DS 《Chemical communications (Cambridge, England)》2011,47(6):1821-1823
The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li(4)·3thf}(4)(μ(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li(4) sites has negligible effect on the structural parameters. 相似文献
73.
Felipe Ledesma 《Metaphysica》2007,8(2):179-201
The intention of this article is to show that the Tractatus deals with the problem of the relation between reality, possibility, and necessity as traditionally considered in the ontological argument, that is, in relation to the idea of limit, and that in Section 5.5521, we find an especially clarifying formulation of this question; the formulation itself, however, is not at all clear, so that a lengthy commentary of it is justified. 相似文献
74.
Juliana Nanclares Jesús Gil Benjamn Rojano Jairo Saez Bernd Schneider Felipe Otlvaro 《Tetrahedron letters》2008,49(24):3844-3847
4-Methoxy-1H-phenalen-1-one (4-methoxyperinaphthenone, 1), a subunit found in some Musa phytoalexins and related natural products from the Haemodoraceae, was synthesized starting from 2-methoxynaphthalene in five steps and an overall yield of 36%. A Heck–Fujiwara coupling between ethyl acrylate and 1-bromonaphthalene afforded the corresponding (E)-naphthylpropanoic acid which, after hydrogenolysis, was subjected to a one-pot Friedel–Crafts acylation–DDQ dehydrogenation procedure to furnish 1. 相似文献
75.
José Felipe Voloch 《Monatshefte für Mathematik》1995,119(4):321-325
We study diophantine approximations to algebraic functions in characteristicp. We improve a theorem of Osgood, and give two classes of examples showing that this result is nearly sharp. One of these classes exhibits a new phenomenon. 相似文献
76.
77.
Ernesto Brunet Jos L. Gracía-Ruano Miguel A. Hoyos Jesús H. Rodríguez Pilar Prados Felipe Alcudia 《Magnetic resonance in chemistry : MRC》1983,21(10):643-648
The conformational analysis of the diastereomeric 2-methylsulphinyl-1-phenylethanol and its O-methyl and O-acetyl derivatives has been performed by 1H NMR spectroscopy. The study of the influence of dilution and solvent polarity changes on the coupling constants has permitted the configurational assignment of each diastereoisomer. The role played by hydrogen bonding in the hydroxysulphoxides has also been studied by IR spectroscopy. 相似文献
78.
Bulat FA Toro-Labbé A Champagne B Kirtman B Yang W 《The Journal of chemical physics》2005,123(1):014319
The performance of the optimized effective potential procedure for exact exchange in calculating static electric-field response properties of push-pull pi-conjugated systems has been studied, with an emphasis on NO2-(CH=CH)n-NH2 chains. Good agreement with Hartree-Fock dipole moments and (hyper)polarizabilities is obtained; particularly noteworthy is the chain length dependence for beta/n. Thus, the problem that conventional density-functional theory functionals dramatically overestimate these properties is largely solved, although there remains a significant correlation contribution that cannot be accounted for with current correlation functionals. 相似文献
79.
Dodds F García F Kowenicki RA McPartlin M Riera L Steiner A Wright DS 《Chemical communications (Cambridge, England)》2005,(40):5041-5043
The tetrameric macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4, obtained from the reaction of the phosphazane dimer [ClP(mu-NtBu)]2 with p-phenylenediamine, has an unusual folded conformation in the solid state and contains a roughly tetrahedral arrangement of endo N-H groups for the potential coordination of anions. 相似文献
80.