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151.
Infrared multiple-photon dissociation of N2H4 and CH3NH2 fluence dependence of the production of NH2
S.V. Filseth J. Danon D. Feldmann J.D. Campbell K.H. Welge 《Chemical physics letters》1979,63(3):615-620
The multiple-photon dissociation of N2H4 and CH3NH2 by pulsed CO2 laser light to produce NH2(X?2BI has been studied using the laser-induced fluorescence detection method. The relative NH2 yield, represented by the fluorescence signal, has been measured as a function of the fluence from the threshold at about 0.1 J/cm2 to about 100 J/cm2, at different CO2-laser lines and at pressures down to 10?4 Torr. 相似文献
152.
To the Knowledge of cis-Sodium Hyponitrite Surprisingly, cis-sodium hyponitrite can be prepared by reacting gaseous N2O and solid Na2O. For the first time, the structure of a simple salt of cis hyponitrous acid has been determinated unambigously. According to an abinitio structure determination based on powder data, cis-Na2N2O2 crystallizes monoclinic (P21/c, a = 5.107(1); b = 9.211(1); c = 6.159(1) Å; β = 97.91(1)°; Z = 4). Results of spectroscopic investigations (vibrational spectroscopy, 15N-MAS-NMR) agree with the symmetry of the cis-N2O22? anion as it has been proved by the crystal structure. Consider able differences regarding some chemical and physical properties have been observed for samples of cis-Na2N2O2 synthesized via different routes. 相似文献
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154.
M. Guillot A. Marchand F. Tchéou P. Feldmann H. Le Gall 《Zeitschrift für Physik B Condensed Matter》1981,44(1):41-52
The magnetic properties of single crystals of erbium iron garnet (ErIG) were studied in applied fields up to 150kOe between 1.4 and 300K. At low temperature, the macroscopic easy direction of the bulk magnetization is [100]; below the compensation temperature (80±2K), the magnetization presents non-linear field evolution. On the assumption of an isolated ground doublet, the anisotropy constantsK i (i=1,2) of ErIG are given byK i (Er)+K i (YIG); theK i are calculated as a function of theG andg tensor components. It is worthwhile noting that theK i (Er) are strongly temperature dependent; so at low temperature the anisotropy of the garnet is determined by the rare earth ions, while in the 50 K regionK 1(Er) becomes comparable toK 1(YIG) with the opposite sign which results in a very weak anisotropy of the garnet. Above 50 K,K 1(YIG) is predominant and the Fe3+ ions determine the garnet anisotropy. 相似文献
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157.
By reaction of MIICl2·x H2O (M = Fe (x = 4), Co, Ni (x = 6)) and LiOH·H2O in diethylene glycol (DEG) rod‐like crystals of the composition MII4Cl4(OCH2CH2OCH2CH2OH)4 are formed. According to X‐ray diffraction data obtained by both, single crystals and powders, the CoII and NiII compounds crystallize monoclinic with C2/c (CoII4Cl4(OCH2CH2OCH2CH2OH)4 ( 1 ): a = 2084.1(4), b = 919.0(2), c = 1754.0(4) pm, β = 124.3(1)°, Z = 4; NiII4Cl4(OCH2CH2OCH2CH2OH)4 ( 2 ): a = 2055.2(4), b = 932.1(2), c = 1727.4(4) pm, β = 125.2(1)°, Z = 4), whereas FeII4Cl4(OCH2CH2OCH2CH2OH)4 ( 3 ) crystallizes tetragonal with (a = 1251.4(2), c = 915.3(2) pm, Z = 2). All compounds exhibit analogous molecular structures which are built of a heterocubane‐type core consisting of four metal ions and four deprotonated oxygen atoms of four coordinated diethylene glycol molecules. Neutrality of charge is realized by additional coordination of four chloride anions. In addition to the structural characterization, the thermal and magnetical properties of the title compounds are investigated in detail. 相似文献
158.
M. Beneke Th Feldmann D. Seidel 《The European Physical Journal C - Particles and Fields》2005,41(2):173-188
We provide standard model expectations for the rare radiative decays
,
and
, and the electroweak penguin decays
and
at the next-to-leading order (NLO), extending our previous results to
transitions. We consider branching fractions, isospin asymmetries and direct CP asymmetries. For the electroweak penguin decays, the lepton-invariant mass spectrum and forward-backward asymmetry is also included. Radiative and electroweak penguin transitions in
are mainly interesting in the search for new flavor-changing neutral current interactions, but in addition the
decays provide constraints on the CKM parameters
. The potential impact of these constraints is discussed.Received: 16 January 2005, Published online: 16 March 2005
Corresponding author: Th. Feldmann 相似文献
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